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A kind of electrolyte containing novel lithium borate and battery using the lithium salt

A technology of lithium borate and electrolyte, which is applied in the field of electrolyte containing new lithium borate, can solve the problems of increased internal resistance of the battery, and achieve the effects of low internal resistance growth rate, good cycle performance and capacity recovery rate

Inactive Publication Date: 2018-05-04
SUN YAT SEN UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, excessive use of sulfonate additives in the electrolyte often leads to an increase in the internal resistance of the battery, which has a greater negative impact on the rate-type battery

Method used

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  • A kind of electrolyte containing novel lithium borate and battery using the lithium salt
  • A kind of electrolyte containing novel lithium borate and battery using the lithium salt
  • A kind of electrolyte containing novel lithium borate and battery using the lithium salt

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Preparation of electrolyte

[0023] in an argon atmosphere glove box (H 2 O6 (1.0M) mixing, adding 1% of the total mass of vinylene carbonate (VC), 2% of fluoroethylene carbonate (FEC), 1.5% of succinonitrile (SN), 0.5% of lithium ethanesulfonic acid borate . Stir well and evenly to obtain the lithium secondary battery electrolyte (free acid<15ppm, moisture<10ppm) of the present invention.

[0024] (3) Preparation of positive pole piece

[0025] Dissolve 3% polyvinylidene fluoride (PVDF) in 1-methyl-2-pyrrolidone solution, 94% LiCoO 2 and 3% conductive agent carbon black were added to the above solution and mixed evenly, and the mixed slurry was coated on both sides of the aluminum foil, dried and rolled to obtain a positive electrode sheet.

[0026] (4) Preparation of negative pole piece

[0027] Dissolve SBR binder with a mass percentage of 4%, CMC thickener with a mass percentage of 1% in an aqueous solution, add graphite with a mass percentage of 95% to the...

Embodiment 2-8

[0033] Except the parameters in the following table, other parameters and preparation method are the same as in Example 2.

Embodiment 3-8

[0035]

[0036]

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PUM

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Abstract

The invention discloses an electrolyte containing novel lithium borate and a battery with lithium salt. The electrolyte containing novel lithium borate comprises electrolyte lithium salt, novel lithium borate, a non-aqueous organic solvent and an additive. The structural formula of the novel lithium borate contains sulfonate groups, the electrolyte is good in high-temperature property as the novel lithium borate containing the sulfonate groups is used, and meanwhile, the internal resistance of the battery is not increased by the additive, therefore, the lithium ion battery is relatively good in property.

Description

technical field [0001] The invention relates to the field of lithium ion batteries, in particular to an electrolyte solution containing novel lithium borate and a battery using the lithium salt. Background technique [0002] Lithium secondary batteries have the advantages of high working voltage, high specific energy density, long cycle life, low self-discharge rate, no memory effect, and low environmental pollution. Ideal power source for power tools. At present, in the technical market, the negative electrode materials are mainly monopolized by graphite negative electrodes. The electrolyte generally adopts a mixed cyclic and linear carbonate system to take into account properties such as viscosity, solubility, and electrical conductivity, and various functional additives to meet the needs of lithium batteries. Comprehensive performance of ion batteries. [0003] Functional additives include film-forming additives, anti-overcharge additives, stabilizers, flame retardant a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M10/0566H01M10/0525
CPCH01M10/0525H01M10/0566H01M2220/20H01M2220/30H01M2300/0025Y02E60/10
Inventor 韩鸿波孟跃中覃旭松陈国华
Owner SUN YAT SEN UNIV