Waterborne polyurethane adhesive for synthetic leather and preparation method thereof
A water-based polyurethane and adhesive technology, used in polyurea/polyurethane adhesives, adhesive types, adhesives, etc., can solve the problems of high health hazards, environmental pollution, and wide use of production personnel and application personnel. , to achieve the effect of easy control of flatness, reduction of treatment costs, and low irritation
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[0049] Example 1
[0050] 1) Under argon atmosphere, 9.0kg of dicyclohexylmethane diisocyanate, 12kg of polytetrahydrofuran ether glycol and 0.005kg of phosphoric acid are reacted at 70°C for 1.5 hours in a reactor equipped with reflux condenser, thermometer and stirring, using HG / T2409-1992 standard detects isocyanate group content reduced to 2.0%;
[0051] 2) Cool down to 40℃, add 0.005kg stannous octoate, 0.8kg dimethylolpropionic acid, 0.03kg trimethylolpropane, 1.1kg trimethylolpropane polyoxypropylene polyoxyethylene ether, After 0.09kg of 1,6-hexanediol and 5kg of methyl acetate, the temperature is increased to 85°C, and the temperature is kept at 85°C to continue the reaction for 3 hours;
[0052] 3) Cool down to 50℃, add 0.03kg tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester, 0.02 kg methyl tin mercaptan, stir for 10 minutes, then Add 0.6kg of dimethylaminoethanol to the reaction kettle to neutralize the reaction solution, and continue t...
Example Embodiment
[0055] Example 2
[0056] 1) Under a nitrogen atmosphere, 9.6kg of dicyclohexylmethane diisocyanate, 18.2kg of polytetrahydrofuran ether glycol and 0.01kg of phosphoric acid were reacted at 90°C for 2 hours in a reactor equipped with reflux condenser, thermometer and stirring, using HG / T2409-1992 standard detects the isocyanate group content reduced to 1.5%;
[0057] 2) Cool down to 50℃, add 0.015kg stannous octoate, 1.5kg dimethylolpropionic acid, 0.08kg trimethylolpropane, 1.2kg trimethylolpropane polyoxypropylene polyoxyethylene ether, After 0.15 kg of 1,6-hexanediol and 9 kg of ethyl acetate, the temperature is increased to 80°C, and the reaction is kept at 80°C for 3.5 hours;
[0058] 3) Cool down to 40°C, add 0.08kg tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester, 0.03㎏ methyl tin mercaptan, stir for 15 minutes, then Add 1.0kg of dimethylaminoethanol to the reaction kettle to neutralize the reaction solution, and continue the reaction at 40...
Example Embodiment
[0061] Example 3
[0062] 1) Under argon atmosphere, 9.3kg of dicyclohexylmethane diisocyanate, 15.5kg of polytetrahydrofuran ether glycol and 0.008kg of phosphoric acid were reacted at 80℃ for 1.8 hours in a reactor equipped with reflux condenser, thermometer and stirring. HG / T2409-1992 standard detects that the content of isocyanate groups is reduced to 1.8%;
[0063] 2) Cool down to 45℃, add 0.007kg stannous octoate, 0.6kg dimethylolpropionic acid, 0.05kg trimethylolpropane, 0.7kg trimethylolpropane polyoxypropylene polyoxyethylene ether, After 0.1 kg of 1,6-hexanediol and 10 kg of propyl acetate, the temperature is increased to 80°C, and the reaction is continued for 3 hours while keeping the temperature at 80°C;
[0064] 3) Cool down to 45℃, add 0.06kg tetra[β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionic acid] pentaerythritol ester, 0.02 ㎏ methyl tin mercaptan, stir for 13 minutes, then Add 0.8kg of dimethylaminoethanol to the reaction kettle to neutralize the reaction solut...
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