Special low-temperature cured body powder coating for aluminum wheel of automobile and preparation method thereof
A powder coating, low temperature technology, used in powder coatings, anti-corrosion coatings, polyester coatings, etc., can solve the problems of temperature sensitivity, easy agglomeration, poor leveling, etc., to improve corrosion resistance and improve compactness. Effect
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Embodiment 1
[0080] Present embodiment adopts the carboxyl polyester resin that resin adopts acid number 65~75mgKOH / g, and its preparation method is as follows:
[0081] 1) In the reactor, add 13kg neopentyl glycol, 2kg1,4-cyclohexanedimethanol, 0.5kg trimethylolpropane, 1kg 1,4-cyclohexanedimethanol and 3kg water in a fixed ratio, Heat until melted.
[0082] 2) Add 26kg of terephthalic acid, 11.5kg of isophthalic acid, 0.6kg of adipic acid and 0.1kg of dibutyltin oxide in sequence, and continue to heat up to 175°C with nitrogen gas.
[0083] 3) The temperature is heated from 175°C to 250°C until the acid value reaches 12-29mgKOH / g, and the first time vacuumizes for polycondensation reaction, the acid value reaches 5-16mgKOH / g, the softening point is 100-105°C and the melt at 200°C When the viscosity is 3000-4000mpa.s, add 3kg of terephthalic acid or adipic acid for acid hydrolysis reaction. When the acid value reaches 70-80mgKOH / g, continue the acid hydrolysis reaction by vacuuming for t...
Embodiment 2
[0100] The polyester resin of the present embodiment adopts the 65~75KOH / kg carboxyl polyester resin of embodiment 1.
[0101] The powder coating for automotive aluminum wheels suitable for bonding of balance weights, its components and weight ratio are as follows:
[0102] 35 parts of low-temperature curing polyester resin with an acid value of 65-75 mgKOH / g
[0103] 35 parts of epoxy resin with an epoxy equivalent of 720-850g / ep
[0104] Carboxyl-terminated polyester compound latent accelerator 2 parts
[0105] Surfactant 2 parts
[0106] Auxiliary 5 parts
[0107] Filling 20 parts
[0108] 1 part of paint.
[0109] The additives are leveling agent, benzoin and amino-modified phenol urea compound. The filler is titanium dioxide and barium sulfate. The pigments are weather-resistant inorganic pigments, such as one or more of iron black, carbon black, chrome yellow, iron red, titanium blue, titanium blue, ultramarine blue, titanium green, etc.
[0110] Preparation:
...
Embodiment 3
[0117] Present embodiment adopts the carboxyl polyester resin that resin adopts acid value 50~64mgKOH / g, and its preparation method is as follows:
[0118] 1) In the reactor, add 0.5kg1,3-propanediol, 0.3kg diethylene glycol, 14kg neopentyl glycol, 0.2kg trimethylolpropane, 2.0kg1,4-cyclohexanedimethanol and 4.0kg water, Heat until melted.
[0119] 2) Add 32kg of terephthalic acid, 10kg of isophthalic acid, 1.0kg of maleic anhydride and 0.5kg of dibutyltin oxide in sequence, and continue to heat up to 175°C with nitrogen gas.
[0120] 3) The temperature is heated from 175°C to 250°C until the acid value reaches 16-25mgKOH / g, and the first time vacuumizes for polycondensation reaction, the acid value reaches 6-14mgKOH / g, the softening point is 100-105°C and the melt at 200°C When the viscosity is 3000-4000mpa.s, add 3kg of terephthalic acid or maleic anhydride for acid hydrolysis reaction. When the acid value reaches 55-70mgKOH / g, continue the acid hydrolysis reaction by vacuu...
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