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Octadecylamine graft epoxy heat-conducting material and preparation method thereof

A heat-conducting material, the technology of octadecylamine, applied in the field of octadecylamine-grafted epoxy heat-conducting materials and its preparation, can solve the problems of easy peeling of layers and low universality, and achieve enhanced thermal conductivity and good dispersibility and compatibility, enhancing the effect of interaction force

Inactive Publication Date: 2017-05-10
ANQING JINHUIHUANG ELECTRONICS TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Each layer of hexagonal BN is a planar hexagonal ring structure with B atoms and N atoms arranged alternately, and B atoms and N atoms are bonded together by SP2 hybrid covalent bonds, and the layers are bonded by Van der Waals force. Therefore, the structure of each layer of hexagonal BN is stable, but the layers are easy to peel off
At present, many researchers have established many models for predicting the thermal conductivity of binary systems based on theories such as the minimum thermal resistance method, thermal resistance network method, and homogenization method. Most of the models are only applicable to the corresponding system, and the universality is not high.

Method used

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Embodiment Construction

[0019] A kind of octadecylamine grafted epoxy thermally conductive material, it is made up of the raw material of following weight part:

[0020] Sodium myristate soap 1.5, diisopropylethanolamine 0.3, hexagonal boron nitride 37, methyl hexahydrophthalic anhydride 8, neodymium acetylacetonate 0.4, octadecylamine 0.7, 3,5 diaminobenzoic acid 4, Triphenyl phosphite 2, pyridine 0.3, N-methylpyrrolidone 32, epoxy resin E40100, sodium lignosulfonate 1, zinc dibutyldithiocarbamate 2, allyl polyethylene glycol 4, 1 , 2 dimethylimidazole 0.6, wollastonite powder 10, hydroxystearic acid 0.6.

[0021] A kind of preparation method of described octadecylamine grafted epoxy thermally conductive material comprises the following steps:

[0022] (1) Add the above wollastonite powder into 10mol / l hydrochloric acid solution, stir and react for 100 minutes, filter, wash the precipitate 3 times with water, dry at room temperature, mix with the above zinc dibutyldithiocarbamate, add to the mixing...

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Abstract

The invention discloses an octadecylamine graft epoxy heat-conducting material which is prepared from the following raw materials in parts by weight: 1.5-2 parts of sodium myristate soap, 0.3-1 part of diisopropyl ethanolamine, 37-40 parts of hexagonal boron nitride, 8-10 parts of methyl hexahydrophthalic anhydride, 0.4-1 part of neodymium acetylacetonate, 0.7-1.3 parts of octadecylamine, 4-6 parts of 3,5-diamidobenzoic acid, 2-3 parts of triphenyl phosphite, 0.3-0.5 part of pyridine, 32-40 parts of N-methylpyrrolidone, 100-110 parts of epoxy resin E40, 1-2 parts of sodium lignosulfonate, 2-3 parts of zinc dibutyl dithiocarbamate, 4-5 parts of allyl polyethyleneglycol, 0.6-1 part of 1,2-dimethyl imidazole, 10-12 parts of wollastonite powder and 0.6-1 part of hydroxystearic acid. The composite material has the advantages of high surface hardness, favorable hydrophobicity and excellent comprehensive properties.

Description

technical field [0001] The invention relates to the technical field of heat-conducting materials, in particular to an octadecylamine-grafted epoxy heat-conducting material and a preparation method thereof. Background technique [0002] As a functional material with great application prospects, high thermal conductivity polymer-based composite materials play a very important role in many manufacturing and high-tech fields such as microelectronics, aviation, aerospace, military equipment, electrical appliances, etc. important role. Especially in recent years, with the rapid development of electronic integration technology, the assembly density has increased rapidly, the volume of electronic components and logic circuits has been reduced by tens of thousands of times, and electronic instruments and equipment have become increasingly ultra-light, thin, short, and small. Under high-frequency operating frequency, the working thermal environment of semiconductors moves rapidly tow...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08L71/02C08K13/06C08K9/04C08K3/34C08K7/00C08K3/38C08K5/19C08K5/526C09K5/14
CPCC08K2201/011C08L63/00C08L2205/03C09K5/14C08L71/02C08K13/06C08K9/04C08K3/34C08K9/08C08K7/00C08K2003/385C08K5/19C08K5/526
Inventor 严华平
Owner ANQING JINHUIHUANG ELECTRONICS TECH CO LTD
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