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A kind of method that utilizes lead-zinc tailings to prepare inorganic mineral polymer

A technology of inorganic minerals and polymers, applied in the direction of cement production, etc., can solve problems such as difficult to use, tailings pollution, etc., and achieve the effects of improving activation degree, short calcination time and low calcination temperature

Inactive Publication Date: 2016-05-04
FUZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Aiming at problems such as tailings pollution and difficulty in utilization, the purpose of the present invention is to provide a method for preparing inorganic mineral polymers from lead-zinc tailings. The activity of the lead-zinc tailings is stimulated by activation treatment, and then a series of Inorganic mineral polymers are finally obtained after treatment, and the obtained inorganic mineral polymers have excellent qualities such as good durability, good sound insulation effect, and good heat insulation performance.

Method used

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  • A kind of method that utilizes lead-zinc tailings to prepare inorganic mineral polymer
  • A kind of method that utilizes lead-zinc tailings to prepare inorganic mineral polymer
  • A kind of method that utilizes lead-zinc tailings to prepare inorganic mineral polymer

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Embodiment 1

[0030] The lead-zinc tailings that the embodiment of the present invention adopts comes from Fujian Jindong mining industry, and main component is SiO 2 38.49%, Fe 2 o 3 19.86%, CaO14.51%, SO 3 12.62, Al 2 o 3 5.14%, MnO4.10%, MgO3.41%;

[0031] The metakaolin used in the embodiments of the present invention has a whiteness value of 90-95%, a loss on ignition <0.25%, a pH value of 6-7, a water content of ≤0.3%, and a residue of 325 mesh <0.4%;

[0032] The modulus of the sodium silicate solution that the embodiment of the present invention adopts is 2.8, Na 2 O content is 11.6%, SiO 2 The content is 39.8%;

[0033] The NaOH used in the embodiments of the present invention is an analytically pure reagent, a white flaky solid with a solid content of not less than 96%;

[0034] The main equipment used in the embodiment of the present invention is a high-temperature resistance furnace, an electric blast drying oven, an electronic hydraulic pressure testing machine, an elec...

Embodiment 2

[0045] The inorganic mineral polymer prepared in Example 1 is mixed with 2.25g sodium lauryl sulfate and 1g stearic acid, poured into the test mold immediately, the mixture expands immediately, and the expansion ends within 10 minutes, followed by exotherm after 25 minutes The reaction starts to harden, and it is formed after 60 minutes. After 24 hours, it is demoulded, and then put into a curing box for curing. After 28 days, it is taken out to obtain a foamed inorganic mineral polymer test piece.

[0046] After testing, the strength of the foamed inorganic mineral polymer test block in this embodiment can reach up to 3.5MPa, and the thermal conductivity can reach 0.056w / m·k. The foamed inorganic mineral polymer test piece of this example was dried at 100°C for 1 hour, and the test piece was intact; then the test piece was calcined at 500°C and 1000°C for 2 hours, although a little Cracking, volume shrinkage and mass change rate are larger than those at 500°C, but there is no...

Embodiment 3

[0048] The inorganic mineral polymer prepared in Example 1 is mixed with 22.5g of hydrogen peroxide, 2g of polyvinyl alcohol and 6g of deionized water and then poured into the test mold. After expansion molding, the mold is demoulded in 24 hours, and then put into the curing box for curing. After 28 days Take out and obtain the foamed inorganic mineral polymer test block.

[0049] The foaming principle of hydrogen peroxide is as follows:

[0050] 2H 2 o 2 ﹦2H 2 O+O 2 ↑;

[0051] Polyvinyl alcohol can act as a surfactant in the system, which can make the gas produced by hydrogen peroxide better contact the slurry and maintain a good pore structure; the water flux of the porous material prepared without deionized water is 0, judging that hydrogen peroxide can only form independent closed pores, and adding deionized water can create small interconnected pores connecting these closed pores, and the size of the pores can be adjusted by adjusting the amount of deionized water a...

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Abstract

The invention discloses a method for preparing inorganic mineral polymers by using lead-zinc tailings. The lead-zinc tailings are activated by wet alkali calcining, metakaolin and sand are added for stirring, and alkali activators are added to carry out inorganic polymerization reaction. , forming an inorganic mineral polymer with a network structure, and the obtained inorganic mineral polymer can be further prepared into a foaming inorganic mineral polymer by adding a foaming agent and a foam stabilizer. The finished product has good durability and good high-temperature insulation, and will not release toxic substances even if it is exposed to flames. It can be used for backfilling, sealing and building materials after mining, and can not only effectively solve the problem of lead-zinc Tailings accumulation problem, reducing environmental pollution, also opened up a new path for the development and utilization of waste lead-zinc tailings resources in my country, and provided a new exploration direction for related research on tailings reuse. Waste and the creation of an environment-friendly society are of great significance.

Description

technical field [0001] The invention belongs to the field of resource recycling, and in particular relates to a method for preparing inorganic mineral polymers from lead-zinc tailings. Background technique [0002] The development of mineral resources plays an important role in the country's economic construction, but it also brings serious negative effects to the environment. For example, a large amount of solid waste such as tailings and waste rocks generated in mine development occupies land, pollutes, destroys ecological environment, causing various geological disasters. But from another point of view, tailings still contain a large number of useful components, which have high utilization value, but have not been well utilized due to technical limitations. Therefore, the rational use of tailings resources is of great significance to the sustainable development of our country. [0003] The domestic use of lead-zinc tailings is mainly to use tailings as raw materials for...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/147
CPCY02P40/10
Inventor 印万忠曹阳王少怀
Owner FUZHOU UNIV
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