81 results about "Self-healing material" patented technology

A crosslinked polyethylene cable is widely applied to a modern power grid, but in the manufacturing and laying process, certain microdefects are inevitably caused in the cable, the cable is corroded by power frequency voltage and different substances in soil during operation, and the microdefects are eroded by water to gradually induce water branch defects. Some water branches grow along the direction of the electric field force and gradually derive into electric branches under the action of overvoltage, and finally the cable insulation layer is broken down. An existing microcapsule type self-repairing material is limited by a triggering mode, is single in function and harsh in triggering condition, cannot perform self-repairing on various defects such as mechanical damage, electric tree branches, water tree branches and micropores, and only can perform single-time repairing, namely, the problems that multiple-time repairing cannot be performed, the repairing efficiency is low and the like exist. Therefore, it is necessary to develop a microcapsule / crosslinked polyethylene composite insulating material with multiple and multiple self-repairing capabilities, and a method for fundamentally exploring and prolonging the service life of the insulating material is provided.

The modified bentonite-cement-based concrete self-repairing material comprises the following components in parts by weight: 20-30 parts of modified bentonite, 15-30 parts of cement and 50-80 parts of water, the mass ratio of the modified bentonite to the cement is 0.8-1, and the water-solid mass ratio is (0.5-2): 1. The concrete self-repairing material comprises bacillus mycoides and bacillus cereus which are screened from a landfill, the bacillus mycoides and the bacillus cereus serve as nucleation sites of calcium carbonate precipitation and are used in cooperation with a nutrient solution and chitosan, the speed of the strains for utilizing the mineralization effect at cracks is increased, calcite is accelerated to be generated and deposited along the surfaces of the cracks, and the effect of calcium carbonate precipitation on the surfaces of the cracks is improved. And a good repairing effect is achieved on the cracks of the barrier material. The repairing material is applied to a landfill site, has the effects of seepage prevention, sun crack resistance and erosion resistance, and realizes effective control of pollutants.

The invention discloses an edge calculation optimization and compression algorithm based on distributed optical fiber sensing data, and the algorithm achieves the full-section continuous monitoring of an embankment through the layering burying of a distributed optical fiber network along the axis of the embankment, and eliminates the blind area of a conventional point sensor. Strain data and temperature data are analyzed by using Brillouin scattering and Raman scattering, time sequence characteristics are analyzed through an LSTM neural network, and piping and crack hidden dangers are identified. External environment parameters such as water level and rainfall are fused to construct a multiple regression model, and the seepage risk level is evaluated. Through combination of BIM three-dimensional modeling and a seepage simulation algorithm, hidden dangers are accurately positioned, and spatial distribution of the hidden dangers is visualized. Based on edge calculation optimization, a data compression technology is adopted to reduce transmission requirements, a self-repairing material injection and high-pressure plugging scheme is triggered through a grading early warning system, closed-loop management from monitoring to repairing is formed, the real-time performance and accuracy of hidden danger recognition are improved, and efficient and reliable monitoring support is provided for dike engineering.

The invention relates to an intelligent permeation grouting process and device for concrete crack self-repairing. The intelligent permeation grouting process and device are suitable for crack detection and repairing of a newly-built concrete structure. The device comprises a blood vessel network embedded into concrete, a crack detection sensor, a control module, a pumping module and a self-repairing material storage module, and automatic detection and repairing of cracks are achieved. The technological process comprises crack detection, data analysis, grouting parameter determination, material injection and repair monitoring. Through the automation and intelligence technology, the repairing efficiency and precision are remarkably improved, and the device is suitable for large structures such as bridges and tunnels.

The invention belongs to the technical field of ocean engineering materials, and particularly relates to an underwater concrete self-repairing material containing dynamic disulfide bonds as well as a preparation method and application of the underwater concrete self-repairing material. The underwater concrete self-repairing material containing the dynamic disulfide bond comprises the following components in parts by weight: 50-70 parts of a hardening agent which is an epoxy prepolymer containing the dynamic disulfide bond; the water repellent agent comprises 20-35 parts of a curing agent and 1-3 parts of an accelerant. According to the underwater concrete self-repairing material containing the dynamic disulfide bonds, the epoxy prepolymer containing the dynamic disulfide bonds serves as a main network, the epoxy prepolymer is broken under the action of external force, and then new covalent bonds can be formed through spontaneous recombination to repair microcracks.

