Cryopreservation solution as well as preparation method and application thereof
A technology for cryopreservation of liquid and cells, applied in the field of cryopreservation and cryopreservation of biological materials
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Embodiment 1
[0045] Preparation of Graphene Oxide
[0046] 1. Pre-oxidized graphite
[0047] Weigh 2.5g of phosphorus pentoxide and 2.5g of potassium persulfate, and add them into a 250mL Erlenmeyer flask. Add 20mL of concentrated sulfuric acid under constant stirring, heat to 80°C, slowly add 3g of graphite powder to the solution, keep the temperature of the solution at 80°C for 4.5h, then cool to room temperature. Then slowly add deionized water. During this process, ensure that the temperature of the solution does not exceed 80°C. The mixture is allowed to stand overnight, filtered to remove excess concentrated sulfuric acid, and dried at 60°C.
[0048] 2. Preparation of graphite oxide
[0049] Add the dried pre-oxidized graphite into 120mL of concentrated sulfuric acid, and slowly add 15g of potassium permanganate while stirring continuously. This process is carried out in an ice bath, and the temperature of the whole process is guaranteed to be below 80°C, and the stirring is contin...
Embodiment 2
[0055] Preparation of cryopreservation solution of the present invention
[0056] 1. Weigh 0.5g glucose, 9g lactose, 0.3g raffinose, 1.1g 4-hydroxyethylpiperazineethanesulfonic acid, 1.2gNaH 2 PO 4 2H 2 O, 1.6gNa 2 HPO 4 2H 2 O, 1.5g of sodium chloride, 3g of potassium chloride, 0.02g of magnesium sulfate, 0.07g of calcium chloride, and 0.6g of casein were added to 1L of deionized water, fully mixed and dissolved, and stored in a thermostat at 37°C. spare. For the convenience described in the following examples, the cryopreservation solution prepared in this step is referred to as cryopreservation solution A for short.
[0057] 2. Preparation of cryopreservation solution containing graphene oxide
[0058] Weigh a certain amount of graphene oxide prepared in Example 1, physically crush it in an ultra-clean room, grind it into a fine powder in an agate mortar, 100W ultrasonic 30min, and disperse it in the cryopreservation solution A prepared in the first step, so that Th...
Embodiment 3
[0062] Inhibitory effect of different samples on ice crystal growth
[0063] The method reported in the literature (DellerRC, VatishM, MitchellDA, et al. Synthetic polymer senable non-vitreous cellular cryopreservation by reducing ice crystal growth during thawing [J]. Naturecommunications, 2014, 5.) was used to evaluate the inhibitory effect of different samples on the growth of ice crystals in a low temperature environment.
[0064] 1. Sample preparation: select 0.7% physiological saline, the cryopreservation solution A (without graphene oxide) of Example 2 of the present invention, 20% glycerin, and a commercially available graphene oxide aqueous dispersion (Sigma-AldrichCo.LLC.763713 , the size distribution of its graphene oxide is 200nm-12μm, 2~3 layers, C / O is 1.9) and the graphene oxide aqueous dispersion prepared in embodiment 1 (two kinds of aqueous dispersion concentrations of graphene oxide are set Concentrations of 0.01%, 0.1% and 0.5% by mass percentage). At the ...
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