Shape memory intrinsic type self-repairing material as well as preparation method and application thereof
A self-healing material and intrinsic type technology, applied in the field of intelligent polymer materials, can solve problems such as the depletion of repairing agent, and achieve the effect of high repair rate, simple repair process, and high repair efficiency
Active Publication Date: 2016-07-27
SUN YAT SEN UNIV
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Abstract
The invention provides a shape memory intrinsic type self-repairing material which is prepared from the following components: a crystal polyether or polyester diol monomer, a diisocyanate monomer, a monomer containing a dynamic covalent bond micromolecule chain extender, a rubber elastic body, a free radical polymeric ultraviolet light initiator, a multi-sulfydryl curing agent and conductive packing. If the shape memory intrinsic type self-repairing material is suffered from mechanical damage, a conductive path consisting of internal conductive packing is damaged, the resistance of the material is increased, under the action of external current, temperature rise can be resulted from the Joule heating effect of the material self, a reversible shape memory effect of the material can be excited, cracks of the material can be shrunk and closed, meanwhile after macroscopic cracking closure, the dynamic covalent bonds inside the material can recombine the material as molecular chains of a fracture surface are diffused with one another and subjected to reversible chemical reaction, at the moment, paths of the conductive packing in the material can be recovered, the resistance of the material can be reduced to an original level, the Joule heating effect can be eliminated, the temperature can be reduced to the room temperature, and the self-repairing process has the characteristics of reversibility and repeatability.
Technology Topic
Self-healing materialChemistry +14
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