Solar battery electrolyte and application thereof
A technology for solar cells and electrolytes, applied in the field of solar cells, can solve problems such as current drop, and achieve the effects of improving filling factor, good electrochemical reversibility, and reducing manufacturing costs
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Embodiment 1
[0052] Embodiment 1: the synthesis of organosulfide--1,3-dimethylimidazolium sulfur salt
[0053] Add 22.60g of 1,3-dimethylimidazolium iodide to a three-necked flask under nitrogen protection, add 20mL of ether as a solvent, slowly add 13.64g of AgO solid, stir for 20 minutes to fully react, and then hydraulically filter the reaction to In another three-necked flask under nitrogen protection, then add 47.01g of (NH 4 ) 2 S (8% aqueous solution), stirred, heated and dried until a solid was obtained.
Embodiment 2
[0054] Embodiment 2: the synthesis of organic sulfide-tetramethylammonium sulfide
[0055] In the there-necked flask under nitrogen protection, add 36.0g tetramethylammonium hydroxide (25% aqueous solution), then add 42.7g (NH 4 ) 2 S (8% aqueous solution), stirred, heated and dried until a solid was obtained.
Embodiment 3
[0056] Embodiment 3: the synthesis of organic sulfide-1-picoline sulfur salt
[0057] Add 7.9g of pyridine raw material to a three-necked flask under nitrogen protection, add 20mL of DMF as a solvent, slowly add 14.2g of methyl iodide in an ice bath, stir for 2 hours, distill under reduced pressure until a solid product is obtained, and then add 20mL of Diethyl ether was made solvent, and the AgO solid of 13.6g was slowly added, stirred 20 minutes and made it fully reacted and then reaction hydraulic pressure was filtered in the there-necked flask under another nitrogen protection, then added 42.7g (NH 4 ) 2 S (8% aqueous solution), stirred, heated and dried until a solid was obtained.
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