Compound modified water glass binder and preparation method thereof

A technology of composite modification and water glass, which is applied in the direction of manufacturing tools, casting molding equipment, metal processing equipment, etc., can solve the problems of high residual strength of water glass sand, poor collapsibility of water glass sand, and thickness of water glass bonding film, etc. Achieve the effects of improving surface stability and hygroscopicity, improving collapsibility, and reducing dosage

Inactive Publication Date: 2013-03-13
XI'AN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the existing water glass binder due to Na 2 The content of O ions is high. After the liquid metal is poured, a large part of the molding sand and water glass are heated to above 800°C. At this time, the water glass will become liquid, which will strongly erode the quartz sand. After cooling, the water glass and the quartz sand The formation of extremely hard sand blocks leads to high residual strength of water glass sand, poor collapsibility, that is, poor sand production, and difficulty in regeneration and reuse. These defects largely limit the application of water glass
[0003] From a chemical point of view, the main reason for the poor collapsibility of water glass sand is Na 2 The result of the action of O ions, that is, the water glass contain

Method used

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Examples

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Effect test

preparation example Construction

[0036] The preparation method of composite modified water glass binder specifically implements according to the following steps:

[0037] Step 1, preparation of water-soluble sodium polyacrylate resin aqueous solution:

[0038] Step 1.1, weigh the acrylic acid monomer and solid sodium hydroxide respectively according to the mass ratio of 1 to 8:1, mix the weighed acrylic acid monomer and solid sodium hydroxide together and stir continuously, so that the acrylic acid monomer and solid sodium hydroxide Sodium hydroxide is neutralized to obtain a sodium acrylate solution, and then the pH value of the sodium acrylate solution is adjusted to 7.0 to 11.0 with solid sodium hydroxide;

[0039] Step 1.2, weigh ammonium persulfate according to the sodium acrylate solution obtained in step 1.1, and the quality of ammonium persulfate is 5% to 15% of the quality of the sodium acrylate solution;

[0040] Step 1.3. Heat the sodium acrylate solution obtained in step 1.1 to 50°C to 95°C, then...

Embodiment 1

[0050] Weigh the monomeric acrylic acid and solid sodium hydroxide respectively according to the mass ratio of 3:1, mix the weighed monomeric acrylic acid and solid sodium hydroxide and keep stirring, so that the monomeric acrylic acid and solid sodium hydroxide are neutralized, Obtain monomeric sodium acrylate aqueous solution, the pH value of monomeric sodium acrylate aqueous solution is 7; Take ammonium persulfate according to the obtained sodium acrylate solution, the quality of ammonium persulfate is 5% of sodium acrylate solution quality; The solution is heated to 50°C, and then the weighed ammonium persulfate is poured into the sodium acrylate solution at 50°C to initiate the polymerization reaction of the sodium acrylate monomer. The polymerization reaction takes 0.5 hours to obtain a water-soluble Sodium polyacrylate resin aqueous solution;

[0051] Weigh 33.3% of water-soluble starch, 23.8% of dextrin, 4.76% of urea, 28.6% of sodium tripolyphosphate, and 9.54% of bor...

Embodiment 2

[0054] Weigh the monomeric acrylic acid and solid sodium hydroxide respectively according to the mass ratio of 4:1, mix the weighed monomeric acrylic acid and solid sodium hydroxide and keep stirring, so that the monomeric acrylic acid and solid sodium hydroxide are neutralized, Obtain monomeric sodium acrylate aqueous solution, the pH value of monomeric sodium acrylate aqueous solution is 9; Take ammonium persulfate according to the obtained sodium acrylate solution, the quality of ammonium persulfate is 10% of the quality of sodium acrylate solution; The solution was heated to 80°C, and then the weighed ammonium persulfate was poured into the sodium acrylate solution at 80°C to initiate the polymerization reaction of the sodium acrylate monomer. The polymerization reaction took 1.5 hours to obtain a water-soluble Sodium polyacrylate resin aqueous solution;

[0055] Weigh 33.3% of water-soluble starch, 23.8% of dextrin, 4.76% of urea, 28.6% of sodium tripolyphosphate, and 9.5...

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PUM

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Abstract

The invention discloses a compound modified water glass binder and a preparation method thereof. The compound modified water glass binder comprises the following effective components in percentage by mass: 10-25 percent of modifying agents and 75-90 percent of water glass; the modifying agents are prepared by the following components in percentage by mass: 33.3-36.6 percent of water-soluble starch, 23.8-24.4 percent of dextrin, 2.43-4.76 percent of urea, 24.4-28.6 percent of sodium tripolyphosphate and 9.52-12.2 percent of borax. The method for preparing the compound modified water glass binder comprises the following steps of: 1, preparing water-soluble sodium polyacrylate resin water solution; 2, weighing raw materials and preparing the modifying agent used by the compound modified water glass binder; and 3, weighing the modifying agent and the water glass to prepare the compound modified water glass binder. By the binder, the addition amount of the water glass in moulding sand is reduced, and the poured moulding sand easily scatters, so that the regeneration rate and the recycling rate of the water glass sand are improved, and the binding capability is improved.

Description

technical field [0001] The invention belongs to the technical field of preparation of molding sand for casting and molding sand binder, in particular relates to a composite modified water glass binder, and also relates to a preparation method of the above binder. Background technique [0002] Water glass, also known as sodium silicate aqueous solution, is an inorganic casting binder. Due to its low price, no smoke and black pollution in the metal casting process, it is one of the sand binders widely used in the production of steel castings. . But the existing water glass binder due to Na 2 The content of O ions is high. After the liquid metal is poured, a large part of the molding sand and water glass are heated to above 800°C. At this time, the water glass will become liquid, which will strongly erode the quartz sand. After cooling, the water glass and the quartz sand The formation of extremely hard sand blocks leads to high residual strength of water glass sand, poor col...

Claims

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Application Information

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IPC IPC(8): B22C1/18
Inventor 屈银虎梁涛王凤刘新峰
Owner XI'AN POLYTECHNIC UNIVERSITY
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