Graphene composite cable material and method for preparing same

A graphene composite and cable material technology, which can be applied to insulated cables, cables, circuits, etc., can solve problems such as poor environmental protection performance, and achieve the effects of being suitable for large-scale industrial application, easy to obtain raw materials, and strong practicability

Active Publication Date: 2017-01-04
湖南三湘电线电缆有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, how to apply graphene to cable materials, thereby improving the hardness and toughness of cables, and at the same time solving the defects of poor environmental performance of materials through reasonable raw material ratios, is particularly necessary.

Method used

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  • Graphene composite cable material and method for preparing same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] (1) Weigh 30 parts of polyimide emulsion, 25 parts of modified montmorillonite, 20 parts of high-density polyethylene, 15 parts of polyethylene naphthalate, 10 parts of silane coupling agent KH-550, sulfur 10 parts of powder, 8 parts of titanium diboride, 8 parts of glass fiber, 7 parts of citrate, 5 parts of graphene, 5 parts of choline alfoscerate, di(3,4-dimethyl)benzyl sorbitol 2 parts, 3 parts of fatty alcohol polyoxyethylene ether, 3 parts of antioxidant MBZ;

[0025] (2) Add an appropriate amount of water to graphene, titanium diboride, and glass fiber, grind for 3 hours to obtain a 450-mesh slurry, and spray dry to obtain a powder. The air inlet temperature of the spray dryer is 250°C, and the air outlet temperature is 180°C;

[0026] (3) Add nitric acid to the powder, react for 5 minutes, dry it and send it to the mixer, then add polyimide emulsion, modified montmorillonite, high-density polyethylene, polyethylene naphthalate Alcohol esters were mixed for 25 m...

Embodiment 2

[0032] (1) Weigh 33 parts of polyimide emulsion, 30 parts of modified montmorillonite, 25 parts of high-density polyethylene, 20 parts of polyethylene naphthalate, 15 parts of silane coupling agent KH-550, sulfur 12 parts of powder, 10 parts of titanium diboride, 10 parts of glass fiber, 9 parts of citrate, 7 parts of graphene, 7 parts of choline alfoscerate, di(3,4-dimethyl) benzyl sorbitol 4 parts, 4 parts of dimethyl sulfoxide, 4 parts of antioxidant RD;

[0033] (2) Add an appropriate amount of water to graphene, titanium diboride, and glass fiber, grind for 4 hours to obtain a 500-mesh slurry, and spray dry to obtain a powder. The air inlet temperature of the spray dryer is 250°C, and the air outlet temperature is 180°C;

[0034] (3) Add nitric acid to the powder, react for 10 minutes, dry it and send it to the mixer, then add polyimide emulsion, modified montmorillonite, high-density polyethylene, polyethylene naphthalate Alcohol esters were mixed for 28 minutes at a te...

Embodiment 3

[0040](1) Weigh 35 parts of polyimide emulsion, 35 parts of modified montmorillonite, 30 parts of high-density polyethylene, 25 parts of polyethylene naphthalate, 20 parts of silane coupling agent KH-550, sulfur 15 parts of powder, 12 parts of titanium diboride, 12 parts of glass fiber, 10 parts of citrate, 8 parts of graphene, 8 parts of choline alfoscerate, di(3,4-dimethyl) benzyl sorbitol 5 parts, 5 parts of coconut acid diethanolamide, 5 parts of anti-aging agent NBC;

[0041] (2) Add an appropriate amount of water to graphene, titanium diboride, and glass fiber, grind for 5 hours to obtain a 550-mesh slurry, and spray dry to obtain a powder. The air inlet temperature of the spray dryer is 250°C, and the air outlet temperature is 180°C;

[0042] (3) Add nitric acid to the powder, react for 15 minutes, dry it and send it to the mixer, then add polyimide emulsion, modified montmorillonite, high-density polyethylene, polyethylene naphthalate Alcohol esters were mixed for 30 ...

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Abstract

The invention discloses a graphene composite cable material and a method for preparing the same. The graphene composite cable material is made of polyimide emulsion, modified montmorillonite, high-density polyethylene, polyfuran dioctyl phthalate glycol ester, silane coupling agents KH-550, sulfur powder, titanium diboride, glass fibers, citrate, graphene, choline alfoscerate, di-(3, 4-dimethyl) benzyl sorbitol, dispersing agents and anti-aging agents. The method includes processes of fitting grinding, spray-drying, acidifying, mixing, ultrasonic treatment, extrusion, stretching, heat setting and the like. The graphene composite cable material and the method have the advantages that requirements of high-voltage and direct-current power transmission cables on the hardness and the toughness of the graphene composite cable material prepared by the aid of the method can be met, the graphene composite cable material is good in environmental protection performance and low in integral cost, accordingly, industrial requirements can be met, and the graphene composite cable material and the method have excellent application prospects.

Description

technical field [0001] The invention relates to the technical field of composite graphene materials, in particular to a graphene composite cable material and a preparation method thereof. Background technique [0002] Cable material is a general term for plastics used for wire and cable insulation and sheathing. It is made of rubber, plastic, nylon and other materials as base materials, combined with auxiliary components such as plasticizers, fillers, color masterbatches, and antioxidants. Different types of cables and The use environment has different requirements on the performance of cable materials. [0003] HVDC transmission technology has developed rapidly in recent years and is mainly used in renewable resource grid connection, island power supply, submarine cables and urban underground cables. Moreover, DC transmission can connect unstable power sources such as solar power generation and wind power generation with the power system, which has more advantages than AC ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L79/08C08L23/06C08L67/02C08K13/06C08K9/02C08K3/04C08K3/38C08K7/14C08K3/34C08K3/06C08K5/11C08K5/521C08K5/053H01B7/18B29C69/02B29C47/92B29C48/92
CPCB29C48/0018B29C48/92B29C2948/92514B29C2948/9259C08L79/08C08L2203/202C08L2205/03C08L2205/035C08L2207/062H01B7/18C08L23/06C08L67/02C08K13/06C08K9/02C08K3/04C08K3/38C08K7/14C08K3/346C08K3/06C08K5/11C08K5/521C08K5/053
Inventor 张伟
Owner 湖南三湘电线电缆有限责任公司
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