Manufacturing method of polyurethane pur elastomer and foamed damping ring buffer ring of automobile parts
A manufacturing method and polyurethane technology, applied in the field of polyurethane PUR new materials, can solve the problems of poor dynamic fatigue resistance, high and low temperature resistance, poor bearing capacity, etc., and achieve the effect of strong compactness, strong dynamic fatigue resistance, and improved bearing capacity.
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Embodiment 1
[0060] The manufacture method of polyurethane PUR elastomer, carries out as follows.
[0061] (1) The polymerization reaction manufacturing of elastomer prepolymers has the following three situations.
[0062] (1) Use polyether polyol or polyester polyol or polycarbonate polyol or polycaprolactone polyol
[0063] Polymerize with NDI at 70°C~145°C for 3~5 hours to form NDI polymer prepolymer, in which -NCO group content satisfies: 1%≤-NCO group content≤9%; the preferred temperature is: 70°C~85 °C, 85°C~105°C, 105°C~120°C or 120°C~145°C; the preferred time is 0.1-5 hours.
[0064] (2) Polyether polyol or polyester polyol or polycarbonate polyol or polycaprolactone polyol
[0065] Polymerize with MDI at 70°C~130°C for 3~5 hours to form MDI polymer prepolymer, in which -NCO group content meets: 1%≤-NCO group content≤9%; the preferred temperature is: 70°C, 83°C , 91°C, 109°C or 130°C; the preferred time is 4 hours.
[0066] (3) Polyether polyol or polyester polyol or polycarbon...
Embodiment 2
[0080] The manufacturing method of the polyurethane PUR auto parts foaming damping ring buffer ring is carried out according to the following steps.
[0081] (1) The polymerization reaction manufacturing of polyurethane PUR microcellular foaming prepolymer has the following three situations:
[0082] (1) Polyether polyol or polyester polyol or polycarbonate polyol or polycaprolactone polyol
[0083]Polymerize with NDI at 50°C~145°C for 0.1~5 hours to form NDI polymer prepolymer, in which -NCO group content satisfies: 11%≤-NCO group content≤50%; the preferred temperature is: 80°C, 95°C °C, 100 °C, 115 °C or 128 °C; the preferred time is 1-3 hours.
[0084] (2) Polyether polyol or polyester polyol or polycarbonate polyol or polycaprolactone polyol
[0085] Polymerize with MDI at 55°C~130°C for 1~5 hours to form MDI polymer prepolymer, in which -NCO group content satisfies: 11%≤-NCO group content≤50%; the preferred temperature is: 80°C, 90 °C, 100 °C, 105 °C, 110 °C, or 119 °C...
Embodiment 3
[0101] The manufacturing method of the polyurethane PUR auto parts foaming damping ring buffer ring is carried out according to the following steps.
[0102] (1) Preparation of polymeric prepolymer: polymerizing isocyanate and polyol to prepare polymeric prepolymer;
[0103] The isocyanate is naphthalene-1,5 diisocyanate (NDI), diphenylmethane 4,4'-diisocyanate (MDI), toluene diisocyanate (TDI), xylylene diisocyanate (XDI), formaldehyde Cyclohexyl diisocyanate (HTDI), dimethyl biphenyl 3,3′-p-phenylene diisocyanate (PPDI), isophorone diisocyanate (IPDI), polymethylene polyphenyl polyisocyanate (PAPI), 1,6-hexylene diisocyanate (HDI) is any one, two or more of the nine materials mixed.
[0104] The polyol is made of polyurethane polyol and polyether polyol; polycarbonate diol (PCD), polypropylene glycol (PPG), polyethylene adipate propylene glycol ester diol (PEPA), polytetramethylene Ether diol, polyethylene adipate diol (PEA), ethylene glycol (EDO), 1,6-hexanediol (HDO), po...
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