Preparation method of photoinduction nano alternative-current power generator based on zinc oxide/ polyaniline/zinc oxide

An alternator, zinc oxide technology, applied in the direction of light radiation generator, generator/motor, etc., to achieve the effect of simple preparation process, single shape and high purity

Inactive Publication Date: 2012-05-02
NORTHEAST NORMAL UNIVERSITY
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although many studies based on these metal oxides and nitrides have demonstrated new nanodevices and applications, however, very little work has been devoted to the self-p

Method used

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  • Preparation method of photoinduction nano alternative-current power generator based on zinc oxide/ polyaniline/zinc oxide
  • Preparation method of photoinduction nano alternative-current power generator based on zinc oxide/ polyaniline/zinc oxide
  • Preparation method of photoinduction nano alternative-current power generator based on zinc oxide/ polyaniline/zinc oxide

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Experimental program
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Effect test

Embodiment 1

[0026] 1. Treatment of conductive glass:

[0027] The ITO conductive glass used as the working electrode was pre-cut into strips of 2cm×1cm, firstly ultrasonicated in absolute ethanol for 15 minutes, and then ultrasonicated in ethanol aqueous solution of sodium hydroxide (the volume ratio of ethanol to water was 1:1) After 15 minutes, ultrasonically clean with absolute ethanol and deionized water respectively, and finally blow dry with nitrogen for use.

[0028] 2. Synthesis of polyaniline nanofibers: carried out in a 50 ml glass container. 3.28 g K 2 S 2 o 8 and 5 g H 4 SiW 12 o 40 The acid was dissolved in 20 mL of deionized water and stirred evenly in an ice bath to form mixture 1. Subsequently, 10 drops of aniline were pipetted with a dropper and dissolved in 20 ml of chloroform, and stirred evenly in an ice bath to form a mixture 2. Mixture 1 was carefully added to Mixture 2 to form a liquid-liquid interface. The interfacial reaction was carried out at 0°C-5°C fo...

Embodiment 2

[0032] 1. Treatment of conductive glass:

[0033] The ITO conductive glass used as the working electrode was pre-cut into strips of 2cm×1cm, firstly ultrasonicated in absolute ethanol for 15 minutes, and then ultrasonicated in ethanol aqueous solution of sodium hydroxide (the volume ratio of ethanol to water was 1:1) After 15 minutes, ultrasonically clean with absolute ethanol and deionized water respectively, and finally blow dry with nitrogen for use.

[0034] 2. Synthesis of polyaniline nanofibers:

[0035] Do this in a 50ml glass container. 3.28 g K 2 S 2 o 8 and 5 g H 4 SiW 12 o 40 The acid was dissolved in 20 mL of deionized water and stirred evenly in an ice bath to form mixture 1. Subsequently, 10 drops of aniline were pipetted with a dropper and dissolved in 20 ml of chloroform, and stirred evenly in an ice bath to form a mixture 2. Mixture 1 was carefully added to Mixture 2 to form a liquid-liquid interface. The interfacial reaction was carried out at 0-5°C...

Embodiment 3

[0039] 1. Treatment of conductive glass:

[0040] The ITO conductive glass used as the working electrode was pre-cut into strips of 2cm×1cm, firstly ultrasonicated in absolute ethanol for 15 minutes, and then ultrasonicated in ethanol aqueous solution of sodium hydroxide (the volume ratio of ethanol to water was 1:1) After 15 minutes, ultrasonically clean with absolute ethanol and deionized water respectively, and finally blow dry with nitrogen for use.

[0041] 2. Synthesis of polyaniline nanofibers:

[0042] Do this in a 50ml glass container. 3.28 g K 2 S 2 o 8 and 5 g H 4 SiW 12 o 40 The acid was dissolved in 20 mL of deionized water and stirred evenly in an ice bath to form mixture 1. Subsequently, 10 drops of aniline were pipetted with a dropper and dissolved in 20 ml of chloroform, and stirred evenly in an ice bath to form a mixture 2. Mixture 1 was carefully added to Mixture 2 to form a liquid-liquid interface. The interfacial reaction was carried out at -2°C ...

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Abstract

The invention discloses a preparation method of an N-P-N-type photoinduction nano alternative-current power generator based on zinc oxide (ZnO)/polyaniline (PANI)/zinc oxide (ZnO). An N-type ZnO nano rod is synthesized in a method that a seed is firstly grown on an Indium Tin Oxide (ITO) substrate and then hydro-thermal reaction is executed, and a P-type PANI nano fiber is synthesized through an inorganic/organic interface method. In the nano alternative-current power generator device, a great amount of electron-hole pairs are produced inside a photosensitive ZnO nano rod after being radiated by ultravoilet ray, the hole is immediately combined with oxygen ions on the surface of the ZnO to generate the oxygen so as to consume a great amount of holes, and the surplus electrons can directionally move along a conducting wire to form current. Therefore, under the situation that no external voltage is applied, the parts containing ZnO at two sides of the device are respectively radiated by the ultravoilet ray, so the alternative-current power in an opposite direction can be generated. A P-N heterojunction plays an important role in controlling the movement direction of the photo-generated electrons in the ZnO/PANI/ZnO device. Due to the adoption of the method, the optical energy can be converted to the electric power.

Description

technical field [0001] The invention belongs to the field of photoelectric functional materials, in particular to a preparation method of a light-induced nanometer alternator for converting light energy into electric energy. Background technique [0002] In 2006, Wang Zhonglin's research group reported a new method to convert nanoscale mechanical energy into electrical energy. This energy conversion occurs through the piezoelectric effect of ZnO nanofiber arrays. This study shows us a Self-powered energy source. In order to improve the energy generation capability, in 2007, the research group drove ZnO nanofibers through ultrasound and obtained continuous current generation, resulting in the birth of a direct current (DC) nanogenerator. These studies provide us with a good example of converting mechanical energy into electrical energy. (Wang, X.D.; Zhou, J.; Song, J.H.; Liu, J.; Xu, N.S.; Wang, Z.L. Nano. Lett. 2006, 6, 2768-2772; Song, J.; Zhou, J.; Wang, Z.L. 2006, 6, 1...

Claims

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Application Information

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IPC IPC(8): H02N6/00C03C17/34
Inventor 龚剑杨圣雪
Owner NORTHEAST NORMAL UNIVERSITY
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