The invention discloses a marine concrete self-repairing material which is of a microcapsule structure and comprises a repairing core material and an environment triggering response wall material wrapping the repairing core material. In parts by weight, the weight ratio of the repairing core material to the environment triggering response wall material is (3-5): (1-2); the environment triggering response wall material is prepared from a water swelling material; the repairing core material comprises a material which generates an expansive hydration product when encountering water. When the concrete system has cracks, the environment-triggered response wall material absorbs water, swells and breaks; and water molecules enter the surface of the repairing core material to react to generate an expansive hydration product, so that the environment-triggered response wall material is further broken due to volume expansion of the repairing core material. After the repairing core material is released, an expansion reaction can be quickly generated, micro-cracks in the concrete are repaired in real time, and the penetration resistance of the concrete is improved.

The present invention discloses a bio-based coating material with super mechanical properties and self-repairing modification and a preparation method thereof, and belongs to the technical field of controlled release fertilizer production. The bio-based coating material of the present invention is made of the following raw materials in parts by weight: 100-120 parts of coating liquid matrix, 0.5-1 parts of toughening agent, and 5-10 parts of self-repairing material. The present invention uses livestock farm waste as the raw material for making coated controlled release fertilizer membrane shell, which reduces costs and promotes the recycling and reuse of waste. By introducing metal ions into the covalent network, the stability of the network and the mobility of covalent bonds and hydrogen bonds are improved, the metal ions and the toughening agent undergo complexation reaction, and the presence of multiple complex molecules promotes the dissipation of energy when the covalent bonds are broken and reorganized, giving the coating super mechanical properties and the ability to continuously self-repair damaged areas at room temperature, effectively solving the problem of poor elasticity and easy damage of the membrane shell of the bio-based slow-release fertilizer, which is of great significance for improving the quality and utilization rate of slow-release fertilizers.

The invention discloses a self-repairing material for electronic device packaging and a preparation method and a packaging method thereof, and belongs to the technical field of electronic device packaging. The self-repairing material comprises the following components: a dynamic reversible chemical bond network formed by a DA bond prepolymer and a hydrogen bond donor in a synergistic manner, boron nitride nanosheets and carbon quantum dots, adding boron nitride nanosheets and carbon quantum dots into the DA bond prepolymer, and fully dispersing; then adding a hydrogen bond donor, and fully stirring to obtain a self-repairing material; spraying a self-repairing material on the surface of the substrate to form a thick packaging layer, curing to form a three-dimensional interpenetrating network structure, and packaging the electronic device; according to the invention, the packaging layer has a rapid self-repairing capability and supports efficient repair; the material has high thermal conductivity, mechanical strength and thermal expansion matching with an LED chip; the self-repairing process does not need high temperature or complex equipment, and is compatible with the existing packaging production line.

The invention relates to the field of ecological materials, and discloses a corrosion-resistant ecological slope protection vegetation concrete and a preparation method thereof.According to the concrete, low-heat slag cement, metakaolin, silica fume and an active admixture are synergistically optimized, and a reinforcing agent, a self-repairing material and vegetation function optimization components are combined; the chlorine salt corrosion resistance, the crack resistance and the vegetation ability of the material are improved. By adopting a multi-scale pore optimization technology, reasonable distribution of micropores, mesopores and macropores is realized, and the strength and vegetation stability of the concrete are improved. By introducing materials such as microcapsule coated calcium carbonate, cracks are automatically healed, and the service life of the material is prolonged. Meanwhile, environment-friendly materials such as fly ash and biochar are utilized, so that carbon emission and cost are reduced. The composite material has corrosion resistance, ecological property and environmental protection property, and is suitable for engineering protection and ecological restoration in a complex marine environment.

