Amorphous alloy cellular material and preparation method thereof

A technology of amorphous alloy and honeycomb material, applied in the field of amorphous alloy honeycomb material and its preparation, can solve the problems of high cost, unstable performance, low connection strength, etc., and achieve the effects of high strength, convenient porosity, and improved strength

Inactive Publication Date: 2012-07-04
BEIJING INSTITUTE OF TECHNOLOGYGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the preparation methods of metal honeycomb materials mainly include: (1) processing metal sheet strips into corrugated shapes, and then bonding or welding them into metal honeycomb materials. It is not high, which has seriously affected the strength of the metal honeycomb material itself; (2) the metal honeycomb material is prepared by using the metal powder plasticized extrusion-sintering process, although the gap between the through holes and the through holes in the method (1) has been improved. The connection performance is poor, but this method of preparing metal honeycomb materials has a high cost and is not easy to promote; (3) Gasar method to prepare honeycomb materials, this method is to use saturated dissolved hydrogen (or oxygen, nitrogen, etc.) The directional solidification of the metal melt, with the help of the large solubility difference of hydrogen in the liquid phase and the solid phase of the metal, utilizes the metal-gas eutectic reaction to make the gas phase and the solid phase grow together to obtain a directional arrangement of cylindrical pores along the solidification direction However, this preparation method is still in the research stage and cannot well control the pore size and shape of the prepared metal honeycomb material. Therefore, this method has poor repeatability and unstable performance. , Metal honeycomb materials with larger dimensions in the axial direction of the hole cannot be obtained and the cost is higher
The metal honeycomb materials prepared by the above methods generally have low strength, which restricts the use and promotion of metal honeycomb materials

Method used

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  • Amorphous alloy cellular material and preparation method thereof
  • Amorphous alloy cellular material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] 1) Seal both ends of a stainless steel 304 alloy hollow tube 1 with an outer diameter of 1 mm, a wall thickness of 0.15 mm, and a length of 40 mm, and then pickle with HCl with a mass concentration of 1% to remove the oxide skin on the surface of the hollow tube 1 and impurities, then rinsed with deionized water, and dried for later use.

[0027] 2) The hollow tube 1 is vertically stacked in a circular copper mold with an inner diameter of 50 mm, and then the copper mold is placed in an electric arc melting furnace.

[0028] 3) Take Zr 55 Cu 30 Al 10 Ni 5 The amorphous alloy is placed in a quartz crucible with a nozzle above the copper mold in the electric arc melting furnace. Under the protection of an argon atmosphere, the amorphous alloy is heated to 1300°C in the electric arc melting furnace to completely melt to obtain a melt; 55Kpa pressure, the melt is pressed between the hollow tube 1 and the hollow tube 1 in the copper mold and rapidly cooled and solidified...

Embodiment 2

[0030] 1) Take a stainless steel 304 alloy hollow tube 1 with an outer diameter of 2 mm, a wall thickness of 0.1 mm, and a length of 40 mm and seal both ends, and then pickle with HCl with a mass concentration of 1% to remove the oxide skin on the surface of the hollow tube 1 and impurities, then rinsed with deionized water, and dried for later use.

[0031] 2) The hollow tube 1 is vertically stacked in a circular copper mold with an inner diameter of 50mm, and then the copper mold is placed in an electric arc melting furnace.

[0032] 3) The alloy powder is weighed, and the total mass of the alloy powder is 100%, wherein the mass fraction of the Zr powder is 50%, the mass fraction of the Cu powder is 25%, the mass fraction of the Al powder is 9%, the mass fraction of the Ni powder The mass fraction of the alloy powder is 16%. The alloy powder is placed in a quartz crucible with a nozzle above the copper mold in an electric arc melting furnace. Under the protection of an argon...

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Abstract

The invention relates to an amorphous alloy cellular material and a preparation method of the amorphous alloy cellular material, belonging to the field of material preparation. The amorphous alloy cellular material is compounded by a hollow pipe and amorphous alloy, wherein the hollow pipe is taken as a straight through hole, the amorphous alloy is taken as a base body, the melting point of the hollow pipe is higher than that the amorphous alloy, and the amorphous alloy cellular material has higher strength. The amorphous alloy cellular material is prepared as follows: after two ends of the hollow pipe are sealed, the hollow pipe is arranged into a prefabricated body to be placed into a metal mold, an alloy or the amorphous alloy is completely melted through heating to obtain a melt under the protection of inert atmosphere, the melt is pressurized to be impregnated into a gap between a prefabricated body hollow pipe in the metal mold and the hollow pipe, and the melt is enabled to be rapidly cooled and solidified to form the amorphous alloy base body. In the invention, the porosity, the hole diameter and the overall dimension of the amorphous alloy cellular material can be conveniently controlled.

Description

technical field [0001] The invention relates to an amorphous alloy honeycomb material and a preparation method thereof, belonging to the field of material preparation. Background technique [0002] Porous material is a material with a network structure of interconnected or closed pores, and the boundary or surface of the pores is composed of pillars or plates; one of them is a two-dimensional structure formed by a large number of polygonal pores aggregated on a plane, because its shape is similar to It is called honeycomb material because of the hexagonal structure of the honeycomb. Among the honeycomb materials, the metal honeycomb material, as a functional material with a large number of through holes, high specific stiffness, high specific strength and anisotropy, has good shock absorption and noise reduction, cushioning energy absorption and electromagnetic shielding properties. [0003] At present, the preparation methods of metal honeycomb materials mainly include: (1...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C45/00B22D23/04
Inventor 李红温术来刘颖赵修臣王玉锋
Owner BEIJING INSTITUTE OF TECHNOLOGYGY
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