Abietate alcohol ether type quaternary ammonium salt surface active agent and preparation method thereof

A technology of rosin ester alcohol ether and surfactant, which is applied in the field of functional green surfactant and its preparation, can solve the problem that surfactant is difficult to meet the needs of production and life, and achieve high added value, low product toxicity, Effect of Unique Chemical Structure

Inactive Publication Date: 2014-07-02
INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

A single type of surfactant is often difficult to meet the needs of production and life, and different types of surfactants are often required for compounding in applications

Method used

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  • Abietate alcohol ether type quaternary ammonium salt surface active agent and preparation method thereof
  • Abietate alcohol ether type quaternary ammonium salt surface active agent and preparation method thereof
  • Abietate alcohol ether type quaternary ammonium salt surface active agent and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021]

[0022] In the formula, the molecular weight n of polyethylene glycol PEG is any one of 200, 400, 600, 1000, 2000, 4000, and in the formula, R is methyl CH 3 , Ethyl CH 2 CH 3 , Ethanol CH 2 CH 2 Any one of OH.

[0023] Example 2

Embodiment 2

[0025] Weigh rosin and polyethylene glycol 400 with a molar ratio of 1:1 and pour them into a 500mL four-necked flask, and then add an appropriate amount of zinc oxide (the amount of zinc oxide accounts for about 0.1-0.2% of the mass of rosin) as a catalyst, Heat to 230-280°C to make it fully react, and when the acid value drops to about 10, the reaction is basically completed, then cool down.

[0026] Then take 0.1 mol of the above reaction product in a 250 mL dry three-necked flask, add 0.1 mol of epichlorohydrin, 0.12 mol of sodium hydroxide (added in 50% aqueous solution), 0.1% of rosin quality tetrabutylammonium bromide and dichloromethane solvent, warming up to 50°C, stirring for 4h, cooling to room temperature and suction filtration. The solid phase was washed twice with dichloromethane, distilled off dichloromethane and a small amount of unreacted epichlorohydrin (around 85°C) to obtain a rosin-based alcohol ether intermediate.

[0027] Add the intermediate synthesize...

Embodiment 3

[0032] Example 4

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Abstract

The invention discloses a rosin ester alcohol ether type quaternary ammonium salt surfactant. Its general structural formula is as follows: in the formula, the molecular weight n of polyethylene glycol PEG is any one of 200, 400, 600, 1000, 2000 and 4000 , where R is any one of methyl CH3, ethyl CH2CH3, ethanol CH2CH2OH. The invention also discloses the preparation method of the surfactant: adopting a one-pot method to prepare, first, rosin and polyethylene glycol are used for esterification to form rosin polyethylene glycol monoester, and the hydroxyl group in polyethylene glycol is passed through epichlorohydrin ether. quaternization, epoxy group and tertiary amine hydrochloride quaternization, obtain rosin ester alcohol ether quaternary ammonium salt type surfactant. The critical micelle concentration of the prepared surfactant is 0.1-0.3mmol / L; the range of surface tension is 37-39.5mN / m. The molecule contains non-ionic and cationic functional groups, and is a new type of functional green surfactant.

Description

technical field [0001] The invention relates to a functional green surfactant and a preparation method thereof, in particular to a rosin ester alcohol ether type quaternary ammonium salt surfactant and a preparation method thereof. Alcohol ether type quaternary ammonium salt cationic surfactant introduces ether bond and alcohol hydroxyl group on the basis of the original long-chain alkyl quaternary ammonium salt structure, so that the surfactant not only has softness, antistatic, emulsification, disinfection and sterilization, etc. In addition to performance, it also has the characteristics of high water solubility and high surface activity. Background technique [0002] Surfactants are composed of non-polar lipophilic hydrocarbon chains and polar hydrophilic groups, and have both lipophilic and hydrophilic amphoteric properties. The unique properties of surfactants make them widely used in various fields such as washing, textiles, medicine, food, and pesticides. At presen...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01F17/42B01F17/52B01F17/18C08G65/00C08G65/48C09K23/42C09K23/18C09K23/52
Inventor 饶小平郑建强宋湛谦商士斌
Owner INST OF CHEM IND OF FOREST PROD CHINESE ACAD OF FORESTRY
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