The invention belongs to the technical field of coal mine machinery, and particularly relates to a self-repairing mining vertical chain connecting ring and a manufacturing method thereof.The chain connecting ring takes 23MnNiMoCr54 alloy steel as a base material and is made of a steel billet added with self-repairing material components; the self-repairing material comprises nano-particles, shape memory alloy particles and a catalyst. According to the mining vertical chain connecting ring, the self-repairing material is added on the original basis, so that the chain connecting ring automatically repairs surface and internal damage under the complex working condition environment of a mine, the service life of the chain connecting ring is effectively prolonged, and compared with a traditional chain connecting ring, the service life can be prolonged by 30%-50%. The 23MnNiMoCr54 alloy steel is used as a base material, self-repairing material components and a special preparation process are combined, the original excellent mechanical properties such as high strength and high toughness of the chain connecting ring are guaranteed, meanwhile, the chain connecting ring is endowed with the self-repairing characteristic, and good comprehensive performance is achieved.

The invention discloses a high-altitude tunnel lining concrete damage self-repairing material and a preparation method thereof, and the self-repairing material is prepared by doping a microcapsule and a conductive filler in a specific proportion into a traditional concrete matrix, the concrete comprises the following components: cement, fine aggregate, coarse aggregate, water, microcapsules I, microcapsules II, nano silicon dioxide, silica fume, carbon fibers and polypropylene fibers. According to the invention, a dual repairing system of the microcapsule I and the microcapsule II is innovatively adopted. The microcapsule I can repair large cracks (the width is larger than or equal to 0.2 mm), and the microcapsule II aims at small cracks (the width is smaller than 0.2 mm). The dual mechanism ensures comprehensive repair of cracks with different sizes, effectively prevents invasion of moisture and harmful substances, and remarkably improves the durability of the concrete. The microcapsule can be rapidly broken and release the repairing agent when the crack is generated, and the repairing agent can be cured in a short time, so that the crack is effectively prevented from further expanding, and the risk of structural damage is reduced.

The invention relates to the technical field of oil and gas well cementation engineering, in particular to a well cementation cement stone micro-crack self-repairing material and a preparation method and application thereof. The well cementation cement stone micro-crack self-repairing material is prepared from the following raw materials in parts by weight: 30 parts of deionized water, 3 to 12 parts of monomer, 0.03 to 0.09 part of cross-linking agent, 0.06 to 0.3 part of initiator, 3 to 20 parts of natural latex, 1.5 to 3 parts of surfactant and 0.03 to 1.5 parts of filler, and is prepared by adopting an emulsion copolymerization method. The obtained self-repairing material is high in liquid absorption rate in a weak acid solution, high in expansion rate when meeting carbon dioxide and excellent in mechanical property, can be doped into a well cementation fluid system, is used for two corrosive medium environments of supercritical CO2 and CO2 formation water in a water wet environment, seals a shaft leakage channel, and improves the sealing integrity of a shaft.

The invention relates to the technical field of self-repairing materials, and provides a microcapsule self-repairing material for concrete structure cracks and a preparation method of the microcapsule self-repairing material. The microcapsule self-repairing material for concrete structure cracks comprises a first microcapsule, the first microcapsule comprises a core material and a shell material in a mass ratio of (1.1-2.5): 1; the shell material is prepared from the following raw materials in parts by weight: 100 parts of urea formaldehyde compound; the core material comprises the following raw material components in parts by weight: 100 parts of epoxy resin and 8-12 parts of a latent curing agent; the latent curing agent comprises a component A and a dicyandiamide compound in a mass ratio of (1: 9)-(9: 1); the component A comprises one or two of a modified amine compound and an imidazole compound. According to the technical scheme, the problem that a microcapsule self-repairing material in the related technology is insufficient in self-repairing effect on concrete cracks is solved.

This invention relates to the field of concrete technology, specifically to a self-healing concrete material, its preparation method, and its application. The self-healing concrete material is a core-shell structured microcapsule, comprising a core material and a wall material. The wall material wraps around the core material. The core material comprises the following raw materials in parts by weight: 4-6 parts β-cyclodextrin, 12-18 parts sepiolite powder, 5-10 parts shellac powder, 25-35 parts sulfoaluminate cement, 10-15 parts magnesium oxide, 12-16 parts sodium silicate aqueous solution, and 14-17 parts calcium carbonate. The wall material comprises the following raw materials in parts by weight: 20-30 parts polyvinyl alcohol, 20-30 parts ethyl cellulose, 15-25 parts bentonite, and 25-35 parts corn starch. The mass ratio of the core material to the wall material is 6-7:3-4. The core material of the self-healing concrete material provided by this invention, comprising β-cyclodextrin, sepiolite powder, and shellac powder, can improve the problems of slow repair speed and poor reinforcement effect of self-healing materials.

