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Zinc oxide pressure-sensitive resistor and preparation method thereof

A piezoresistor and zinc oxide technology, which is applied in the direction of piezoresistor core, piezoresistor, and resistors with lead-outs, can solve the problem of uneven distribution of current density, easy burning of electrode layers, and easy detachment of electrode layers and other problems, to achieve the effect of good process consistency and repeatability, green and environmental protection in the preparation process, and low production cost

Active Publication Date: 2013-11-20
杭州比凡科电子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] 1. Since silver and zinc oxide ceramics are mismatched in terms of mechanical properties and electrical properties, it will cause two problems: first, the bonding force between the electrode layer and the zinc oxide varistor ceramic substrate is very poor, generally low For 15N, the electrode layer is easy to fall off during use, the reliability of the device is poor, and the service life is short; second, the ohmic contact resistance is large, generally greater than several ohms, and the heat generated when the surge current passes through such a large ohmic contact resistance It is also correspondingly large, and it is easy to burn the electrode layer
[0007] 2. Since the electrode lead wire is a straight wire, the current is mainly concentrated at the contact between the straight wire and the electrode layer, the current density distribution is extremely uneven, and the strong surge current can easily burn through the electrode layer locally, resulting in resistors permanent damage
[0008] 3. In order to prevent the electrode layer from being burned, the thickness of the silver electrode layer has to reach tens of microns or even hundreds of microns, which requires a large amount of expensive silver materials and high production costs
[0009] 4. The silk screen silver paste on the electrode layer needs to be sintered at a high temperature in a tunnel kiln, which consumes a lot of energy and will volatilize toxic substances such as lead oxide during the process, causing serious pollution and the product does not meet the RoHS standard

Method used

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  • Zinc oxide pressure-sensitive resistor and preparation method thereof
  • Zinc oxide pressure-sensitive resistor and preparation method thereof
  • Zinc oxide pressure-sensitive resistor and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0044] This example is a production process for preparing a three-layer film electrode layer by sputtering on the surface of a zinc oxide varistor ceramic substrate with a diameter of Ф10mm and a thickness of 2mm and a model of 10471K. The bottom transition layer is chromium, and the intermediate barrier layer is nickel copper. Alloy, the surface welding layer is silver.

[0045] Put the high-temperature sintered zinc oxide varistor ceramic substrate into a ball mill for rolling washing for 30 minutes, then ultrasonically clean it in tap water and deionized water for 20 minutes, and dry it in an oven at 120°C for 20 minutes; Put the cleaned and dried ceramic substrate into the special mask fixture, and then install the mask fixture on the workpiece holder; send the workpiece holder into the multi-target sputtering coating equipment, and vacuum the equipment cavity, Make the vacuum in the cavity reach 5×10 -3 Pa; fill the vacuum chamber with high-purity argon, and dynamically ...

Embodiment 2

[0048] This example is the production process of sputtering on the surface of a 14561K zinc oxide varistor ceramic substrate with a diameter of Ф14mm and a thickness of 2mm to prepare two layers of film electrode layers. The bottom transition layer is chromium and the surface welding layer is copper.

[0049] In this embodiment, except that there is no intermediate barrier layer and copper is used as the surface soldering layer, other process steps are the same as those in Embodiment 1, and will not be repeated here. The bottom transition layer in the two-layer film system electrode layer is made of chromium film with a thickness of 200nm, and the surface welding layer is made of copper with a thickness of 2800nm. After the sputtering is completed, an anti-oxidation process is carried out on the surface of the surface welding layer, and coil-like electrode leads are welded on the surface welding layer, and the performance is measured after packaging.

[0050] For zinc oxide va...

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Abstract

The invention discloses a zinc oxide pressure-sensitive resistor. The zinc oxide pressure-sensitive resistor comprises a zinc oxide pressure-sensitive ceramic substrate, electrode layers and electrode leads, wherein the electrode layers are arranged on the upper surface and the lower surface of the zinc oxide pressure-sensitive ceramic substrate respectively; the electrode leads are arranged on the electrode layers respectively. The zinc oxide pressure-sensitive resistor is characterized in that each electrode layer comprises a bottom transition layer which is used for improving bonding force between the zinc oxide pressure-sensitive ceramic substrate and the corresponding electrode layer and reducing contact resistance. Therefore, the electrode layers and the zinc oxide pressure-sensitive ceramic substrate are firmly bonded, and the self through-current capability of the electrode layers is improved. Furthermore, the curved electrode leads are capable of uniformly distributing current on the electrode layers. The surge impact resistance capacity of the zinc oxide pressure-sensitive resistor is improved. The whole preparation process has an environment protection effect, and can reduce over 45 percent of consumed energy and save over 60 percent of production costs compared with the prior art.

Description

technical field [0001] The invention relates to a zinc oxide varistor and a preparation method thereof. Background technique [0002] Zinc oxide varistors are based on zinc oxide powder, doped with metal oxides in different proportions and sintered into a ceramic substrate at high temperature, covered with an electrode layer on the surface of the ceramic substrate, and then welded electrode leads. Zinc oxide Varistors are widely used in various electronic instruments and power facilities because of their good voltage nonlinearity, low limit voltage, large surge resistance, and fast response. [0003] Zinc oxide varistors consist of three parts: a zinc oxide varistor ceramic substrate, an electrode layer arranged on the surface of the zinc oxide varistor ceramic substrate, and an electrode lead welded on the surface of the electrode layer. The electrode layer is used to communicate with the zinc oxide varistor The ceramic substrate produces ohmic contacts, and the electrode ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01C17/28H01C17/12H01C7/112
Inventor 金浩王德苗王文婷冯斌何梅
Owner 杭州比凡科电子科技有限公司
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