A method for synthesizing high-strength polyaryl ether sulfone resin by adding chain extender in the middle section
A technology of polyaryl ether sulfone and chain extender, which is applied in the field of polymer materials, can solve the problems of difficulty in increasing molecular weight, shortening the service life of plastics, and large loss of sulfolane recovery rate, and achieves shortened reaction time, easy processing and molding, and simplified synthesis. The effect of craftsmanship
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Embodiment 1
[0033]In a 300L stainless steel reaction kettle equipped with a nitrogen pipe, a condensing water separator and a high-efficiency stirrer, first add 85.00KG sulfolane, then start stirring and raise the temperature to 80°C, and then add 36.0KG 4,4′-dichlorodiphenylsulfone in sequence , 23.0KG 4,4′-biphenyldiphenol, after the monomers are completely dissolved, add 15.0KG sodium carbonate to the system when the temperature rises to 110°C, then add 65.0 liters of tetramethylbenzene, and continue stirring to raise the temperature to 200°C, The salt-forming reaction starts, the water generated in the system azeotropes with tetramethylbenzene, cooling water begins to drip from the condenser tube, and the layers are separated in the water separator. After the upper layer of tetramethylbenzene changes from turbid to clear, continue to reflux for another 20 minutes In order to ensure the completion of the salt-forming reaction, the salt-forming stage is 1.2 hours, and the solid content o...
Embodiment 2
[0036] Same as Example 1, except that the amount of sulfolane is 70.0KG and 64.0 liters of mesitylene, add 40.04g of titanium tetrachloride after constant temperature for 1. to 2.0 hours, and continue to react for 35 minutes to obtain a set viscosity polymerization mucus, a system in the polymerization reaction stage The solid content is 42%, and other conditions are the same.
[0037] The obtained PPSU resin melt index MI=28.5g / 10min (365.0°C, 5KG).
Embodiment 3
[0039] Same as Example 1, except that the dosage of sulfolane is 65.0KG and 60.0 liters of m-trimethylbenzene, add 60.04g of dimethyldichlorosilane after constant temperature for 1.0 to 2.0 hours, and continue to react for 40 minutes to obtain a set viscosity polymerization mucus. The solid content of the system is 38%, and other conditions are the same.
[0040] The obtained PPSU resin melt index MI=23.8g / 10min (365.0°C, 5KG).
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