Silicon carbide composite zero-valent iron porous ceramics for sewage treatment and preparing method

A technology for porous ceramics and sewage treatment, applied in the direction of reduced water/sewage treatment, ceramic products, applications, etc., can solve the problems of inconspicuous treatment effects, complicated methods, and incompleteness, etc., to overcome the inconspicuous treatment effects, simple process, low cost effect

Active Publication Date: 2016-10-12
SHAANXI UDC MATERIALS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] There are many methods for preparing silicon carbide porous ceramics, including fiber drawing process, organic foam impregnation process, chemical deposition process, etc., but these methods are relatively complicated, it is not easy to carry out large-scale industrial production, and the cost is high
[0004] Traditional sewage treatment and polluted soil treatment require a series of complicated processes such as filtration, neutralization reaction, resin adsorption, and chemical precipitation. The workload is heavy, the treatment effect is not obvious, not thorough, and even causes secondary pollution.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] 100Kg of deionized water, 100Kg of silicon carbide micropowder, 10Kg of zero-valent iron powder, 2Kg of glass powder, 5Kg of carbon powder, 5Kg of graphite, 500mL of ethylene glycol, 3.5Kg of polyvinyl alcohol, and an aqueous solution of ammonium polyacrylate (mass fraction is 20%) Put 600mL into a ball mill and mill for 48 hours, filter, spray granulate (inlet temperature is 200-230°C, outlet temperature is 180-200°C), press the green body with a 200MPa press, put it into a vacuum sintering furnace, and feed With high-purity argon, the temperature was gradually raised to 1350°C at a heating rate of 2°C / min, and kept for 1 hour and then lowered to room temperature, finally forming a silicon carbide composite zero-valent iron porous ceramic with a porosity of 35%.

Embodiment 2

[0022] 150Kg of deionized water, 150Kg of silicon carbide micropowder, 10Kg of zero-valent iron powder, 3Kg of glass powder, 10Kg of carbon powder, 15Kg of graphite, 750mL of ethylene glycol, 10Kg of polyvinyl alcohol, and 950mL of ammonium polyacrylate aqueous solution (mass fraction is 20%) Put it into a ball mill for 48 hours, filter, spray and granulate, press the green body with a 200MPa press, put it into a vacuum sintering furnace, and feed high-purity argon at the same time, and gradually raise the temperature to 1350°C at a heating rate of 2°C / min , and kept for 1 hour, and then cooled down to room temperature, finally forming a silicon carbide composite zero-valent iron porous ceramic with a porosity of 45%.

Embodiment 3

[0024] 150Kg of deionized water, 150Kg of silicon carbide powder, 15Kg of zero-valent iron powder, 5Kg of glass powder, 10Kg of carbon powder, 10Kg of graphite, 800mL of ethylene glycol, 12Kg of polyvinyl alcohol, and 1000mL of ammonium polyacrylate aqueous solution (20% by mass fraction) Put it into a ball mill for 48 hours, filter, spray and granulate, press the green body with a 200MPa press, put it into a vacuum sintering furnace, and feed high-purity argon at the same time, and gradually raise the temperature to 1350°C at a heating rate of 2°C / min , and kept for 1 hour, and then cooled down to room temperature, finally forming a silicon carbide composite zero-valent iron porous ceramic with a porosity of 57%.

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PUM

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Abstract

The invention relates to silicon carbide composite zero-valent iron porous ceramics for sewage treatment and a preparing method. The porous ceramics is prepared by uniformly mixing, by mass, 60-90 parts of silicon carbide micro powder, 5-25 parts of zero-valent iron power, 1-5 parts of glass powder, 3-20 parts of carbon powder, 1-8 parts of graphite, 0.1-0.5 part of ethanediol, 0.1-0.5 part of ammonium polyacrylate, 2-10 parts of polyvinyl alcohol and water, then spray granulation is carried out, a blank is manufactured, and under the protection of nitrogen, the blank is sintered for 1 h at the temperature of 1350-1400 DEG C and cooled to the room temperature to obtain the silicon carbide composite zero-valent iron porous ceramics for sewage treatment. The zero-valent iron is compounded into the ceramics and has the advantages of being low in toxicity, low in price, easy to operate, environmentally friendly and free of secondary pollution. The porous ceramics is simple in process, low in cost, capable of being produced on a large scale and applied to a practical sewage treatment project, and the problems that in the prior art, secondary pollution is caused as the treatment effect is unobvious and not thorough are solved.

Description

technical field [0001] The invention belongs to the technical field of preparation of environmental protection materials, and relates to a silicon carbide composite zero-valent iron porous ceramic for sewage treatment and a preparation method thereof. Background technique [0002] Silicon carbide has the characteristics of low density, high strength, corrosion resistance, oxidation resistance, good thermal conductivity, high temperature resistance, etc. Zero-valent iron can easily lose electrons and has good reducibility. After the two materials are combined to form a new functional material with many pores in the internal structure, it can be widely used in the field of sewage treatment. [0003] There are many methods for preparing silicon carbide porous ceramics, including fiber drawing process, organic foam impregnation process, chemical deposition process, etc., but these methods are relatively complicated, it is not easy to carry out large-scale industrial production, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/565C04B38/06C04B35/622C02F1/70
CPCC02F1/70C04B35/565C04B35/622C04B38/06C04B2235/36C04B2235/405C04B2235/422C04B2235/425
Inventor 王东陈兵邱冰山刘飞张博
Owner SHAANXI UDC MATERIALS TECH CO LTD
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