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Biomedical Mg-Sn-Mn series magnesium alloy and plate rolling process thereof

A mg-sn-mn, biomedical technology, applied in the field of alloys, can solve the problems of unclear biological effects, poor room temperature plasticity, etc., and achieve the effect of improving room temperature plasticity and strength, improving corrosion resistance, and good plasticity

Active Publication Date: 2011-08-03
JIANGYIN BIODEGRADE MEDICAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although rare earth elements such as neodymium and yttrium can improve the strength and corrosion resistance of magnesium alloys, their biological effects are still unclear, so their safety needs to be observed in long-term experiments
[0003] Aiming at the problem of poor room temperature plasticity of magnesium and magnesium alloys, people have developed ductile magnesium alloys, such as the technical solution disclosed in the invention patent document with the application number 200810234439.5 and the name "a ductile magnesium alloy and its preparation method"

Method used

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  • Biomedical Mg-Sn-Mn series magnesium alloy and plate rolling process thereof
  • Biomedical Mg-Sn-Mn series magnesium alloy and plate rolling process thereof
  • Biomedical Mg-Sn-Mn series magnesium alloy and plate rolling process thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0028] Using pure magnesium ingot (purity 99.95%), pure tin ingot (purity 99.9%) and Mg-9.7%Mn master alloy, according to Mg-3Sn-0.5Mn alloy composition (nominal composition: Sn 3%, Mn 0.5%, impurity elements Fe 6 / CO 2 Under the protection of mixed gas, it is poured into the metal mold for gravity casting. The metallographic structure of the as-cast Mg-3Sn-0.5Mn alloy obtained by the present invention is as follows: figure 1 shown.

Embodiment 2

[0030] Using pure magnesium ingot (purity 99.95%), pure tin ingot (purity 99.9%) and Mg-9.7% Mn master alloy, according to Mg-3Sn-1Mn alloy composition (nominal composition: Sn 3%, Mn 1%, impurity element Fe 6 / CO 2 Under the protection of mixed gas, it is poured into the metal mold for gravity casting. The metallographic structure of the as-cast Mg-3Sn-1Mn alloy obtained by the present invention is as follows: figure 2 shown. The above-mentioned as-cast Mg-3Sn-1Mn alloy is subjected to high-temperature short-term solution treatment (solution treatment temperature is 555 ° C, holding time is 10-40min), and its phase composition, that is, the X-ray diffraction (XRD) pattern is as follows image 3 shown.

Embodiment 3

[0032] Before rolling the Mg-3Sn-0.5Mn alloy ingot described in Example 1, adopt two kinds of homogenization heat treatment processes of traditional solution treatment and high-temperature short-time solution treatment and traditional solution treatment respectively, and the obtained rolled Mg The phase composition of -3Sn-0.5Mn alloy is the X-ray diffraction (XRD) pattern as shown in Figure 4 Rolling state 1 and rolling state 2 are shown. Rolling deformation after homogenization heat treatment: rough rolling billet opening temperature is 400-450°C, pass reduction 10-15%; intermediate rolling temperature is 350-400°C, pass reduction can reach 50-60% ; Finish rolling temperature is 260~350℃, pass reduction is 5-10%. With the above rolling process, the rolling reduction exceeds 90% without cracks. The metallographic structure of the obtained as-rolled Mg-3Sn-0.5Mn alloy is as follows Figure 5 As shown, it can be seen from the figure that the grains of the magnesium alloy af...

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Abstract

The invention provides a biomedical Mg-Sn-Mn series magnesium alloy and a plate rolling process thereof. The process is characterized in that: an Mg-Sn-Mn series magnesium alloy ingot comprising 1 to 3 percent of Sn, 0.15 to 1.0 percent of Mn, less than 0.002 percent of impurity element Fe or less than or equal to 0.02 percent of Fe / Mn, less than 0.002 percent of Cu, less than 0.002 percent of Niand the balance of Mg is selected; a uniform thermal treatment process combining high-temperature short-time solid solution treatment and traditional solid solution treatment is adopted before rolling the ingot, wherein the temperature of the high-temperature short-time solid solution treatment is 550 to 560 DEG C and the treatment time is 1 to 2 hours, and the temperature of the traditional solid solution treatment is 300 to 450 DEG C and the time is 20 to 30 hours; and variable temperature large-deformation rolling is adopted during rolling. The Mg-Sn-Mn series magnesium alloy obtained by the rolling process has the advantages of no toxicity, full degradation and high toughness, and can be used as an orthopedic surgery internal fixation and implant material for intravascular stents, bone lamellas, bone nails and the like.

Description

technical field [0001] The invention relates to an alloy, and the invention also relates to a preparation method of the alloy. In particular, an alloy used in the field of biomedical materials and a preparation method thereof. Background technique [0002] At present, most biodegradable biomedical materials are polymer materials such as polylactic acid (PLA) and polyglycolic acid (PGA), but they have problems such as low mechanical properties, difficult processing, and degradation products in the body that easily cause inflammation and swelling. Degradable magnesium alloys have good comprehensive mechanical properties and mechanical processing properties. For example, extruded AZ31 magnesium alloy has high strength (tensile strength is 255MPa, yield strength can reach 200MPa), which can meet the mechanical properties of biomedical materials. Require. Moreover, the elastic modulus of magnesium alloy is about 40GPa, which is very close to bone tissue, which can effectively r...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C23/00C22F1/06B21B37/16B21B37/74
Inventor 李新林李莉杨小荣郑玉峰王香侯理达杨宝林
Owner JIANGYIN BIODEGRADE MEDICAL TECH CO LTD