The invention relates to the technical field of building materials, in particular to a solid-waste-based Yellow River sediment cementing material and a preparation method of an artificial flood prevention preparation stone. The solid waste-based Yellow River sediment cementing material is prepared from the following raw materials in parts by weight: 300 to 500 parts of Yellow River sediment, 80 to 130 parts of furnace slag ash, 40 to 80 parts of steel slag, 20 to 50 parts of alunite tailings, 25 to 55 parts of mirabilite gypsum, 0.5 to 1.5 parts of crack self-repairing material and 1 to 3 parts of workability regulator. The artificial flood prevention prepared stone prepared by the method has excellent mechanical properties and erosion resistance, can reduce carbon emission and improve the ecological property, and realizes resource utilization of the Yellow River silt.

The present invention discloses a multilayer film with high antibacterial resistance and a preparation method thereof. The key points of the technical scheme are that the multilayer film with high antibacterial resistance consists of three layers, namely an antibacterial layer, a barrier layer and a support layer, wherein the antibacterial layer is located at the outermost layer of the film and adopts a material containing antibacterial components, the barrier layer is located below the antibacterial layer, and the support layer is located below the barrier layer; the present invention solves the problem that the antibacterial effect of traditional antibacterial films decays over time by adopting self-repairing materials and sustained-release technology; the sustained-release agent is designed to control the release rate of the antibacterial components so that it maintains a stable antibacterial effect during long-term use, and by selecting a high-strength support layer material and adopting an optimized processing technology, the tensile strength, tear resistance and wear resistance of the film are significantly improved, and the peeling or damage of the antibacterial layer caused by the influence of the external environment (such as friction, ultraviolet radiation, etc.) is avoided, thereby improving the long-term stability and service life of the film, and having strong market potential.

The invention relates to the field of building materials, and particularly discloses a self-repairing special concrete and a preparation method thereof, the self-repairing special concrete comprises the following raw materials by weight: 40-80 parts of cement, 60-100 parts of gravel, 70-90 parts of machine-made sand, 15-25 parts of an admixture, 20-30 parts of a self-repairing material, 2-6 parts of an auxiliary agent, and 20-45 parts of water; the self-repairing material is prepared by the following steps: uniformly dispersing a repairing material in a water-soluble coating material, adding a wetting agent, shearing, emulsifying and homogenizing to form a stable emulsion, and spray-drying to form microcapsules; adding the microcapsules into a polylactic acid solution, carrying out ultrasonic oscillation and mixing, and emulsifying, curing and centrifuging the mixed solution to obtain the self-repairing material. The preparation method of the self-repairing special concrete comprises the following step: uniformly stirring and mixing the cement, the broken stones, the machine-made sand, the admixture, the self-repairing material, the auxiliary agent and the water to obtain the self-repairing special concrete. The obtained concrete can automatically repair cracks and cracks, and the repair effect is good.

The invention belongs to the technical field of building materials, and particularly relates to an anti-seepage self-repairing material and a preparation method and application thereof. According to the material, graded porous SiOmicrospheres with functionalized surface epoxy groups are taken as a carrier, are loaded in order through space, and are coated with a hydrophobic dynamic repairing agent and a mineral reinforced precursor at the same time. A main chain of the hydrophobic dynamic repairing agent contains a dynamic disulfide bond, so that the hydrophobic dynamic repairing agent has rapid hydrophobic plugging and room-temperature self-healing capabilities; the mineral reinforced precursor can generate secondary C-S-H gel in the cracks, and long-term reinforcement is achieved. The two realize efficient cascade repair under the adjacent action of the carrier space, and the epoxy group on the carrier surface and the cement matrix form strong chemical bonding. After the material is doped into concrete, the self-repairing efficiency and the long-term durability of cracks can be remarkably improved, the material is particularly suitable for concrete structures in water conservancy, ocean and other harsh and humid environments, and the problems that an existing repairing technology product is poor in durability and an interface is prone to falling off are solved.

