Method for preparing quaternary ammonium salt containing adamantine alkyl

A technology of adamantane trimethylammonium halide salt and adamantyl, which is applied in the field of preparation of quaternary ammonium salts with adamantyl, and can solve the problems of incomplete reaction of raw materials, impossibility of purification, impossibility of improving purity, etc.
CN101935286AInactive Publication Date: 2011-01-05IDEMITSU KOSAN CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Current Assignee / Owner
IDEMITSU KOSAN CO LTD
Publication Date
2011-01-05
Estimated Expiration
Not applicable · inactive patent

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Abstract

The present invention relates to a method for preparing a quaternary ammonium salt containing adamantine alkyl. By means of the method of the invention, it is possible to effectively in a short time and industrially high-yield and high -purity prepare the quaternary ammonium salt containing the adamantine alkyl. The method is characterized in that it includes a step A and a step B, step A: a step of preparing 1-adamantane dimethyl amine (formula (2)) selected from a step of reacting a reactant of an adamantane hydrochloric acid and a base metal hydroxide dissolved in a solvent (a) which relative inductivity is 10.0 to 20.0 with aminic acid and methyl aldehyde or paraformaldehyde, a step of reacting 1-amidogen adamantane dissolved in the solvent (a) with aminic acid and methyl aldehyde or paraformaldehyde, and a step of reacting 1-halogeno adamantane with dimethyl amine; step B: a step of preparing a 1-adamantane trimethyl halogenation aminium salt by reacting the 1-adamantane dimethyl amine of the step A dissolved in a solvent (b) with halomethane.
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Description

technical field

[0001] The present invention relates to the preparation method of the quaternary ammonium salt with adamantyl group, more specifically, relates to the method for preparing the quaternary ammonium salt with adamantyl group with high yield and high purity. Background technique

[0002] Adamantane has a structure of four cyclohexane rings condensed into a cage shape. It is a stable compound with high symmetry. Its derivatives show specific functions. Therefore, it is known that it is a raw material for pharmaceuticals and high-functional industrial materials. useful.

[0003] For example, adamantane derivatives have been tried to be used in optical disk substrates, optical fibers, lenses, etc. due to their optical properties, heat resistance, etc. (see, for example, Patent Documents 1 and 2).

[0004] In addition, adamantyl esters have been attempted to be used as resin raw materials for photoresists by utilizing their acid sensitivity, dry etching resistance, ...

Claims

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