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Loaded type catalyst and preparation method and application thereof

A supported catalyst and catalyst technology, applied in chemical instruments and methods, preparation of organic compounds, preparation of amino hydroxyl compounds, etc., to achieve the effects of many application times, good catalyst stability and good catalytic performance

Active Publication Date: 2016-08-24
ZHEJIANG UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But this catalyst is only suitable for the treatment of chlorophenol compounds in low concentration (1000-2000mg / L) aqueous solution, and the phenol content in its degradation product also has about 15-40%

Method used

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  • Loaded type catalyst and preparation method and application thereof
  • Loaded type catalyst and preparation method and application thereof
  • Loaded type catalyst and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 Embodiment 10

[0052] The content, proportion and preparation conditions of the catalyst active components are provided, as shown in Table 1. The specific preparation process of the catalyst is as follows: 4.0-12.0%: 0.2-3.5%: 0.2-3.5% of the carrier mass are respectively weighed soluble palladium salt (see Table 1), lanthanum nitrate and cerium nitrate according to the metal mass content percentage, configured as The aqueous solution having the same volume as the total pore volume of the activated carbon (see Table 1 for details) was placed in a constant pressure funnel and inserted into a three-necked flask. Then dry the activated carbon in the three-necked flask for 1.5-4.0 hours in a vacuum state of -0.08--0.1MPa and 120.0-180.0°C. After drying, lower the temperature to 5.0-80.0°C, open the valve of the constant pressure funnel, and fully wet the aqueous solution containing palladium, lanthanum and cerium with the activated carbon. Then in a vacuum anaerobic state (between -0.08—-0.1MPa...

Embodiment 10

[0056] Table 3 shows the application of the catalyst prepared in Example 10 to the catalytic conversion of hexachlorobenzene to prepare phenetole.

[0057] The specific hydrogenation conversion process is as follows: put hexachlorobenzene, ethanol, and catalyst in a ratio of 100g:600ml:1.0g, and the molar ratio of chlorine atoms contained in sodium hydroxide to hexachlorobenzene is 1.5, and put into a 500ml high-pressure hydrogenation reactor Inside, the feeding volume is 70%. Close the reactor, replace the air in the reactor with nitrogen, then replace the nitrogen with hydrogen, start stirring, maintain the reaction temperature at about 90-110°C, and the hydrogen pressure between 0.5-1.2MPa, until no hydrogen is absorbed, stop the reaction, filter catalyst. Sodium chloride is precipitated by low-temperature evaporation, and ethanol and sodium hydroxide are recovered for reuse. The filtrate was analyzed by gas chromatography.

[0058]

[0059]

[0060] Table 3. Catal...

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Abstract

The invention discloses a loaded type catalyst and a preparation method and application thereof. The catalyst is prepared from a carrier and an active component loaded on the carrier; the carrier is activated carbon; the active component is prepared from palladium, lanthanum, cerium and boron; mass of the palladium, the lanthanum, the cerium and the boron respectively is 3.0 to 15.0 percent, 0.1 to 5.0 percent, 0.1 to 5.0 percent and 0.1 to 2.5 percent of mass of the carrier. The invention provides application of the loaded type catalyst to a chlorobenzene compound as shown in a formula (I) and an alcohol reaction generation as shown in a formula (II) and phenyl ether compounds as shown in a formula (III). The catalyst prepared by the preparation method has excellent catalytic performance for the chlorobenzene compound, a catalytic conversion rate can reach 100 percent, selectivity is 99 percent or above, and the catalyst has high stability, and not only can effective degradation of the chlorobenzene compound be implemented, but also phenyl ether organic matter with a higher application value can be obtained. (see the descreiption).

Description

(1) Technical field [0001] The invention relates to a supported catalyst, its preparation method and its application in catalytic hydrogenation conversion of chlorobenzene compounds into phenyl ether compounds. (2) Technical background [0002] Chlorobenzene is an important class of industrial raw materials. It is widely used in various fields such as chemical industry, medicine, pesticide, dyestuff, etc. as organic synthesis raw material and fine chemical intermediate. However, such compounds usually have residual, bioaccumulative, low volatility and high toxicity (carcinogenic, teratogenic, mutagenic), and are not easy to be decomposed or naturally degraded, and long-term accumulation in the environment will affect the ecological environment and human health. pose a serious threat. Therefore, how to degrade chlorobenzene and carry out its non-toxic and harmless treatment has become an important research topic that needs to be solved urgently in the field of environmental ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/63C07C41/16C07C43/205C07C43/225C07C201/12C07C205/37C07C213/00C07C217/84
CPCC07C41/16C07C43/205C07C43/225C07C201/12C07C205/37C07C213/00C07C217/84B01J23/63B01J35/617B01J35/635
Inventor 卢春山周强李小年马利勇王树华
Owner ZHEJIANG UNIV OF TECH
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