This invention relates to the field of cement-based engineering materials technology, and in particular to a self-healing plugging material and its preparation method. The material uses calcined magnesium oxide, lightly calcined magnesium oxide, modified silica fume, and magnesium chloride as raw materials to form a heat-resistant self-healing material. Hollow polyvinyl alcohol fiber is used as a carrier, and the outer layer is treated with a silane coupling agent to prepare the self-healing fiber. Combined with calcium carbonate whiskers, the plugging material is toughened, its crack resistance is improved, and microcracks are self-repaired. It can be used for high-temperature cementing and plugging in environments of 150-180℃.

The invention belongs to the technical field of building materials, and discloses a metal adsorption type crack self-repairing material and a preparation method and application thereof.The metal adsorption type crack self-repairing material is of a shell-core structure, an inner core comprises granular foamed copper and a strength repairing component adsorbed in the granular foamed copper, and a shell is made of sulfur aluminum cement fiber mortar; the strength recovery component is prepared from the following raw materials in parts by mass: 50 to 200 parts of ordinary Portland cement, 150 to 300 parts of aluminate cement, 100 to 250 parts of slaked lime and 10 to 30 parts of zeolite powder; the sulphoaluminate cement fiber mortar is prepared from the following raw materials in parts by mass: 400 to 500 parts of sulphoaluminate cement, 6 to 10 parts of chopped fiber, 500 to 600 parts of fine sand, 0.5 to 1.5 parts of thickening time control agent, 1 to 2 parts of water reducing agent and 100 to 120 parts of water. All the components of the crack self-repairing material are linked with one another, when a cement-based material cracks, all the components participate in the reaction sequentially and hierarchically, the conditions needed by the hydration reaction can be rapidly constructed, gel substances can be rapidly generated, and strong self-repairing of cracks is achieved.

The invention discloses a polymer self-repairing material and a preparation method thereof, belonging to the technical field of polymer self-repairing materials. It is a multi-layer network structure constructed by epoxy resin layers with cross-linking density from low to high through layer-by-layer self-assembly technology, each epoxy resin layer contains self-repairing microcapsules and anti-aging agents, and the epoxy resin layer with the highest cross-linking density contains reinforcing fillers and compatibilizers. The damaged part of the polymer self-repairing material finally prepared can be repeatedly repaired, the damaged part has many reaction sites on the healing surface, and the self-repairing microcapsules in other areas of the material can supplement the deficiencies of the damaged part, so that the crack repair efficiency of the damaged part is high and the repair effect is good.

An electronic device may have a hinge that allows the device to be flexed about a bend axis. A display may span the bend axis. To facilitate bending about the bend axis without damage, the display may include a display cover layer with a flexible portion. The flexible portion of the display cover layer may be interposed between first and second rigid portions of the display cover layer. The display cover layer may also include a layer with self-healing properties. The layer of self-healing material may be formed across the entire display cover layer or may be formed only in the flexible region of the display cover layer. The display cover layer may include a layer of elastomer in the flexible region of the display cover layer for increased flexibility. Self-healing may be initiated or expedited by externally applied heat, light, electric current, or other type of external stimulus.

This invention discloses a method for preparing a high-salinity intelligent responsive cement-based anti-salt corrosion and self-healing material. The method includes constructing an intelligent responsive base by preparing a microcapsule self-healing agent and regulating the ZIF-8 preparation process, followed by in-situ growth of Mg-Al-LDH and functional film coating. This achieves the synergistic functions of active anti-salt corrosion, efficient and stable self-healing, promoting cement hydration, and regulating ion adsorption in high-salt environments. This invention can accurately sense changes in high-salt environments and intelligently release the self-healing agent, realizing the dual functions of anti-salt corrosion and self-healing in cement-based materials. It can be widely applied in cement-based engineering projects in high-salt environments such as marine and salt lake environments, extending the service life of concrete structures.

A sensor cover includes a base layer, a cover layer disposed on the base layer and made of a self-healing material, and a heating film disposed between the base layer and the cover layer and configured to generate heat. The base layer and the cover layer are integrated with each other through a double injection molding process.

The present application provides a flexible light-emitting device and a production method thereof, comprising: a bendable light-emitting device body, the light-emitting device body having a bend inner side; a repair layer, the repair layer being arranged on the bend inner side of the light-emitting device body; the repair layer being formed of a self-repairing material; the self-repairing material comprising a polymer matrix, and microcapsules containing a polymer precursor doped in the polymer matrix and a polymerization reaction catalyst; the repair layer having a bend area and a base area distributed around the bend area; the concentration of the microcapsules containing a polymer precursor doped in the polymer matrix located in the bend area is greater than the concentration of the microcapsules containing a polymer precursor doped in the polymer matrix located in the base area. The flexible light-emitting device provided by the present application can be folded and bent according to the designed shape, and can self-repair the cracks caused by the folding and bending.

