Textile water-based pigment printing binding agent and preparation method

A water-based paint and paint printing technology, applied in the direction of adhesive types, textiles and papermaking, ester copolymer adhesives, etc. Brightness, improved toughness and wear resistance, and storage stability

Active Publication Date: 2012-07-25
LIAONING FIXED STAR FINE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The title is "Formaldehyde-free Low-Temperature Adhesive", which discloses a synthesis method of an aldehyde-free low-temperature self-crosslinking pigment printing adhesive. The aldehyde-free crosslinking monomer glycidyl methacrylate is used instead of the traditional crosslinking monomer N-methylol acrylamide makes the

Method used

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  • Textile water-based pigment printing binding agent and preparation method
  • Textile water-based pigment printing binding agent and preparation method
  • Textile water-based pigment printing binding agent and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1. Emulsion polymerization:

[0033] 1) Raw material weight ratio: 33 grams of acrylonitrile, 34 grams of ethyl acrylate, 123 grams of butyl acrylate, 3.5 grams of acrylic acid, 3 grams of hydroxyethyl methacrylate, 2 grams of acrylamide, 1.5 grams of sodium lauryl sulfate , 6 grams of lauryl alcohol polyoxyethylene (10) ether, 300 grams of deionized water, 0.8 grams of ammonium persulfate, and 0.4 grams of sodium bisulfite;

[0034] 2) Mix 0.8 g of ammonium persulfate and 15 g of deionized water to obtain an aqueous solution of ammonium persulfate for use;

[0035] 3) Mix 0.4 g of sodium bisulfite and 15 g of deionized water to obtain an aqueous solution of sodium bisulfite for use;

[0036] 4) Add 175 grams of deionized water, 1.5 grams of the emulsifier sodium lauryl sulfate, and 6 grams of lauryl alcohol polyoxyethylene (10) ether into the pre-emulsion kettle, and then add all the monomer propylene 2 grams of amide, 33 grams of acrylonitrile, 34 grams of ethyl acr...

Embodiment 2

[0042] 1. Emulsion polymerization:

[0043] 1) Raw material weight ratio: 34 grams of acrylonitrile, 35 grams of ethyl acrylate, 124 grams of butyl acrylate, 3.7 grams of acrylic acid, 3.2 grams of hydroxyethyl methacrylate, 2.2 grams of acrylamide, 1.6 grams of sodium lauryl sulfate , 6.4 grams of lauryl alcohol polyoxyethylene (10) ether, 304 grams of deionized water, 0.82 grams of ammonium persulfate, and 0.41 grams of sodium bisulfite;

[0044] 2) Mix 0.82 g of ammonium persulfate and 15 g of deionized water to obtain an aqueous solution of ammonium persulfate for use;

[0045] 3) Mix 0.41 g of sodium bisulfite and 15 g of deionized water to obtain an aqueous solution of sodium bisulfite for use;

[0046]4) Add 177 grams of deionized water, 1.6 grams of the emulsifier sodium lauryl sulfate, and 6.4 grams of polyoxyethylene lauryl alcohol (10) ether into the pre-milk kettle, and then add all the monomer propylene 2.2 grams of amide, 34 grams of acrylonitrile, 35 grams of ...

Embodiment 3

[0052] 1. Emulsion polymerization:

[0053] 1) Raw material weight ratio: 34.5 grams of acrylonitrile, 35.5 grams of ethyl acrylate, 124.5 grams of butyl acrylate, 3.8 grams of acrylic acid, 3.3 grams of hydroxyethyl methacrylate, 2.3 grams of acrylamide, 1.7 grams of sodium lauryl sulfate , 6.8 grams of lauryl alcohol polyoxyethylene (10) ether, 308 grams of deionized water, 0.86 grams of ammonium persulfate, and 0.43 grams of sodium bisulfite;

[0054] 2) Mix 0.86 g of ammonium persulfate and 15 g of deionized water to obtain an aqueous solution of ammonium persulfate for use;

[0055] 3) Mix 0.43 g of sodium bisulfite and 15 g of deionized water to obtain an aqueous solution of sodium bisulfite for use;

[0056] 4) Add 179 grams of deionized water, 1.7 grams of the emulsifier sodium lauryl sulfate, and 6.8 grams of lauryl alcohol polyoxyethylene (10) ether into the pre-milk kettle, and then add all the monomer propylene 2.3 grams of amide, 34.5 grams of acrylonitrile, 35....

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PUM

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Abstract

The invention relates to a textile water-based pigment printing binding agent and a preparation method. The textile water-based pigment printing binding agent is prepared in a way that acrylonitrile, ethyl acrylate, butyl acrylate, crylic acid, hydroxyethyl methacrylate, acrylamide, sodium dodecyl sulfate, alcohol dodecyl polyoxyethylene (10) ether, deionized water, ammonium persulfate and sodiumhydrogen sulfite are subjected to emulsion polymerization and then are mixed with pyrolysis closed polyurethane crosslinking agent according to proportion. The product is cured in low temperature condition, has remarkable advantages in the aspects of dry rubbing fastness, wet rubbing fastness, soaping fastness and the like, is simple and easily-controllable in production operation, and is energy-saving and environment-friendly.

Description

technical field [0001] The invention relates to a polyurethane-modified acrylate polymer emulsion and a preparation method thereof, which is an adhesive used in textile pigment printing, especially an adhesive with excellent fastness when baked at low temperature. Background technique [0002] Pigment printing is to form a film of insoluble pigments through adhesives, and mechanically fix them on the surface of fibers, so as to achieve the purpose of color printing. The binder is a polymer film-forming substance, which is the main component of pigment printing. It exists in the printing paste as a dispersion, and is cross-linked to form a film by baking. Since the world's industry is currently aiming at energy saving and environmental protection, the research on adhesives also tends to explore low-temperature and environmental protection. Currently used adhesives generally use N-methylolacrylamide as a cross-linking monomer, but it requires high-temperature baking and also ...

Claims

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Application Information

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IPC IPC(8): D06P1/52C09J133/08C08F220/18C08F220/44C08F220/28C08F220/56C08F2/26C08F2/30C08J3/24C08G18/73C08G18/66C08G18/48C08G18/32
Inventor 李秀颖杨文堂郑文慧陈红梅
Owner LIAONING FIXED STAR FINE CHEM
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