Efficient flocculating agent for rapidly removing heavy metals in water

A technology for removing water and heavy metals, applied in the direction of flocculation/sedimentation water/sewage treatment, water/sewage treatment, biological water/sewage treatment, etc. It can solve the problems of slow flocculation and sedimentation, air pollution, narrow application range, etc., and achieve concentration Easy dehydration, high degree of water purification, high removal effect

Active Publication Date: 2015-01-07
佑景天(北京)国际水环境研究中心有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditional flocculants mainly include low-molecular flocculants such as aluminum salts and iron salts, which have the disadvantages of slow flocculation and sedimentation, loose and easily broken flocs, and high chemical consumption; high-molecular flocculants such as basic polyaluminum chloride ( PAC), polyaluminum chloride, polyferric sulfate, etc., have high cost, narrow scope of application, and are easily affected by water temperature and pH value; polydimethyldiallylammonium chloride such as polyacrylamide flocculant, etc. It has strong neurotoxicity and certain carcinogenicity. When a large amount of polyacrylamide is used to treat wastewater, it will produce polymer residues, destroy the biological chain of water body, and then affect human health.
At the same time, the sludge produced by traditional flocculants is unstable and easy to dissolve heavy metals. Not only will dioxins be produced during sludge combustion, but it will also cause new pollution to the atmosphere due to the unstable heavy metal fly ash.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Preparation of flocculant

[0032] 1) Take 100kg of Hangjin 2# soil, add 5kg of soil bacteria and 15kg of activated carbon to it, mix well, and prepare mixture A;

[0033] 2) Take 10 kg of iron oxide, 10 kg of ferric chloride, 20 kg of polyaluminum chloride, 2.5 kg of organic flocculant (polydimethyldiallyl ammonium chloride), 25 kg of cement and 16 kg of sodium thiosulfate, mix Uniform, prepared as mixture B;

[0034] 3) Mix mixture A and mixture B evenly to prepare the flocculant.

[0035] (2) Control experiment on the removal of hexavalent chromium in water

[0036] The raw water is industrial sewage, and the concentration of hexavalent chromium in the raw water is 2.5mg / L. Under the condition of sufficient stirring, add 5wt% (mass ratio of flocculant to raw water, the same below) of the above prepared Flocculant and conventional flocculant PAC, after conventional mixing, flocculation, sedimentation and filtration, according to the detection method specified i...

Embodiment 2

[0038] (1) Preparation of flocculant

[0039] 1) Take 100kg of Hangjin 2# soil, add 8kg of soil bacteria and 20kg of activated carbon to it, mix well, and prepare mixture A;

[0040] 2) Take 15kg of iron oxide, 15kg of ferric chloride, 35kg of polyaluminum chloride, 4kg of organic flocculant (polydimethyldiallyl ammonium chloride), 35kg of cement and 24kg of sodium thiosulfate, mix well, and prepare into mixture B;

[0041] 3) Mix mixture A and mixture B evenly to prepare the flocculant.

[0042] (2) Control experiment on the removal of hexavalent chromium in water

[0043] The raw water is industrial sewage, and the concentration of hexavalent chromium in the raw water is 2.5mg / L. Under the condition of sufficient stirring, add the above-mentioned flocculant and conventional flocculant PAC of 4wt% to the above-mentioned sewage, through conventional mixing, flocculation, After precipitation and filtration, according to the detection method specified in GB 8978-1996, the con...

Embodiment 3

[0045] (1) Preparation of flocculant

[0046] 1) Take 100kg of Hangjin 2# soil, add 5kg of soil bacteria and 25kg of activated carbon to it, mix well, and prepare mixture A;

[0047] 2) Take 10kg of iron oxide, 20kg of ferric chloride, 20kg of polyaluminum chloride, 2.5kg of organic flocculant (polydimethyldiallyl ammonium chloride), 25kg of cement and 16kg of sodium thiosulfate, mix well, Formulated into mixture B;

[0048] 3) Mix mixture A and mixture B evenly to prepare the flocculant.

[0049] (2) Control experiment of lead removal in water

[0050] The raw water is industrial sewage, and the concentration of lead in the raw water is 2.0mg / L. Under the condition of sufficient stirring, add 6wt% of the above-mentioned flocculant and conventional flocculant PAC to the above-mentioned sewage respectively, and through conventional mixing, flocculation and precipitation After filtration, according to the detection method stipulated in GB 8978-1996, the concentrations of lead...

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Abstract

The invention relates to an efficient flocculating agent for rapidly removing heavy metals in water. The efficient flocculating agent comprises a mixture A and a mixture B, wherein the mixture A comprises the following components in parts by mass: 100 parts of No.2 Hangjin soil, 5-10 parts of soil bacteria and 15-25 parts of activated carbon; and the mixture B comprises the following components in parts by mass: 10-20 parts of iron oxide, 10-20 parts of iron chloride, 20-50 parts of poly-aluminum chloride, 2.5-5 parts of an organic flocculating agent, 25-50 parts of cement and 16-32 parts of sodium thiosulfate. The efficient flocculating agent disclosed by the invention can be used for rapidly and effectively removing a variety of heavy metals such as mercury, lead, chromium, cadmium, arsenic and copper in the water, is short in reaction time, cannot cause secondary pollution, can be directly fed without early dissolution, is simple in use method, and can be widely applied to removal of the heavy metals in various industrial wastewater, polluted underground water, lakes, rivers and reservoirs.

Description

technical field [0001] The invention relates to a high-efficiency water treatment flocculant used for industrial waste water, polluted ground water, lakes, rivers and reservoirs. Background technique [0002] The problem of heavy metal pollution in China's waters is very serious, and the pollution rate of the bottom of rivers, lakes and reservoirs is as high as 80.1%. In the basins of the ten major river basins including the Yellow River, Huaihe River, Songhua River, and Liaohe River, the pollution degree of heavy metal-exceeding sections is all Class V; the total Cu, total Pb, and total Cd contents in the bottom sediment of Taihu Lake are all at the light pollution level; the main stream of the Huangpu River In surface sediments, Cd exceeded the background value by 2 times, and Pb exceeded the limit by 1 time; in Suzhou Creek, all Pb exceeded the standard, 75% of Cd exceeded the standard, and 62.5% of Hg exceeded the standard. In 35.11% of urban river sections, the total H...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/52C02F1/62C02F1/72C02F1/70C02F1/28
CPCC02F3/34C02F2103/007C02F2103/06
Inventor 董志刚张伟锋席北斗赵颖刘文芳李晓光郭祎阁彭星
Owner 佑景天(北京)国际水环境研究中心有限公司
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