Perforated film capable of being biodegraded completely and preparation process, application and preparation device thereof

A technology for preparing devices and biodegradable resins, applied in applications, other household appliances, household appliances, etc., can solve the problems of poor toughness and tensile properties, poor hole shape and three-dimensionality, and easy reverse osmosis, etc., to achieve good Good toughness and tensile properties, improved quality, and good three-dimensionality

Inactive Publication Date: 2016-08-17
SUZHOU HANFENG NEW MATERIAL +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the traditional perforated membranes are made of non-degradable materials. These perforated membranes are difficult to dispose of after use. Landfills cause environmental pollution because they cannot be degraded, and incineration will produce a large amount of dioxins and toxic gases. In addition, The production of traditional perforated film is made by secondary molding, that is, the produced film substrate is softened by the heating system of the punching machine, and the film is formed by vacuum suction in an instant, and the hole shape is formed with the punching. The hole type of the device depends on the shape of the device, and then the finished product is wound by slitting. This secondary molding process has the following disadvantages: high energy consumption, the film needs to be softened and vacuum-formed by a heating device, and then wound by the winding system; the production capacity is too large. Low, too much waste; the process is cumbersome; the perforated film product is of poor quality, it needs to be reheated on the basis of the film, and the toughness and tensile properties of the product become poor after the secondary plasticization caused by high temperature, and the three-dimensional shape of the hole The degree is also poor, so the hole shape on the film cannot form a funnel shape, which is prone to reverse osmosis

Method used

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  • Perforated film capable of being biodegraded completely and preparation process, application and preparation device thereof
  • Perforated film capable of being biodegraded completely and preparation process, application and preparation device thereof
  • Perforated film capable of being biodegraded completely and preparation process, application and preparation device thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A preparation process of fully biodegradable perforated film, which comprises the following process steps:

[0031] 1) Material configuration: In terms of weight ratio, 100 parts of tapioca modified starch, 100 parts of polybutylene terephthalate-adipate, 30 parts of polybutylene succinate, 20 parts of polylactic acid, zirconium phosphate Add 2 parts of silver-loaded antibacterial powder, 16 parts of glycerin, 3 parts of ethylene ethyl acrylate, and 4 parts of glyceryl monostearate into a low-speed mixer and mix until uniform. The mixing temperature is 110°C, and the mixing time is 35 minutes. The mixing speed of the mixer is 800 rpm;

[0032] 2) Compression molding: put the mixed material into the hopper of the screw extruder, shear, knead, plasticize and melt the material through the twin screws of the screw extruder, and generate a crosslinking reaction in the barrel to make The plant modified starch and the biodegradable resin undergo a graft reaction, and at the s...

Embodiment 2

[0036] A preparation process of fully biodegradable perforated film, which comprises the following process steps:

[0037] 1) Material configuration: in terms of weight ratio, 100 parts of modified potato starch, 120 parts of polybutylene succinate-co-butylene terephthalate, 20 parts of polylactic acid, and 2.5 parts of silver-loaded zirconium phosphate antibacterial powder Parts, 12 parts of xylitol, 6 parts of ethylene acrylic acid copolymer, and 8 parts of glyceryl laurate were added to a low-speed mixer and mixed until uniform. The mixing temperature was 115 ° C, the mixing time was 33 minutes, and the stirring speed 900 rpm;

[0038] 2) Compression molding: put the mixed material into the hopper of the screw extruder, shear, knead, plasticize and melt the material through the twin screws of the screw extruder, and generate a crosslinking reaction in the barrel to make The plant modified starch and the biodegradable resin undergo a grafting reaction, and at the same time,...

Embodiment 3

[0042] A preparation process of fully biodegradable perforated film, which comprises the following process steps:

[0043] 1) Material configuration: In terms of weight ratio, 100 parts of sweet potato modified starch, 60 parts of polybutylene succinate, 60 parts of polycaprolactone, 10 parts of polylactic acid, 3 parts of silver-loaded zirconium phosphate antibacterial powder, and Add 18 parts of alcohol, 10 parts of ethylene-vinyl acetate, and 8 parts of monoglyceride succinate into a low-speed mixer and mix until uniform. The mixing temperature is 120°C, the mixing time is 30 minutes, and the stirring speed of the low-speed mixer is 1200 rev / min;

[0044] 2) Compression molding: put the mixed material into the hopper of the screw extruder, shear, knead, plasticize and melt the material through the twin screws of the screw extruder, and generate a crosslinking reaction in the barrel to make The plant modified starch and the biodegradable resin undergo a grafting reaction, a...

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PUM

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Abstract

The invention relates to a perforated film capable of being biodegraded completely and a preparation process, application and preparation device thereof. The perforated film capable of being biodegraded completely is prepared from, by weight, 95-100 parts of plant modified starch, 100-150 parts of biodegradable resin, 2-3 parts of zirconium phosphate silver-loaded antimicrobial powder, 0.5-20 parts of pasting agent, 0.3-10 parts of compatibilizer and 0.2-10 parts of dispersant. The preparation device of the perforated film comprises a low-speed mixing machine for raw material mixing, and a film extrusion molding device, a film perforating device and a winding device which are sequentially arranged. The film extrusion molding device comprises a screw extruder, a melt pump and a T-shaped die head which are sequentially connected and communicated. The preparation process of the perforated film comprises material preparation and pressed film molding processes. The prepared perforated film has an antimicrobial effect and can be biodegraded completely, and the preparation efficiency of the perforated film is improved through the preparation device.

Description

technical field [0001] The invention relates to a fully biodegradable perforated film and its preparation process, application and preparation device. Background technique [0002] Hygienic products that are often used in daily life in contact with the body, such as medical wound dressings, diapers for infants and adults, and feminine sanitary napkins, must have the functions of absorbing liquid, preventing rewet, and being dry and breathable. Therefore, in order to achieve the above functions, it is necessary to use a perforated membrane that can provide permeation and avoid rewetting. Most of the traditional perforated membranes are made of non-degradable materials. These perforated membranes are difficult to dispose of after use. Landfills cause environmental pollution because they cannot be degraded, and incineration will produce a large amount of dioxins and toxic gases. In addition, The production of traditional perforated film is made by secondary molding, that is, t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L3/04C08L67/02C08L67/04C08K13/02C08K3/32C08K3/08C08K5/103B29D7/01B29C47/00B29C43/24B26F1/26A61L15/62A61L15/28A61L15/26
CPCC08L3/04A61L15/26A61L15/28A61L15/62B26F1/26B29C43/24B29C48/08B29D7/01C08J5/18C08J2303/04C08J2367/02C08L67/02C08L2201/06C08L2203/16C08L2205/03C08L2205/035C08L67/04C08K13/02C08K2003/328C08K2003/0806
Inventor 余润保黄祥秋刘小文吕光春
Owner SUZHOU HANFENG NEW MATERIAL
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