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Boiler waste water treatment agent based on graphene modified polyaspartic acid and preparation method

A technology of polyaspartic acid and wastewater treatment agent, which is applied in the direction of adsorption water/sewage treatment, chemical instruments and methods, and other chemical processes. It can solve the problems of poor comprehensive performance, unsatisfactory effect, and single functional group. The manufacturing process is simple, the cost is low, and the effect of efficient adsorption

Active Publication Date: 2016-01-20
安徽精高水处理有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] As a polymer scale and corrosion inhibitor that can be completely degraded and harmless to the environment, polyaspartic acid has a strong chelating and extraction ability for heavy metals. In recent years, it has been widely used in domestic and foreign medicine, health, and industrial and agriculture and other fields, but polyaspartic acid in CaCO 3 , Ca 3 (PO 4 ) 2 and dispersed iron oxide and stabilized Zn 2+ The effect of salt is not ideal, and its functional group is also relatively single, resulting in poor overall performance when used as a water treatment agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A boiler wastewater treatment agent based on graphene-modified polyaspartic acid, the composition comprises raw materials by the following weight (kg): polyaspartic acid 20, sodium gluconate 2, citric acid 2, polyammonium salt Lignin flocculant 50, graphene 10, alkaline trehalose 2, sodium bentonite 20, salicylic acid 4, sepiolite powder 20, cross-linked rectorite powder 10, starch xanthate 3, aminotrimethylene phosphonic acid 2. Potassium sulfate polysilicate 1, dimethyl diallyl ammonium chloride 1, appropriate amount of deionized water, appropriate amount of water.

[0018] A preparation method of a boiler wastewater treatment agent based on graphene modified polyaspartic acid, comprising the following steps:

[0019] (1) Mix polyaspartic acid, graphene, and 2.5 times the total weight of deionized water, use a high-pressure homogenizer to process for 2.5 hours, and use spray drying technology to dry graphene grafted modified polyaspartic acid compound powder spare; ...

Embodiment 2

[0025] A kind of boiler wastewater treatment agent based on graphene modified polyaspartic acid, its composition comprises the raw material by following weight (kg): polyaspartic acid 25, sodium gluconate 2.5, citric acid 2.5, polyammonium Salt lignin flocculant 45, graphene 9, alkaline trehalose 3, sodium bentonite 25, salicylic acid 5, sepiolite powder 25, cross-linked rectorite powder 12, starch xanthate 4, amino trimethylene phosphine Acid 3, polysilicate potassium sulfate 2, dimethyl diallyl ammonium chloride 2, appropriate amount of deionized water, appropriate amount of water.

[0026] A preparation method of a boiler wastewater treatment agent based on graphene modified polyaspartic acid, comprising the following steps:

[0027] (1) Mix polyaspartic acid, graphene and 3 times the total weight of deionized water, use a high-pressure homogenizer to process for 3 hours, and use spray drying technology to dry graphene grafted modified polyaspartic acid composite powder sp...

Embodiment 3

[0033] A boiler wastewater treatment agent based on graphene-modified polyaspartic acid, the composition comprises raw materials by the following weight (kg): polyaspartic acid 30, sodium gluconate 3, citric acid 2, polyammonium salt Lignin flocculant 40, graphene 8, alkaline trehalose 4, sodium bentonite 30, salicylic acid 6, sepiolite powder 30, cross-linked rectorite powder 14, starch xanthate 5, aminotrimethylene phosphonic acid 4. Potassium sulfate polysilicate 3. Dimethyl diallyl ammonium chloride 3. Appropriate amount of deionized water and appropriate amount of water.

[0034] A preparation method of a boiler wastewater treatment agent based on graphene modified polyaspartic acid, comprising the following steps:

[0035] (1) Mix polyaspartic acid, graphene and 3 times the total weight of deionized water, use a high-pressure homogenizer to process for 3 hours, and use spray drying technology to dry graphene grafted modified polyaspartic acid composite powder spare;

...

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Abstract

The invention discloses a boiler waste water treatment agent based on graphene modified polyaspartic acid and a preparation method. A composition of the agent is prepared from, by weight, 20-30 parts of polyaspartic acid, 2-3 parts of sodium gluconate, 2-3 parts of citric acid, 40-50 parts of poly-ammonium salt lignin flocculating agents, 20-30 parts of sodium bentonite, 8-10 parts of graphene, 4-6 parts of salicylic acid, 2-4 parts of alkaline trehalose, 20-30 parts of sepiolite powder, 10-14 parts of crosslinked rectorite powder, 3-5 parts of starch xanthate, 2-4 parts of amino tri-methylene phosphonic acid, 1-3 parts of polymerized potassium silicate sulfate, 1-3 parts of dimethyl diallyl ammonium chloride, an appropraite amount of deionized water and an appropriate amount of water. According to the boiler waste water treatment agent and the preparation method, graphene is adopted for modifying polyaspartic acid and improving dispersity of the polyaspartic acid for CaCO<3>, Ca<3>(PO<4>)<2>, dispersed ferric oxide, stable Zn<2+> salt and the like; meanwhile, efficient adsorption is achieved by adding the sodium bentonite, the sepiolite powder and the crosslinked rectorite powder, the boiler waste water treatment agent is low in cost and simple in preparation process, hollow porous particles are obtained, recovery is facilitated, and adsorption efficiency is improved.

Description

technical field [0001] The invention belongs to the field of water treatment preparations, and in particular relates to a graphene-modified polyaspartic acid-based boiler wastewater treatment agent and a preparation method. Background technique [0002] With the increase of energy demand, relying on boilers and coal is still the main way for the power industry to obtain energy. The boilers used for power generation in the power industry will generate a large amount of wastewater during operation, which will cause harm to the boiler itself and also cause damage to the environment. Pollution; the harm to itself is reflected in the formation of scale in the boiler sewage, which in turn corrodes the boiler. How to prevent the harm of boiler waste water to itself and the pollution of the environment is an important topic of environmental protection in the current power industry. [0003] As a polymer scale and corrosion inhibitor that can be completely degraded and harmless to th...

Claims

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Application Information

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IPC IPC(8): B01J20/26B01J20/30C02F1/28
Inventor 徐享
Owner 安徽精高水处理有限公司
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