Symclosene production wastewater processing system and method thereof

A technology for the production of trichloroisocyanuric acid and waste water, which is applied in natural water treatment, water/sewage treatment, water/sewage multi-stage treatment, etc. It can solve the problems of production raw material waste, refractory treatment, air pollution, etc., and achieve treatment The system is scientific and reasonable, the processing method is simple and effective, and the effect of reducing the production cost

Pending Publication Date: 2017-03-01
中盐内蒙古化工钠业有限公司 +1
View PDF4 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The production method of trichloroisocyanuric acid mainly adopts the liquid caustic method, that is, cyanuric acid and liquid caustic soda generate trisodium cyanurate, and then feeds chlorine gas to generate trichloroisocyanuric acid, but a large amount of Wastewater contains a large amount of sodium chloride and trichloroisocyanuric acid, wherein the recovery value of sodium chloride is low, and trichloroisocyanuric acid compound is a heterocyclic compound containing a triazine ring structure, which is difficult to degrade; currently, Wastewater such as centrifuge mother liquor and washing water produced by the production of trichloroisocyanuric acid is generally treated by dechlorination. After treatment, the existing wastewater becomes high-salt water and some trichloroisocyanuric acid remains, resulting in that the treated wastewater still cannot be discharged up to the standard. During the storage process, the wastewater will release some chlorine gas, causing air pollution, which eventually leads to the difficulty of treating the wastewater produced by the production of trichloroisocyanuric acid, and the production raw materials in the wastewater cannot be recycled, resulting in waste of production raw materials

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Symclosene production wastewater processing system and method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] like figure 1 As shown, the wastewater treatment system for the production of trichloroisocyanuric acid includes a wastewater storage tank 1, a heat exchanger 2, a delivery pump 3, an acid desorption tower 4, a hydrochloric acid storage tank 5, a vacuum pump 6, a chlorine buffer tank 7, and a chlorination tank. Kettle 8, analysis waste water storage tank 9, sodium bisulfite storage tank 10, cyanuric acid production tank 11, lye storage tank 12, plate and frame filter press 13, cyanuric acid recovery tank 14, filter press liquid storage tank 15, membrane filtration device 16, resin adsorption tower 17, evaporation crystallizer 18, salt storage tank 19 and condensed water pipeline 20, gel type resin is filled in the resin adsorption tower 17, evaporation crystallizer 18 is a mechanical vapor recompression crystallizer or Multi-effect evaporation crystallizer;

[0030] The outlet of the waste water storage tank 1 is connected with the waste water inlet of the heat exchang...

Embodiment 2

[0033] Utilize the method for treating waste water from the production of trichloroisocyanuric acid carried out in Example 1, which comprises the steps of: (1) heating and conveying of waste water; (2) acid analysis; (3) waste liquid reduction after the reaction; (4) cyanuric acid Generate; (5) press filtration; (6) post-treatment of press filtrate;

[0034] (1) Heating and transportation of waste water: the waste water produced by trichloroisocyanuric acid in the waste water storage tank 1 is heated to 35°C through the heat exchanger 2, and the heated waste water produced by trichloroisocyanuric acid is transported to the In the acid-adding analysis tower 4, the waste water produced by trichloroisocyanuric acid in the waste water storage tank 1 is heated to 35°C, so that the acid-adding dechlorination reaction can be carried out more thoroughly. Free chlorine content is less than 300PPm;

[0035](2) Add acid analysis: add the hydrochloric acid that mass percentage concentrat...

Embodiment 3

[0041] Utilize the method for treating waste water from the production of trichloroisocyanuric acid carried out in Example 1, which comprises the steps of: (1) heating and conveying of waste water; (2) acid analysis; (3) waste liquid reduction after the reaction; (4) cyanuric acid Generate; (5) press filtration; (6) post-treatment of press filtrate;

[0042] (1) Heating and conveying of waste water: the waste water produced by trichloroisocyanuric acid in the waste water storage tank 1 is heated to 37°C through the heat exchanger 2, and the heated waste water produced by trichloroisocyanuric acid is transported to the In the acid-adding analysis tower 4, the waste water produced by trichloroisocyanuric acid in the waste water storage tank 1 is heated to 37°C, so that the acid-adding dechlorination reaction can be carried out more thoroughly. Free chlorine content is less than 300PPm;

[0043] (2) Acid-adding analysis: adding mass percent concentration in the acid-adding analy...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a symclosene production wastewater processing system and a method thereof. The processing system comprises a wastewater storage tank, a heat exchanger, a transfer pump, an acidification analytic tower, a hydrochloric acid storage tank, a vacuum pump, a chlorine buffer tank, a chlorination kettle, an analytic wastewater storage tank, a sodium bisulfite storage tank, a cyanuric acid generation tank, an alkali lye storage tank, a plate-and-frame filter press, a cyanuric acid recovery tank, a press filtrate storage tank, a membrane filter, a resin adsorption tower, an evaporated crystallizer, a salt storage tank and a condensate reclaimed water pipeline. The processing method comprises the following steps: (1) heating and transportation of wastewater; (2) acidification analysis; (3) effluent reduction after reaction; (4) generation of cyanuric acid; (5) press filtration; and (6) press filtrate aftertreatment. The processing system is scientific and reasonable and the processing method is simple and effective. By the system and the method, the problem that symclosene wastewater cannot reach the discharge standards after treatment and the generated exhaust gas pollutes the air is thoroughly solved; treated water, salt and gas are recycled; and utilization rate of production materials is raised.

Description

[0001] Technical field: [0002] The invention relates to a treatment system and method for industrial production wastewater, in particular to a treatment system and method for trichloroisocyanuric acid production wastewater. [0003] Background technique: [0004] The production method of trichloroisocyanuric acid mainly adopts the liquid caustic method, that is, cyanuric acid and liquid caustic soda generate trisodium cyanurate, and then feeds chlorine gas to generate trichloroisocyanuric acid, but a large amount of Wastewater contains a large amount of sodium chloride and trichloroisocyanuric acid, wherein the recovery value of sodium chloride is low, and trichloroisocyanuric acid compound is a heterocyclic compound containing a triazine ring structure, which is difficult to degrade; currently, Wastewater such as centrifuge mother liquor and washing water produced by the production of trichloroisocyanuric acid is generally treated by dechlorination. After treatment, the exis...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/10C07D251/32C02F103/36C02F101/12C02F101/38
CPCC02F9/00C07D251/32C02F2103/36C02F2101/38C02F2101/12C02F2001/5218C02F1/285C02F1/04C02F1/001C02F1/70C02F1/66C02F1/52C02F1/44
Inventor 王成军徐国庆李海军骆秋福高永忠卢世颜李发环魏存福刘思伟陆少峰王东飞谢景林程智程贝
Owner 中盐内蒙古化工钠业有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products