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An improved slow-release long-lasting super-hydrophobic antifouling flashover coating

An antifouling flashover coating and super-hydrophobic technology, applied in the field of coatings, can solve problems such as low elongation, low breaking strength and tear strength, easy aging service life, weak coating adhesion, etc., to reduce the impact of static electricity, strong Electron-attracting property, no effect of corona discharge

Active Publication Date: 2019-07-05
STATE GRID CORP OF CHINA +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, although the introduction of RTV coatings has alleviated the increasingly serious pollution flashover problem in power systems, the performance of current RTV coatings is still low. First, the coatings have weak adhesion, poor wear resistance, and poor corrosion resistance. Due to poor adhesion, In the process of maintenance, the coating is easy to detach due to the action of external force; secondly, due to the problem of its own structure and composition, its own mechanical properties, such as elongation, breaking strength and tear strength are all low, and it is easy to be damaged during actual use. Peeling, cracking, and falling off occur; thirdly, the surface of the current RTV paint is easy to absorb and accumulate dust. When the loose dirt reaches a certain thickness, the inside of the dirt is easy to form water flow channels and large-area stagnation areas, and finally forms flashover channel, leading to the occurrence of pollution flashover events; in addition, because RTV coatings not only have to withstand the effects of electric field and wind force, but also bear the erosion of temperature changes, rain, snow, frost and sunlight, the performance of RTV coatings gradually decreases with time. Small, easy to age and short service life, requires regular maintenance or even re-spraying, which brings great limitations to its use

Method used

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  • An improved slow-release long-lasting super-hydrophobic antifouling flashover coating

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preparation example Construction

[0048] The preparation method of the improved slow-release long-acting super-hydrophobic antifouling flashover coating of the present invention comprises the following steps:

[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and methylcyclosiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add dropwise Concentrated hydrochloric acid with a concentration of 37%, react for 1-2 hours after the dropwise addition, cool to 20-30°C, add ammonia water, adjust the pH to 6-7, and obtain hydrogen-terminated fluorine-containing polysiloxane; among them, trifluoropropyl The mass ratio of methylcyclotrisiloxane, tetramethyldisiloxane, methylcyclosiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~1:0.2~0.5;

[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 hours to obtain hydroxy...

Embodiment 1

[0057] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, and hydrophobic gas-phase 20kg of white carbon black, 3kg of nano zinc oxide, 2kg of ethyl oleate, 4kg of diatomaceous earth, 1kg of ketoxime type crosslinking agent, 5kg of dimethylaminopropylamine, 1kg of silane coupling agent, 3kg of magnesium hydroxide and 165kg of organic solvent;

[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of methylcyclosiloxane evenly, add 12.5kg of sodium sulfate, heat up to 60°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react fo...

Embodiment 2

[0064] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45 kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 30 kg of hydrogen-terminated polysiloxane, 65 kg of 107 silicone rubber, and hydrophobic gas-phase 30kg of white carbon black, 5kg of nano zinc oxide, 4kg of ethyl oleate, 6kg of diatomaceous earth, 3kg of ketoxime type crosslinking agent, 10kg of dimethylaminopropylamine, 2kg of silane coupling agent, 6kg of magnesium hydroxide and 175kg of organic solvent;

[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:

[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of methylcyclosiloxane evenly, add 10kg of sodium sulfate, heat up to 70°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react f...

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Abstract

The invention discloses an improved type 2 slow-release long-acting superhydrophobic anti-pollution flashover coating. The improved type 2 slow-release long-acting superhydrophobic anti-pollution flashover coating is prepared from the following raw materials in parts by weight: 35 to 45 parts of hydroxypropyl-terminated fluorine-containing polysiloxane, 20 to 30 parts of hydrogen-terminated polysiloxane, 55 to 65 parts of silicone rubber 107, 20 to 30 parts of hydrophobic gas phase white black carbon, 3 to 5 parts of nanometer zinc oxide, 2 to 4 parts of ethyl oleate, 4 to 6 parts of diatomite, 1 to 3 parts of ketoxime type crosslinking agent, 5 to 10 parts of dimethyl aminopropyl amine, 1 to 2 parts of silane coupling agent, 3 to 6 parts of magnesium hydroxide, and 165 to 175 parts of organic solvent. The improved type 2 slow-release long-acting superhydrophobic anti-pollution flashover coating has the advantages that the mechanical property is strong, the service life is long and can reach 15 years, the flame-retardant property is good and can reach FV-0 class, the salt mist aging-resistant property is good, the anti-pollution property is excellent, the validity is still realized in the haze pollution weather, the expected anti-pollution flashover effect is realized, and the pollution flashover accident is avoided.

Description

technical field [0001] The invention relates to the technical field of coatings, in particular to an improved slow-release long-acting super-hydrophobic antifouling flashover coating. Background technique [0002] Pollution flashover accidents involve a wide range of areas, and the power outage lasts for a long time, which seriously threatens the operation safety of power transmission and transformation equipment. Especially in winter, there are thousands of pollution flashover trips in the national power grid, sometimes almost causing the provincial power grid to be disconnected. The anti-fouling flashover measures are nothing more than four main measures: taking measures to adjust creepage, cleaning insulators, using synthetic insulators, and coating RTV paint (room temperature vulcanized silicone rubber). Comprehensive investigation and comparison of the above anti-fouling flashover measures, it can be seen that coating RTV paint is the most economical and effective measu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/06C09D183/08C09D183/05C09D5/16C09D5/18C09D7/61C08G77/38C08G77/12
CPCC08G77/12C08G77/38C08K2201/011C08L2201/02C08L2205/02C08L2205/03C09D5/1675C09D5/18C09D7/61C09D7/62C09D7/63C09D7/70C09D183/06C08L83/08C08L83/04C08K13/06C08K9/04C08K3/36C08K7/26C08K2003/2296C08K2003/2224
Inventor 冯迎春乔耀华袁森杜远韩正新王洪川王震冯海清卢志鹏黄锐周洋
Owner STATE GRID CORP OF CHINA
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