The present application relates to the technical field of
polyester material modification, and particularly relates to a high-transparency
polyethylene naphthalate material, a preparation method and application, aiming at the problems of fast
crystallization rate of the PEN material in the process of
processing and molding, easy
crystallization of thick products, light
transmittance reduction caused by the
crystallization, and insufficient material
toughness, the present application introduces a
diol monomer containing a side group and a flexible
chain segment diol monomer into the PEN melt polycondensation process for copolymerization, wherein the
diol containing a side group introduces a steric hindrance structure in the molecular chain to destroy the regular packing of the PEN molecular chain, thereby inhibiting the material crystallization behavior and improving the light
transmittance of the thick product; the flexible diol introduces a flexible
chain segment in the molecular chain to increase the free volume of the molecular chain and improve the molecular chain movement ability, thereby improving the material
toughness. Through the above-mentioned synergistic copolymerization modification method, the crystallization tendency of the PEN material can be effectively reduced, the obtained PEN thick product has excellent light
transmittance and
toughness at the same time, and is suitable for the preparation of high-performance transparent
polyester products.