Organic electroluminescent device and preparation method thereof

An electroluminescent device and luminescence technology, which is applied in the direction of organic light-emitting devices, organic light-emitting device structures, organic semiconductor devices, etc., can solve the problems of organic layer damage, low luminous efficiency, easy quenching, etc.

Inactive Publication Date: 2015-04-15
OCEANS KING LIGHTING SCI&TECH CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The cathode of traditional organic electroluminescent devices is generally made of silver (Ag), gold (Au) and other metals. After preparation, the cathode is very easy to penetrate into the organic layer, causing damage to the organic layer, and the electrons are easily quenched near the cathode, so that the luminous efficiency lower

Method used

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  • Organic electroluminescent device and preparation method thereof
  • Organic electroluminescent device and preparation method thereof
  • Organic electroluminescent device and preparation method thereof

Examples

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preparation example Construction

[0034] The preparation method of the organic electroluminescence device 100 of an embodiment, it comprises the following steps:

[0035] Step S110 , sequentially forming a hole injection layer 20 , a hole transport layer 30 , a light emitting layer 40 , an electron transport layer 50 and an electron injection layer 60 on the surface of the anode 10 .

[0036] The anode 10 is indium tin oxide glass (ITO), fluorine-doped tin oxide glass (FTO), aluminum-doped zinc oxide glass (AZO) or indium-doped zinc oxide glass (IZO), preferably ITO.

[0037] In this embodiment, before the hole injection layer 20 is formed on the surface of the anode 10, the anode 10 is pretreated. The pretreatment includes: performing photolithography on the anode 10, cutting it into the required size, using detergent, deionized Water, acetone, ethanol, and isopropanone were each ultrasonically cleaned for 15 minutes to remove organic pollutants on the surface of the anode 10 .

[0038] The hole injection la...

Embodiment 1

[0053] The structure prepared in this example is ITO / WO3 / NPB / Alq 3 / Bphen / LiF / ZnS:Ag / TAZ:TiO 2 / ITO organic electroluminescent device, in this embodiment and the following embodiments, " / " indicates a layer, and ":" indicates doping.

[0054] First, carry out photolithography treatment on ITO, cut it into the required size, and then use detergent, deionized water, acetone, ethanol, and isopropanol to sonicate for 15 minutes each to remove organic pollutants on the glass surface; clean the conductive substrate Carry out suitable treatment: oxygen plasma treatment, treatment time is 5min, power is 30W; evaporation hole injection layer, material is WO 3 , with a thickness of 60nm; evaporated hole transport layer, made of NPB, with a thickness of 30nm; evaporated luminescent layer, made of BCzVBi, with a thickness of 30nm; evaporated electron transport layer, made of Bphen, with a thickness of 50nm; evaporated electron Injection layer, material is LiF, thickness is 0.7nm; Evapo...

Embodiment 2

[0062] The structure prepared in this example is AZO / MoO 3 / TCTA / ADN / Bphen / CsF / CdS:Al / OXD-7:TiO 2 / AZO's organic electroluminescent devices.

[0063] First, use detergent, deionized water, and ultrasonication on the AZO glass substrate for 15 minutes to remove organic pollutants on the glass surface; evaporate the hole injection layer: the material is MoO 3 , with a thickness of 80nm; evaporated hole transport layer: the material is TCTA, with a thickness of 60nm; evaporated luminescent layer: the selected material is ADN, with a thickness of 5nm; evaporated electron transport layer, the material is Bphen, with a thickness of 200nm; evaporated The electron injection layer is plated, the material is CsF, and the thickness is 10nm; the vapor deposition cathode is vapor-deposited on the surface of the electron injection layer by thermal resistance evaporation to prepare a metal sulfide doped layer, and the material is CdS:Al, CdS and Al The mass ratio is 5:1, the thickness is 1...

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Abstract

The invention provides an organic electroluminescent device. The organic electroluminescent device comprises an anode, a cavity implantation layer, a cavity transmission layer, a luminescent layer, an electron transmission layer, an electron injecting layer and a cathode which are successively stacked. A cathode layer is composed of a metal sulfide doping layer, an organic electron transmission layer and a film material layer. The material of the metal sulfide doping layer comprises metal sulfide and metal doped in the metal sulfide. An organic electron transmission doping layer comprises an organic electron transmission material and titanium dioxide doped in the organic electron transmission material. The material of the organic electron transmission doping layer is selected from at least one from 2,2'-(1,3-pheyl)bis[5-(4- tert-butyl phenyl)-1,3,4-oxadiazol], 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline and 2,8-bis(diphenylphosphinoxy) dibenzo[b,d] thiophene. The material of the film material layer is selected from at least one from an indium tin oxide target material, an aluminum zinc oxide target material and an indium zinc oxide target material.

Description

technical field [0001] The invention relates to an organic electroluminescence device and a preparation method thereof. Background technique [0002] The luminescence principle of organic electroluminescent devices is based on the action of an external electric field, electrons are injected from the cathode to the lowest unoccupied molecular orbital (LUMO) of organic matter, and holes are injected from the anode to the highest occupied molecular orbital (HOMO) of organic matter. Electrons and holes meet, recombine, and form excitons in the light-emitting layer. Excitons migrate under the action of an electric field, transfer energy to the light-emitting material, and excite electrons to transition from the ground state to the excited state. The excited state energy is deactivated by radiation to generate photons , releasing light energy. [0003] The cathodes of traditional organic electroluminescent devices are generally silver (Ag), gold (Au) and other metals. After prepa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/52H01L51/54H01L51/56
CPCH10K85/60H10K50/826H10K50/82H10K2102/00H10K2102/302H10K71/00
Inventor 周明杰黄辉张娟娟王平
Owner OCEANS KING LIGHTING SCI&TECH CO LTD
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