The application provides a microcapsule self-repairing material constitutive curve prediction method and device, and relates to the technical field of tunnel and underground engineering materials, and aims to solve the problem that the mesoscopic mechanics model cannot reflect and predict the softening stage after the peak value of a cement-based material in the prior art. The method comprises the following steps: if the self-repairing concrete material is a conventional concrete material, calculating the constitutive curve of the conventional concrete material under tensile load in a plane strain condition; if the self-repairing concrete material is a microcapsule self-repairing concrete material containing a strong healing agent, calculating the constitutive curve of the microcapsule self-repairing concrete material containing the strong healing agent under tensile load in a plane strain condition; and if the self-repairing concrete material is a microcapsule self-repairing concrete material containing a weak healing agent, calculating the constitutive curve of the microcapsule self-repairing concrete material containing the weak healing agent under tensile load in a plane strain condition. The microcapsule self-repairing material constitutive curve prediction device is applied to the microcapsule self-repairing material constitutive curve prediction method.

The invention discloses a self-repairing composite material as well as a preparation method and application thereof, and belongs to the technical field of self-repairing materials. According to the self-repairing composite material provided by the invention, thermoplastic polyamide particles with the average particle size of less than 50 microns are distributed between two adjacent layers of carbon fiber / epoxy resin materials in a laying density range of 45-80mg / 100cm < 2 >, and liquid defects are not introduced, so that relatively high I-type interlaminar fracture toughness repairing efficiency is obtained, and relatively high I-type post-healing interlaminar fracture toughness is maintained at the same time; and the preparation method is simple, convenient and efficient, and has good market prospects and industrial application prospects.

The application provides a light response self-repairing material and a preparation method and application thereof, and relates to the technical field of self-repairing materials.The light response self-repairing material takes a photosensitive polymer as a matrix, modified nanosilica and a plant extraction adhesive are wrapped in the self-repairing material, under ultraviolet irradiation, the photosensitive polymer is softened and the modified nanosilica and the plant extraction adhesive are released, the plant extraction adhesive expands when meeting water, and a silica gel network is formed by combining the modified nanosilica, so that cracks are rapidly filled; meanwhile, the toughening fibers in the silica gel network can effectively improve the strength of the repaired crack gap. In addition, it has been verified that the light response self-repairing material can achieve good repair effect in low-temperature or high-salinity water, and can be widely applied to the preparation process of river revetment surface coating.

This application relates to the field of self-healing materials, specifically disclosing a high-toughness self-healing functional material, its preparation method, and its applications. This self-healing functional material is a supramolecular elastomer formed by in-situ free radical polymerization of the tetrad hydrogen-bonded monomer UPy-EMA, a host-guest inclusion complex, and an acrylate monomer under the action of a crosslinking agent and an initiator. The high-toughness self-healing functional material provided in this application is the first to effectively integrate multiple functions of "strength, toughness, self-healing, conductivity, and antibacterial properties," ultimately obtaining a self-repairing material that combines high strength and toughness, rapid self-healing at room temperature, conductivity, and antibacterial properties, with broad application prospects.

The invention provides a battery pack shell repairing system (1), comprising: a battery pack shell (2) comprising an outer shell (21) and a self-repairing material layer (22); a detection device (3) that detects damage to the battery pack case (2); and the control device is used for controlling the heating device (5) to heat the battery pack shell (2) according to the detected damage of the battery pack shell (2) so as to excite the self-repairing material layer (22) to release the self-repairing material, so that the damage of the battery pack shell (2) is repaired. According to the invention, even if the outer shell (21) of the battery pack shell (2) is damaged and the self-repairing material layer (22) is not damaged or the self-repairing material released by the self-repairing material layer (22) is insufficient to repair the damage, the self-repairing material layer (22) can repair the damage. And the detection device (3) can be used for judging the existence of the damage and exciting the self-repairing material layer (22) to release the self-repairing material for repairing.