Electrolyte as well as preparation method thereof and lithium sulfur battery

Abstract

The invention provides electrolyte as well as a preparation method thereof and a lithium sulfur battery prepared by the electrolyte. The electrolyte comprises electrolyte lithium salt, a non-aqueous organic solvent and ion liquid containing ether-base functional groups. The ion liquid containing the ether-base functional groups is used as a solvent, so that the vapor pressure of the electrolyte can be remarkably reduced, the flame resistance of the electrolyte is improved, and the solubility and the degree of dissociation of lithium salt in the electrolyte can be improved in the presence of the ether-base functional groups.

Description

technical field [0001] The invention relates to the field of preparation of lithium battery electrode materials, in particular to an electrolytic solution and a preparation method thereof, and a lithium-sulfur battery prepared by using the electrolytic solution. Background technique [0002] With the rapid development of compact portable electronic devices and power batteries, the demand for high energy density batteries is increasing. Elemental sulfur has a high theoretical specific capacity (1675mAh / g) and specific energy (2600Wh / kg), which is more than five times the theoretical energy density of traditional lithium-ion batteries. The actual energy density of lithium-sulfur batteries currently developed is 400~ 600Wh / kg, which is 2 to 3 times the actual energy density of commercial lithium-ion batteries. Elemental sulfur as a cathode material also has the advantages of abundant natural reserves, low price, and environmental friendliness. [0003] The lithium-sulfur batt...

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Problems solved by technology

[0003] The lithium-sulfur battery system is also the focus of extensive research in the current academic circles. It is generally believed that the main problems of lithium-sulfur batteries are: 1) The electronic conductivity of elemental sulfur is low

2) The S generated during charging and discharging x n- Anion has a strong nucleophilic ability, and it is compatible with carbonate, LiPF 6 There are interactions between solvents or electrolyte materials, so traditional lithium-ion battery electrolytes are not suitable for lithium-sulfur battery systems. 3) Polysulfides (Li 2 S x ) (x=4~8) will gradually dissolve into the electrolyte and shuttle between the positive and negative electrodes, resulting in the loss of positive active materials, and this is also an important factor for the low coulombic efficiency and fast capacity decay of lithium-sulfur batteries

4) Using metal lithium as the negative electrode, there is a problem of lithium dendrites in the long cycle process

It has also been reported that the selection of solid-state electrolytes can partially inhibit the generation of dendrites (X.Liang, et al., Journal of Power Sources, 2011, 196, 3655), but the conductivity of organic all-solid-state electrolytes is low, resulting in the battery's low temperature at room temperature. Difficult to charge and discharge with high current

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