Acid mine drainage OLWS method

A technology for acid mine wastewater and mine wastewater, applied in chemical instruments and methods, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc. problem, to achieve the effect of low maintenance cost, strong processing ability and long effect time

Active Publication Date: 2014-08-06
衢州绿怡环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the neutralization method is widely used in the treatment of AMD in my country as a simple and reliable method. Commonly used neutralization agents include limestone, calcium carbonate, calcium hydroxide, caustic soda, etc., but a large amount of sludge generated during the neutralization process ( Contains a large amount of heavy metals and toxic and harmful substances) is very likely to cause secondary pollution to the environment, and at the same time the operating cost and management cost are high; the sulfide precipitation method is to add sulfide reagents to the sewage to make the metal ions in the sewage form sulfide precipitation, Commonly used vulcanizing agents mainly include: sodium sulfide, sodium hydrogen sulfide, hydrogen sulfide, calcium sulfide, iron sulfide, etc. The sulfidation precipitation method has a high removal rate of heavy metal ions, strong adaptability to wastewater treatment, and is conducive to the recovery and utilization of heavy metals. , but the pH value is difficult to control, and the treatment cost is high. When the temperature control is not good, it is easy to produce hydrogen sulfide gas to pollute the air; the aeration oxidation filtration method has a good effect on removing heavy metals such as Fe and Mn in acid wastewater, but its treatment structure Many (requires pretreatment), high power consumption, high maintenance cost

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1: see figure 1 , firstly, the acid mine wastewater A is collected in the wastewater collection tank to ensure the stability of the subsequent process water; then, the acid mine wastewater A with a pH value of α=4.47 enters the natural In the oxidation system, a sulfuric acid-ferric sulfate solution is formed. At this time, the ambient temperature T0 of the natural oxidation system is T0=15°C, and the residence time of acidic mine wastewater in the natural oxidation system is t0=3d (days). The pH value of wastewater B is defined as β, where the β value needs to be determined according to the on-site detection, and the subsequent parameters are determined according to the detection value β; moreover, the acid mine wastewater B that has undergone the aforementioned treatment and has a pH value of β enters the filter containing calcium carbonate. The filter material neutralization system of the filter material increases the pH of the acid mine tailings water. Th...

Embodiment 2

[0027] Embodiment 2: First, the acid mine wastewater A is collected in the wastewater collection pond; then, the acid mine wastewater A with a pH value of α=5.37 enters the natural oxidation system in a quantitative manner (to prevent the impact of the excessive water volume on the treatment system, The oxidation system can adopt a number of water channels arranged at equal intervals, and the water inflow of each water channel also enters the acid mine wastewater A) in an equal flow manner to form a sulfuric acid / ferric sulfate solution. At this time, the ambient temperature of the natural oxidation system T0=25℃, acid The residence time of mine wastewater in the natural oxidation system is t0=0 hours (under the same temperature environment, the lower the pH value of acid mine wastewater A, the shorter the residence time in the oxidation system), the treated acid mine wastewater The pH value of B is defined as β, and β=4.92; moreover, the acid mine wastewater B with the pH valu...

Embodiment 3

[0028] Embodiment 3: This case is the acid mine wastewater treatment project in Shicheng Village, Yinkeng Township, Kaihua County. Using the acid mine wastewater OLWS method of the present invention, the values ​​measured by the Changshan County Monitoring Station are as follows in Table 3:

[0029] The ambient temperature T0 and T1 here are 25°C, the residence time t0 of the acid mine wastewater in the natural oxidation system is about 48 hours, and the residence time t1 of the acid mine wastewater B in the filter material and the system is about 3 hours.

[0030] table 3

[0031]

[0032] The raw water here is acid mine wastewater A; the effluent of the oxidation system is acid mine wastewater B; the effluent of the neutralization system is acid mine wastewater C; the total drainage is treated discharge water.

[0033] If the wastewater collection tank is in the open air, the rainwater will have a greater impact on the wastewater collection tank. At this time, the wastewa...

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Abstract

The invention discloses a coal mine drainage OLWS method. The method comprises the following steps: collecting mine drainage A in a drainage collecting pool; 2, adding a quantitative amount of the mine drainage A with the pH value of alpha to a natural oxidation system in order to form a sulfuric acid / ferric sulfate solution; 3, adding acid mine drainage B obtained in step 2 to a filter material neutralization system with a calcium carbonate-containing filter material as a main component in order to rise the pH value of acid mine tailing drainage; and 4, discharging mine drainage C obtained in step 3 into wetland, wherein a multi-matrix filler is placed in the wetland, and plants capable of easily absorbing the mine tailing drainage resistant component environment are planted, and the mine drainage C can effectively stay and can be adsorbed by the wetland. The method has the advantages of long action time, strong processing capability, high efficiency, convenient construction, low running cost and maintenance cost, and completely no power.

Description

technical field [0001] The invention relates to a mine wastewater OLWS method. Background technique [0002] Acid Mine Drainage (AMD) is caused by the oxidation of sulfide minerals and is closely related to the action of microorganisms. The sulfate content of AMD is high and the pH value is low, and the discharge of such wastewater is very serious to the destruction of the ecological environment. [0003] There are many ways to treat acid mine wastewater at home and abroad, which can be roughly divided into "active treatment" and "passive treatment" methods. Active treatment mainly includes neutralization method, sulfide precipitation method, aeration oxidation filtration method, etc. Among them, the neutralization method is widely used in the treatment of AMD in my country as a simple and reliable method. Commonly used neutralization agents include limestone, calcium carbonate, calcium hydroxide, caustic soda, etc., but a large amount of sludge generated during the neutra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/14
Inventor 成建家
Owner 衢州绿怡环保科技有限公司
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