Silicon carbide composite zero-valent iron porous ceramics for sewage treatment and preparing method
A technology for porous ceramics and sewage treatment, applied in the direction of reduced water/sewage treatment, ceramic products, applications, etc., can solve the problems of inconspicuous treatment effects, complicated methods, and incompleteness, etc., to overcome the inconspicuous treatment effects, simple process, low cost effect
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Embodiment 1
[0020] 100Kg of deionized water, 100Kg of silicon carbide micropowder, 10Kg of zero-valent iron powder, 2Kg of glass powder, 5Kg of carbon powder, 5Kg of graphite, 500mL of ethylene glycol, 3.5Kg of polyvinyl alcohol, and an aqueous solution of ammonium polyacrylate (mass fraction is 20%) Put 600mL into a ball mill and mill for 48 hours, filter, spray granulate (inlet temperature is 200-230°C, outlet temperature is 180-200°C), press the green body with a 200MPa press, put it into a vacuum sintering furnace, and feed With high-purity argon, the temperature was gradually raised to 1350°C at a heating rate of 2°C / min, and kept for 1 hour and then lowered to room temperature, finally forming a silicon carbide composite zero-valent iron porous ceramic with a porosity of 35%.
Embodiment 2
[0022] 150Kg of deionized water, 150Kg of silicon carbide micropowder, 10Kg of zero-valent iron powder, 3Kg of glass powder, 10Kg of carbon powder, 15Kg of graphite, 750mL of ethylene glycol, 10Kg of polyvinyl alcohol, and 950mL of ammonium polyacrylate aqueous solution (mass fraction is 20%) Put it into a ball mill for 48 hours, filter, spray and granulate, press the green body with a 200MPa press, put it into a vacuum sintering furnace, and feed high-purity argon at the same time, and gradually raise the temperature to 1350°C at a heating rate of 2°C / min , and kept for 1 hour, and then cooled down to room temperature, finally forming a silicon carbide composite zero-valent iron porous ceramic with a porosity of 45%.
Embodiment 3
[0024] 150Kg of deionized water, 150Kg of silicon carbide powder, 15Kg of zero-valent iron powder, 5Kg of glass powder, 10Kg of carbon powder, 10Kg of graphite, 800mL of ethylene glycol, 12Kg of polyvinyl alcohol, and 1000mL of ammonium polyacrylate aqueous solution (20% by mass fraction) Put it into a ball mill for 48 hours, filter, spray and granulate, press the green body with a 200MPa press, put it into a vacuum sintering furnace, and feed high-purity argon at the same time, and gradually raise the temperature to 1350°C at a heating rate of 2°C / min , and kept for 1 hour, and then cooled down to room temperature, finally forming a silicon carbide composite zero-valent iron porous ceramic with a porosity of 57%.
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