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A kind of rapid prototyping material for three-dimensional printing and its preparation method

A technology for 3D printing and molding materials, applied in the field of 3D printing, can solve the problems of affecting the efficiency of rapid prototyping of 3DP technology, the accuracy of printed parts, the difficulty of ensuring the accuracy of printed parts, and the slow hardening speed of gypsum powder. The processing process, the use method is simple, and the effect is conducive to market promotion

Active Publication Date: 2019-04-19
ZHONGBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] For ordinary gypsum powder, although it can be hardened when exposed to water, the hardening time takes 7 to 8 minutes. The hardening speed is too slow to provide a certain strength support in the shortest time to ensure the local molding of the mold, which affects the rapid prototyping of 3DP technology. Work efficiency and accuracy of printed parts
In addition, since 3DP technology is formed by bonding the powder layer by layer by spraying a binder, there are a large number of pores on the surface and inside of the printed part, and the compressive strength is less than 2MPa, so the use is severely limited
[0006] CN 1850694A discloses a gypsum-based material system for three-dimensional spraying and bonding and its preparation method. The prepared material has high precision and small dimensional deformation, but has the disadvantages of poor water resistance and insufficient strength. At the same time, printing for the preparation of the material is still required post-processing
[0007] CN 103992088A discloses a rapid prototyping powder for three-dimensional printing and its preparation method and application. It adds thermoplastic resin and other powders that are in a molten state when heated to the gypsum-based powder material, and then heats the printed part through post-processing Improve the strength, but the hardening speed of gypsum powder is slow, it is difficult to ensure the accuracy of printed parts
[0008] CN 103709917A discloses a post-treatment liquid for three-dimensional printing devices and its preparation method and application, which can effectively improve the strength of the device by soaking the three-dimensional printing device in two kinds of post-treatment liquids and then taking it out for heat treatment. However, the operation steps are very cumbersome, and the device needs to be soaked in two kinds of treatment solutions successively to achieve the enhanced effect.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Weigh 800g gypsum powder (commercially available α-calcium sulfate hemihydrate, product average particle size 65µm, whiteness 93%, initial setting time 6.5min, 3h flexural strength 5.5MPa), 150g gellan gum powder, 15g gas phase dioxide Mix the silicon powder evenly, ball mill for 4 hours at room temperature, then add 35g of sodium alginate (of which β - D -mannuronic acid unit with α - L - The molar ratio of guluronic acid units is 0.35) mixed ball mill for 2 hours, and passed through a 180-mesh sieve to obtain a modified gypsum-based powder material modified with sodium alginate, with a particle size range of 1-80 µm and a bulk density of 0.98 g / cm 3 , real density 2.80g / cm 3 , powder flow rate 5.5g / s, hardening speed 80s.

[0034] Prepare a 0.2mol / L calcium chloride solution as an aqueous binder.

[0035] Take the above-mentioned modified gypsum-based powder material and water-based adhesive liquid, and conduct a machine test on the PJ660 rapid prototyping printe...

Embodiment 2

[0038] Weigh 850g gypsum powder (commercially available α-calcium sulfate hemihydrate, average particle size 80µm, whiteness 92%, initial setting time 7min, 3h flexural strength 6.5MPa), 120g agarose gel powder, 10g gas phase dioxide Mix the silicon powder evenly, ball mill for 6 hours at room temperature, then add 20g of sodium alginate (of which β - D -mannuronic acid unit withα - L - The molar ratio of guluronic acid units is 0.85) mixed with ball mill for 1 hour, and passed through a 180-mesh sieve to obtain a modified gypsum-based powder material modified with sodium alginate, with a particle size range of 1-80 µm and a bulk density of 1.09 g / cm 3 , real density 3.02g / cm 3 , powder flow rate 5.3g / s, hardening speed 90s.

[0039] Prepare a 0.2mol / L zinc chloride solution as an aqueous binder.

[0040] Take the above-mentioned modified gypsum-based powder material and water-based adhesive liquid, and carry out the machine test on the PJ660 rapid prototyping printer prod...

Embodiment 3

[0043] Weigh 750g gypsum powder (commercially available α-calcium sulfate hemihydrate, product average particle size 80µm, whiteness 92%, initial setting time 7min, 3h flexural strength 6.5MPa), 150g cardlan gum powder, 10g gas phase dioxide Mix the silicon powder evenly, ball mill for 6 hours at room temperature, then add 90g of sodium alginate (of which β - D -mannuronic acid unit with α - L - The molar ratio of guluronic acid units is 1.05) mixed ball mill for 3 hours, and passed through a 180-mesh sieve to obtain a modified gypsum-based powder material modified with sodium alginate, with a particle size range of 1-80 µm and a bulk density of 0.91 g / cm 3 , the real density is 2.73g / cm 3 , The powder flow rate is 4.3g / s, and the hardening speed is 65s.

[0044] Prepare a 0.3mol / L aluminum chloride solution as an aqueous binder.

[0045] Take the above-mentioned modified gypsum-based powder material and water-based adhesive liquid, and carry out the machine test on the P...

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Abstract

The invention discloses a rapid prototying material for three-dimensional printing. The rapid prototying material for three-dimensional printing comprises modified gypsum-based powder material, and an aequous adhesive for prototying the powder material, wherein the modified gypsum-based powder material comprises 70-85% of gypsum powder, 5-15% of a polysaccharide gel particle, 5-10% of sodium alginate, and 0.5-5% of additive; the aqueous adhesive is a water aqueous containing high-valence cations. The rapid prototying material for three-dimensional printing is fast to harden, and high in prototying precision; a prepared printing product is high in pressure resistance and high in waterproofing performance, and can be applied to the fields of medial model manufacturing, industrial die manufacturing, building design, and the like.

Description

technical field [0001] The invention belongs to the technical field of three-dimensional printing, and relates to a three-dimensional printing rapid prototyping material and a preparation method of the material. Background technique [0002] With the rapid development of modern science and technology, the society pays more and more attention to production efficiency. Manufacturing enterprises must design products that meet more requirements and have higher cost performance within the shortest possible research and development cycle, in order to seize the opportunity in the fierce market competition. The development and trial production of new products using traditional manufacturing techniques requires a number of high-level skilled workers to use a variety of machining equipment and tools, which is not only costly but also long-term, and it is difficult to adapt to the rapidly developing market requirements. [0003] 3D printing rapid prototyping (Three Dimension Printing, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/14C04B38/00B33Y70/00B33Y10/00B28B1/00B28B17/02B28B11/24C04B24/38C04B16/04
CPCB28B1/001B28B11/243B28B17/023B33Y10/00B33Y70/00C04B28/146C04B2201/50C04B24/38C04B16/04C04B14/066C04B22/124C04B38/00C04B22/12
Inventor 刘炜白培康王建宏张浩谭乐闫国伟
Owner ZHONGBEI UNIV