Improved 3 type slow release long-acting super-hydrophobic anti-contamination flashover coating
An anti-fouling flashover coating and super-hydrophobic technology, applied in the field of coatings, can solve the problems of low elongation, breaking strength and tear strength, easy aging service life, poor corrosion resistance, etc., and achieve salt spray aging resistance Good, excellent stain resistance, and the effect of improving mechanical properties
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[0048] The preparation method of the improved Type 3 slow-release long-acting super-hydrophobic antifouling flashover coating of the present invention comprises the following steps:
[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and methylcyclosiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add dropwise Concentrated hydrochloric acid with a concentration of 37%, react for 1-2 hours after the dropwise addition, cool to 20-30°C, add ammonia water, adjust the pH to 6-7, and obtain hydrogen-terminated fluorine-containing polysiloxane; among them, trifluoropropyl The mass ratio of methylcyclotrisiloxane, tetramethyldisiloxane, methylcyclosiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~1:0.2~0.5;
[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 hours to obtain ...
Embodiment 1
[0057] An improved Type 3 slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, hydrophobic Type fumed silica 20kg, nano zinc oxide 3kg, oleyl amino oleate 2kg, wollastonite powder 4kg, ketoxime type crosslinking agent 1kg, dimethylaminopropylamine 5kg, silane coupling agent 1kg, aluminum hydroxide 3kg and organic Solvent 165kg;
[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:
[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of methylcyclosiloxane evenly, add 12.5kg of sodium sulfate, heat up to 60°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 1 hour after the dropwise ...
Embodiment 2
[0064] An improved type 3 slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 30kg of hydrogen-terminated polysiloxane, 65kg of 107 silicone rubber, hydrophobic Type fumed silica 30kg, nano zinc oxide 5kg, oleyl amino oleate 4kg, wollastonite powder 6kg, ketoxime type crosslinking agent 3kg, dimethylaminopropylamine 10kg, silane coupling agent 2kg, aluminum hydroxide 6kg and organic Solvent 175kg;
[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:
[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of methylcyclosiloxane evenly, add 10kg of sodium sulfate, heat up to 70°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 2 hours after the dropwise a...
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