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A kind of extraction method of microalgae oil

An extraction method and a technology for microalgae oil, which are applied in the directions of oil/fat production, fat production, etc., can solve problems such as limited effect of alcohol dissolution, and achieve the effects of lightening load, high yield and simple operation process

Active Publication Date: 2019-09-10
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this method, a short-chain alcohol solvent is added after the microalgae are subjected to microwave treatment to destroy the cells. Although the short-chain alcohol solvent has a certain dissolution effect on the cell membrane phospholipid layer after the cell destruction, the effect of alcohol dissolution is limited, and the short-chain alcohol Mainly involved in base-catalyzed reactions

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The microalgae is chlorella vulgaris, which was cultured in a 10L photobioreactor for 10 days. At the end of the culture, the concentration of algae cells was analyzed to be 1.82g / L (dry weight basis). Take 5L of the microalgae liquid and carry out centrifugation, control the centrifugal rotation speed to 4000 rpm, and centrifuge for 3 minutes to obtain the microalgae mud. Add 0.03mol / L Na to the microalgae mud 2 CO 3 solution 45ml and 10% sodium hydroxide solution 45ml. The above system was heated to 60 ºC while stirring, and kept for 100 min to break the cells and saponify the oil. Then use a membrane with a pore size of 10 -1 μm microfiltration membrane to remove algae cells and debris. Continue to add 1mol / L Na to the liquid system 2 CO 3 Solution 90ml, make fatty acid salt precipitate, filter and collect solid; Dissolve fatty acid salt solid in a small amount of water, add hydrochloric acid solution and acidify to pH 2.0, obtain free fatty acid; Centrifuge th...

Embodiment 2

[0028] The microalgae is botrytis, which was cultured in a 10L photobioreactor for 10 days. At the end of the culture, the concentration of algae cells was analyzed to be 1.78g / L (dry weight basis). Take 5L of microalgae liquid for centrifugation, control the centrifugation speed to 4000rpm, and centrifuge for 5 minutes to obtain microalgae mud, dry and grind the microalgae mud to obtain 8.9g of microalgae powder. Add 0.02mol / L NaNO to the microalgae powder 3 Solution 58ml and 30% sodium hydroxide solution 29ml. The above system was heated to 70 ºC while stirring, and kept for 120 min to carry out cell disruption and oil saponification. Then use a membrane with a pore size of 10 -1 μm microfiltration membrane to remove algae cells and debris. Continue to add 1.5 mol / L NaNO to the liquid system 3 Solution 45ml, make fatty acid salt precipitate, filter and collect solid; Dissolve fatty acid salt solid in a small amount of water, add hydrochloric acid solution and acidify to ...

Embodiment 3

[0030] The microalgae is botrytis, which was cultured in a 10L photobioreactor for 10 days. At the end of the culture, the concentration of algae cells was analyzed to be 1.92g / L (dry weight basis). Take 5L of microalgae liquid for centrifugation, control the centrifugation speed to 4000rpm, and centrifuge for 5 minutes to obtain microalgae mud, dry and grind the microalgae mud to obtain 9.6g of microalgae powder. Add 0.03mol / L of KH to the microalgae powder 2 PO 4 solution 40ml and 10% potassium hydroxide solution 40ml. The above system was heated to 50 ºC while stirring, and kept for 120 min to carry out cell disruption and oil saponification. Then use a membrane with a pore size of 10 -1 μm microfiltration membrane to remove algae cells and debris. Continue to add 1.5mol / L of KH to the liquid system 2 PO 4 Solution 48ml, make fatty acid salt precipitate, filter and collect solid; Dissolve fatty acid salt solid in a small amount of water, add hydrochloric acid solution...

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Abstract

The invention discloses a method for extracting microalgae grease. The method includes the steps: (1) adding an inorganic salt solution with a certain concentration and an alkali solution with a certain concentration into collected microalgae, stirring and heating, and dissolving and crushing cell walls by using the alkali and salt synergistic effect; (2) continuing to carry out a saponification reaction of fatty acid ester released from the interiors of cells with an alkali, to generate fatty acid salt; (3) removing algae cell debris; (4) continuing to add the inorganic salt solution to the system, precipitating the fatty acid salt, and filtering and collecting a solid; and (5) adding an inorganic acid to the fatty acid salt, acidifying to obtain free fatty acid, and collecting the product fatty acid. The microalgae grease is extracted by adopting an aqueous phase method, and the method has the advantages of simple operation process, high yield of the microalgae grease, environmental friendliness and the like.

Description

technical field [0001] The invention relates to a method for extracting microalgae oil, in particular to a method for extracting microalgae oil by using an aqueous phase method. Background technique [0002] Microalgae are a class of lower plants that grow in water and are diverse and widely distributed. This type of organism has an efficient photosynthetic reaction system, which can 2 Light energy is converted into chemical energy and stored in the body cells in the form of organic matter such as oil or starch. With the pressure of shortage of resources in human society and the increasingly serious environmental problems, the development of biodiesel and some fossil energy substitutes using microalgae has become a research hotspot. [0003] The use of microalgae for biodiesel production is a complex system engineering, covering multiple technical links, including screening and cultivation of microalgae species, large-scale cultivation of microalgae and induction of oil pr...

Claims

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Application Information

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IPC IPC(8): C11B1/00C11B1/04
Inventor 李晓姝高大成张霖廖莎孙启梅
Owner CHINA PETROLEUM & CHEM CORP