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Antibacterial and radiation resistant composite fiber membrane preparing method

A composite fiber film, radiation protection technology, applied in fiber processing, conjugated synthetic polymer rayon, single-component polyester rayon, etc. Membrane structure damage and other problems, to achieve the effect of adding emotional and artistic effects, long-term antibacterial activity, and improving stability

Inactive Publication Date: 2017-01-25
佛山市高明区尚润盈科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The silver-loaded nanoparticle / composite fiber membrane prepared by the prior art has poor biocompatibility, and by-products are produced during the preparation process, causing the structure of the fiber membrane to be destroyed, which limits the application of the antibacterial fiber membrane
Moreover, because nano-silver is granular and the particle size is nano-level, it can only be gathered in specific parts of graphene and cannot be evenly distributed on the surface, thereby affecting the antibacterial effect; on the other hand, nano-silver and graphene cannot be tightly combined (especially When the content of nano-silver particles increases, it is easy to agglomerate), and it is easy to fall off during use, thus affecting the service life and antibacterial effect
At the same time, the existing fiber membranes have a single function, and one fiber membrane cannot meet various needs. Often, the fiber membrane materials with multiple functions are superimposed, but it is difficult to achieve the expected effect.

Method used

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  • Antibacterial and radiation resistant composite fiber membrane preparing method
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  • Antibacterial and radiation resistant composite fiber membrane preparing method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A kind of preparation method of antibacterial composite material, it comprises the following steps:

[0033] (1) Preparation of graphene quantum dot suspension: weigh 0.5g of C60 powder, measure 50ml of concentrated sulfuric acid with a mass fraction of 98%, mix C60 powder and concentrated sulfuric acid in a beaker, place the beaker in an ice-water bath, and simultaneously Stir at a speed of 500rpm to obtain a mixed solution; weigh 3g of potassium permanganate powder, and slowly add it to the above mixed solution; remove the ice-water bath and replace it with a water bath, keep the temperature of the water bath at 30~40°C, and react for 8 hours; quickly add 200ml of pure Water, filtered, and then dialyzed for 3 days with a dialysis bag with a molecular weight cut-off of 1000 to obtain a suspension of graphene quantum dots; the suspension of graphene quantum dots was stirred at a speed of 100 rpm, while laser irradiation was performed for 30 minutes, and the laser irradia...

Embodiment 2

[0042] A kind of preparation method of antibacterial composite material, it comprises the following steps:

[0043] (1) Preparation of graphene quantum dot suspension: Weigh 0.7g of C60 powder, measure 80ml of concentrated sulfuric acid with a mass fraction of 98%, mix C60 powder and concentrated sulfuric acid in a beaker, place the beaker in an ice-water bath, and simultaneously Stir at a speed of 500rpm to obtain a mixed solution; weigh 2g of potassium permanganate powder, and slowly add it to the above mixed solution; remove the ice-water bath and replace it with a water bath, keep the temperature of the water bath at 30-40°C, and react for 6 hours; quickly add 200ml of pure Water, filtered, and then dialyzed for 3 days with a dialysis bag with a molecular weight cut-off of 1000 to obtain a suspension of graphene quantum dots; the suspension of graphene quantum dots was stirred at a speed of 100 rpm, while laser irradiation was performed for 45 minutes, and the laser irradia...

Embodiment 3

[0052] A kind of preparation method of antibacterial composite material, it comprises the following steps:

[0053] (1) Preparation of graphene quantum dot suspension: Weigh 0.8g of C60 powder, measure 100ml of concentrated sulfuric acid with a mass fraction of 98%, mix C60 powder and concentrated sulfuric acid in a beaker, put the beaker in an ice-water bath, and simultaneously Stir at a speed of 500rpm to obtain a mixed solution; weigh 1g of potassium permanganate powder, and slowly add it to the above mixed solution; remove the ice-water bath and replace it with a water bath, keep the temperature of the water bath at 30-40°C, and react for 5 hours; quickly add 100ml of pure Water, filtered, and then dialyzed for 3 days with a dialysis bag with a molecular weight cut-off of 1000 to obtain a suspension of graphene quantum dots; the suspension of graphene quantum dots was stirred at a speed of 100 rpm, while laser irradiation was performed for 60 minutes, and the laser irradiat...

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Abstract

The invention discloses an antibacterial and radiation resistant composite fiber membrane preparing method, the method comprises the steps of 1, preparation of polymer antibacterial / radiation resistant fiber layer: dissolving polymer A with small molecule solvent, adding antibacterial / radiation resistant dispersion into mixture under stirring, continuing to stir, and preparing antibacterial / radiation resistant nanofibers; 2, preparation of polymer photochromic fiber membrane layer: fully mixing 5-10 parts of mixture with 70-80 parts of polymer B, 0.5-2 parts of antioxidant and 10-15 parts of plasticizer to produce photochromic composite fiber; 3, the fiber layers prepared in steps 1 and 2 are combined to form a membrane. The antibacterial and radiation resistant composite fiber membrane respectively makes antibacterial / radiation resistant fibers and photochromic fiber, the membrane is composited, after the combination of antimicrobial compounds, nano-bamboo charcoal, photochromic complexes and diatomaceous earth / porous carbon, the composite fiber membrane has excellent antibacterial, radiation resistance, formaldehyde scavenging and photochromic properties to meet the needs of multi-functional fiber membrane, and further borden the application.

Description

technical field [0001] The invention relates to the technical field of composite fiber membranes, in particular to a preparation method of an antibacterial and anti-radiation composite fiber membrane. Background technique [0002] Nanofibrous membrane has the advantages of large surface area, high porosity, loose structure, pre-designed composition according to the required function, simulating extracellular matrix, and simple preparation method, and has great application potential in many fields. It has been used in food, medicine, Daily chemicals and other fields have been widely used. In particular, nanofibrous membranes prepared with natural polymers as spinning solutions not only have the above characteristics, but also have excellent biocompatibility, biodegradability and renewability. [0003] The silver-loaded nanoparticle / composite fiber membrane prepared by the prior art has poor biocompatibility, and by-products are produced during the preparation process, which ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92D01F8/06D01F1/10D01D5/00D04H1/4382D04H1/559D04H1/593
CPCD01F6/92D01D5/0023D01D5/003D01D5/0069D01D5/0076D01D5/0092D01F1/10D01F1/103D01F1/106D01F8/06D04H1/4382D04H1/559D04H1/593
Inventor 陆庚
Owner 佛山市高明区尚润盈科技有限公司
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