Reverse osmosis membrane scale inhibitor and application thereof

A technology of reverse osmosis membrane and scale inhibitor, applied in the field of reverse osmosis membrane scale inhibitor, can solve the problem that the scale inhibition efficiency of the agent cannot reach the scale inhibition level of the imported reverse osmosis membrane scale inhibitor, the scale inhibitor is expensive, and the scale inhibitor The problem of low performance is to achieve the effect of strengthening the sterilization and algae killing performance, maintaining the drug effect for a long time, and not easy to gel

Inactive Publication Date: 2015-12-09
SHANDONG TIANQING TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the scale inhibitors used by various manufacturers are imported from abroad, such as Qingli PTP-0100 from the United States and Bedi MDC220 from the United States. These scale inhibitors are expensive and the treatment costs are relatively high.
Although there are many varieties of antiscalants for reverse osmosis membranes in China, the scale inhibition performance of the products is not high, and the scale inhibition efficiency of the agents cannot reach the scale inhibition level of imported antiscalants for reverse osmosis membranes.

Method used

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  • Reverse osmosis membrane scale inhibitor and application thereof
  • Reverse osmosis membrane scale inhibitor and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A reverse osmosis membrane scale inhibitor, consisting of the following components, polyamino polyether tetramethylene phosphonic acid 13%, polymaleic anhydride copolymer 26%, aminopropanesulfonic acid-acrylic acid copolymer 19%, four 2% of hydroxymethylphosphonium sulfate, 0.3% of dithiocyanomethane, and the rest is deionized water. The preparation method is to mix the polyamino polyether group tetramethylene phosphonic acid, polymaleic anhydride, aminopropanesulfonic acid-acrylic acid copolymer, tetrakis phosphonium sulfate, dithiocyanomethane and deionized water at room temperature Add it into the container and stir evenly to obtain the product.

Embodiment 2

[0024] A reverse osmosis membrane antiscalant, consisting of the following components: 15% diethylene triamine pentamethylene phosphonic acid, 25% acrylic anhydride-acrylamide copolymer, itaconic acid-sodium propylene sulfonate copolymer Compound 20%, Tetradecyltributylphosphonium Chloride 1%, Dithiocyanomethane 0.2%, and the rest is deionized water. The preparation method is to combine diethylene triamine pentamethylene phosphonic acid, acrylic anhydride-acrylamide copolymer, itaconic acid-sodium propylene sulfonate copolymer, tetradecyl tributyl phosphonium chloride, disulfide Cyanomethane and deionized water are added into the container at room temperature and stirred evenly to obtain the product.

Embodiment 3

[0026] A reverse osmosis membrane antiscalant, consisting of the following components, diethylenetriaminepentamethylenephosphonic acid 10%, epoxy succinic acid 35%, polystyrene sulfonate 10%, dodecyl tributyl 2% phosphonium chloride, 0.2% dithiocyanomethane, and the rest is deionized water. The preparation method is to mix diethylene triamine pentamethylene phosphonic acid, epoxy succinic acid, polystyrene sulfonate, dodecyl tributyl phosphonium chloride, dithiocyanomethane and deionized water at room temperature Add it into the container and stir evenly to obtain the product.

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Abstract

The invention provides a reverse osmosis membrane scale inhibitor. The reverse osmosis membrane scale inhibitor mainly comprises organic phosphonic acid, organic carboxylic polymers, sulfonic copolymers, a quaternary phosphonium salt, and methane dithiocyanate. The invention further provides an application of the reverse osmosis membrane scale inhibitor in scale inhibition of a reverse osmosis system. When used for reverse osmosis water treatment, the reverse osmosis membrane scale inhibitor provided by the invention can effectively eliminate membrane pollution caused by deposition of CaCO3, CaSO4, SiO2 and silicate; working efficiency of the reverse osmosis system is improved, service lives of the reverse osmosis membrane and reverse osmosis equipment are prolonged, and reverse osmosis cost is reduced; the reverse osmosis membrane scale inhibitor is compatible with various common flocculating agents such as polyaluminum chloride and cationic polyacrylamide; and a pH value is not required to regulate.

Description

technical field [0001] The invention relates to the field of chemical industry, in particular to a reverse osmosis membrane scale inhibitor and its application. Background technique [0002] The development and application of membrane separation technology has solved high-quality separation problems for many industries, such as pure water production, seawater desalination, brackish water desalination, electronics industry, pharmaceutical and bioengineering, environmental protection, food, chemical, textile and other industries. , Concentration and purification issues, and provide the supporting technology for circular economy and clean production. [0003] Reverse osmosis technology is an important part of membrane separation technology. Membrane separation technology can remove a large number of impurities in water, such as inorganic substances, organic substances, colloids, metal ions, etc., because of its high water quality, low operating cost, no pollution, and easy oper...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D65/08C02F1/44
Inventor 胡新霞王俊明梁清雷黄凯王金明刘文峰高云峰苗吉宾张少尉郑萍
Owner SHANDONG TIANQING TECH DEV
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