Inferior coal catalysis sulphur-fixing agent used in cement industry and preparing and using methods thereof

A technology for cement industry and sulfur-fixing agent, applied in chemical instruments and methods, physical/chemical process catalysts, petroleum industry, etc., can solve problems such as inability to adapt to the combustion characteristics of pulverized coal, unfavorable cement production and performance, and utilization in the cement industry, etc. Achieve the effect of saving coal consumption, reducing sulfide emissions and reducing ignition temperature

Inactive Publication Date: 2016-06-22
TIANJIN CEMENT IND DESIGN & RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to improve the combustion status of low-quality coal and reduce the emission of sulfide, some research work has been carried out on the research and use of coal-fired combustion accelerants at home and abroad, but most of them are aimed at the efficient utilization of coal in power plants or industrial boilers. Of course, due to the production principle and Due to the difference in the process, on the one hand, the combustion aids used in production cannot meet the needs of the combustion characteristics of pulverized coal in the new dry process;

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] A low-quality coal catalytic sulfur-fixing agent used in the cement industry, which uses potassium perchlorate as an oxygen-increasing agent, uses sodium chloride as a bulking agent, and uses Tween as a dispersant, and is composed of calcium carbonate, iron oxide, boron oxide and rare earth tailings Catalyst, and the mass percent of each component in this catalytic sulfur-fixing agent is: 32% of oxygen increasing agent, 15% of bulking agent, dispersant 5%, catalyzer 48%; Wherein, the mass percent of each component in the catalyzer is: 18% calcium carbonate, 6% iron oxide, 1% boron oxide, 75% rare earth tailings; the composition and mass percentage of rare earth tailings are: 5% cerium dioxide, 10% lanthanum oxide, 75% neodymium oxide, nitric acid Cerium 10%.

[0014] The preparation method of above-mentioned cement industry inferior coal catalytic sulfur-fixing agent is:

[0015] Mix oxygenate, leavening agent, dispersant and catalyst according to the above mass percen...

Embodiment 2

[0018] A low-quality coal catalytic sulfur-fixing agent used in the cement industry, which uses potassium perchlorate as an oxygen-increasing agent, uses sodium chloride as a bulking agent, and uses Tween as a dispersant, and is composed of calcium carbonate, iron oxide, boron oxide and rare earth tailings Catalyst, and the mass percent of each component in this catalytic sulfur-fixing agent is: 30% of oxygen increasing agent, 17% of leavening agent, dispersant 4%, catalyzer 49%; Wherein, the mass percent of each component in the catalyzer is: Calcium carbonate 13%, iron oxide 17%, boron oxide 2%, rare earth tailings 68%; the components and mass percentages of rare earth tailings are: cerium dioxide 12%, lanthanum oxide 21%, neodymium oxide 55%, nitric acid Cerium 12%.

[0019] The preparation method of above-mentioned cement industry inferior coal catalytic sulfur-fixing agent is:

[0020] Mix oxygenate, bulking agent, dispersant and catalyst according to the above mass perc...

Embodiment 3

[0023] A low-quality coal catalytic sulfur-fixing agent used in the cement industry, which uses potassium perchlorate as an oxygen-increasing agent, uses sodium chloride as a bulking agent, and uses Tween as a dispersant, and is composed of calcium carbonate, iron oxide, boron oxide and rare earth tailings Catalyst, and the mass percent of each component in this catalytic sulfur-fixing agent is: 31% of oxygen increasing agent, 16% of bulking agent, dispersant 5%, catalyzer 48%; Wherein, the mass percent of each component in the catalyzer is: 15% calcium carbonate, 7% iron oxide, 1% boron oxide, 77% rare earth tailings; the composition and mass percentage of rare earth tailings are: 7% cerium dioxide, 22% lanthanum oxide, 65% neodymium oxide, nitric acid Cerium 6%.

[0024] The preparation method of above-mentioned cement industry inferior coal catalytic sulfur-fixing agent is:

[0025] Mix oxygenate, leavening agent, dispersant and catalyst according to the above mass percent...

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PUM

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Abstract

The invention discloses an inferior coal catalysis sulphur-fixing agent used in the cement industry. Potassium perchlorate, sodium chloride and tween are used as oxygenate, a bulking agent and a dispersing agent respectively, and a catalyst is prepared from 10-18% of calcium carbonate, 6-17% of ferric oxide, 1-2% of boric oxide and 68-83% of rare earth tailings. The catalysis sulphur-fixing agent is prepared from, by mass, 30-36% of the oxygenate, 8-17% of the bulking agent, 2-5% of the dispersing agent and 48-55% of the catalyst, wherein the rare earth tailings are prepared from, by mass, 5-12% of ceric oxide, 10-22% of lanthanum oxide, 55-75% of neodymium oxide and 5-12% of cerous nitrate. The invention further discloses preparing and using methods of the catalysis sulphur-fixing agent. The catalysis sulphur-fixing agent can promote coal powder combustion and reduce emission of sulfide and has no negative effect on performance of cement clinker.

Description

technical field [0001] The invention belongs to the field of inorganic non-metallic materials, and in particular relates to a low-quality coal catalytic sulfur-fixing agent for cement industry and its preparation and use method. Background technique [0002] The main fuel used in the production of cement industry is coal. With the increasing shortage of high-quality bituminous coal and the increasing price of coal, the cement industry is developing towards the direction of using inferior fuel. However, the use of low-quality coal in cement production will deteriorate the combustion characteristics, increase energy consumption, affect clinker calcination, and ultimately affect product quality. To make low-quality coal meet the requirements of cement production, the combustion characteristics of low-quality coal must be improved. [0003] In addition, some low-quality coal will produce a large amount of sulfide during the combustion process, resulting in SO in the cement kiln...

Claims

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Application Information

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IPC IPC(8): C10L9/10C10L10/00B01J27/232
CPCC10L9/10B01J27/232C10L10/00C10L2230/22C10L2290/24
Inventor 刘瑞芝孙于龙赵艳妍陶从喜
Owner TIANJIN CEMENT IND DESIGN & RES INST
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