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Improved 3 type slow release long-acting super-hydrophobic anti-contamination flashover coating

An anti-fouling flashover coating and super-hydrophobic technology, applied in the field of coatings, can solve the problems of low elongation, breaking strength and tear strength, easy aging service life, poor corrosion resistance, etc., and achieve salt spray aging resistance Good, excellent stain resistance, and the effect of improving mechanical properties

Active Publication Date: 2017-05-17
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, although the introduction of RTV coatings has alleviated the increasingly serious pollution flashover problem in power systems, the performance of current RTV coatings is still low. First, the coatings have weak adhesion, poor wear resistance, and poor corrosion resistance. Due to poor adhesion, In the process of maintenance, the coating is easy to detach due to the action of external force; secondly, due to the problem of its own structure and composition, its own mechanical properties, such as elongation, breaking strength and tear strength are all low, and it is easy to be damaged during actual use. Peeling, cracking, and falling off occur; thirdly, the surface of the current RTV paint is easy to absorb and accumulate dust. When the loose dirt reaches a certain thickness, the inside of the dirt is easy to form water flow channels and large-area stagnation areas, and finally forms flashover channel, leading to the occurrence of pollution flashover events; in addition, because RTV coatings not only have to withstand the effects of electric field and wind force, but also bear the erosion of temperature changes, rain, snow, frost and sunlight, the performance of RTV coatings gradually decreases with time. Small, easy to age and short service life, requires regular maintenance or even re-spraying, which brings great limitations to its use

Method used

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Experimental program
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Effect test

preparation example Construction

[0048] The preparation method of the improved Type 3 slow-release long-acting super-hydrophobic antifouling flashover coating of the present invention comprises the following steps:

[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and methylcyclosiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add dropwise Concentrated hydrochloric acid with a concentration of 37%, react for 1-2 hours after the dropwise addition, cool to 20-30°C, add ammonia water, adjust the pH to 6-7, and obtain hydrogen-terminated fluorine-containing polysiloxane; among them, trifluoropropyl The mass ratio of methylcyclotrisiloxane, tetramethyldisiloxane, methylcyclosiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~1:0.2~0.5;

[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 hours to obtain ...

Embodiment 1

[0057] An improved Type 3 slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, hydrophobic Type fumed silica 20kg, nano zinc oxide 3kg, oleyl amino oleate 2kg, wollastonite powder 4kg, ketoxime type crosslinking agent 1kg, dimethylaminopropylamine 5kg, silane coupling agent 1kg, aluminum hydroxide 3kg and organic Solvent 165kg;

[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of methylcyclosiloxane evenly, add 12.5kg of sodium sulfate, heat up to 60°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 1 hour after the dropwise ...

Embodiment 2

[0064] An improved type 3 slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 30kg of hydrogen-terminated polysiloxane, 65kg of 107 silicone rubber, hydrophobic Type fumed silica 30kg, nano zinc oxide 5kg, oleyl amino oleate 4kg, wollastonite powder 6kg, ketoxime type crosslinking agent 3kg, dimethylaminopropylamine 10kg, silane coupling agent 2kg, aluminum hydroxide 6kg and organic Solvent 175kg;

[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of methylcyclosiloxane evenly, add 10kg of sodium sulfate, heat up to 70°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react for 2 hours after the dropwise a...

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PUM

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Abstract

The invention discloses an improved 3 type slow release long-acting super-hydrophobic anti-contamination flashover coating which comprises the following raw materials in parts by weight: 35-45 parts of hydroxypropyl terminal fluorine-containing polysiloxane, 20-30 parts of hydrogen terminal polysiloxane, 55-65 parts of 107 silicone rubber, 20-30 parts of hydrophobic fumed silica, 3-5 parts of nanometer zinc oxide, 2-4 parts of oil amino oleate, 4-6 parts of wollastonite powder, 1-3 parts of ketoxime cross-linking agent, 5-10 parts of dimethylamino propylamine, 1-2 parts of silane coupling agent, 3-6 parts of aluminum hydroxide and 165-175 parts of organic solvent. The improved 3 type slow release long-acting super-hydrophobic anti-contamination flashover coating disclosed by the invention has the advantages of strong mechanical property, long service life as long as 15 years, excellent fire resistance reaching up to FV-1 level, excellent salt spray and ageing resistance, excellent stain resistance, capability of acting under haze polluted weather, capability of achieving expected anti-contamination flashover effect and capability of preventing contamination flashover accident from happening.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to an improved Type 3 slow-release long-acting super-hydrophobic antifouling flashover coating. Background technique [0002] Pollution flashover accidents involve a wide range of areas, and the power outage lasts for a long time, which seriously threatens the operation safety of power transmission and transformation equipment. Especially in winter, there are thousands of pollution flashover trips in the national power grid, sometimes almost causing the provincial power grid to be disconnected. The anti-fouling flashover measures are nothing more than four main measures: taking measures to adjust creepage, cleaning insulators, using synthetic insulators, and coating RTV paint (room temperature vulcanized silicone rubber). Comprehensive investigation and comparison of the above anti-fouling flashover measures, it can be seen that coating RTV paint is the most economical and effectiv...

Claims

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Application Information

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IPC IPC(8): C09D183/06C09D183/08C09D183/05C09D7/12C09D5/16
CPCC08L2205/02C08L2205/03C09D5/16C09D7/61C09D7/63C09D183/06C08L83/08C08L83/04C08K13/02C08K3/36C08K2003/2296C08K5/17C08K5/54C08K2003/2227
Inventor 冯迎春王震袁森冯海清卢志鹏黄锐王洪川孙兆国惠杰杨靖波杜远
Owner STATE GRID CORP OF CHINA
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