Optical multilayer body and producing method thereof
A technology of optical laminates and adhesive layers, applied in chemical instruments and methods, optics, nonlinear optics, etc., can solve the problems of polarizing plate peeling and polarizing film cracking, and achieve good adhesion and reduced thickness
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manufacture example 1
[0155] (Production Example 1: Production of Polarizing Film)
[0156] A polyvinyl alcohol film with a thickness of 75 μm having an average degree of polymerization of about 2400 and a degree of saponification of 99.9 mol% or more was immersed in pure water at 30°C, and then immersed in iodine / potassium iodide / water at a weight ratio of 0.02 / 2 / at 30°C. 100 in aqueous solution. Then, it immersed in the aqueous solution whose weight ratio of potassium iodide / boric acid / water is 12 / 5 / 100 at 56.5 degreeC. Next, after washing with pure water at 8° C., drying was performed at 65° C. to obtain a polarizing film having a thickness of about 30 μm in which iodine was adsorbed and oriented in polyvinyl alcohol. The stretching was mainly carried out in the steps of iodine dyeing and boric acid treatment, and the total stretching ratio was 5.3 times.
manufacture example 2
[0157] (Production Example 2: Production of Polarizing Plate)
[0158] On one side of a polyethylene terephthalate (PET) film (manufactured by Toyobo Co., Ltd., Toyobo Ester Film E7002), a coating machine (manufactured by Daiichi Rika Co., Ltd., bar coater) was used, The active energy ray-curable resin composition of the following composition which forms the transparent protective layer of a polarizing film is apply|coated.
[0159] [Active energy ray-curable resin composition for transparent protective layer]
[0160] 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (manufactured by Daicel Chemical Co., Ltd., Seirokisoid 2021P) 35 parts
[0161] 15 parts of bis(3-ethyl-3-oxetanyl methyl) ether (ARONOXETANE OXT-221, manufactured by Toagosei Co., Ltd.)
[0162] Diacrylate of acetal compound of hydroxytrimethylacetaldehyde and trimethylolpropane (manufactured by Shin-Nakamura Chemical Industry Co., Ltd., A-DOG) 50 parts
[0163] 2-Hydroxy-2-methyl-1-phenylpropan-1-on...
manufacture example 3
[0169] (Production Example 3: Preparation of Adhesive Composition)
[0170] The following components were mixed to obtain an ultraviolet curable adhesive composition.
[0171] [UV-curable adhesive composition]
[0172] 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (manufactured by Daicel Chemical Co., Ltd., Seirokisoid 2021P) 75 parts
[0173] 25 parts of bis(3-ethyl-3-oxetanyl methyl) ether (ARONOXETANE OXT-221, manufactured by Toagosei Co., Ltd.)
[0174] 4,4'-bis[diphenylsulfonium]diphenylthiobishexafluorophosphate-based photocationic polymerization initiator (UVACURE 1590 manufactured by Daicel-Saitech Co., Ltd.) 5 parts
[0175] Silicone-based leveling agent (made by Toray Dow Corning, SH710) 0.2 part
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