An improved slow-release long-lasting super-hydrophobic antifouling flashover coating
An antifouling flashover coating and super-hydrophobic technology, applied in the field of coatings, can solve problems such as low elongation, low breaking strength and tear strength, easy aging service life, weak coating adhesion, etc., to reduce the impact of static electricity, strong Electron-attracting property, no effect of corona discharge
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[0048] The preparation method of the improved slow-release long-acting super-hydrophobic antifouling flashover coating of the present invention comprises the following steps:
[0049] ① Stir trifluoropropylmethylcyclotrisiloxane, tetramethyldisiloxane and methylcyclosiloxane evenly, add sodium sulfate, stir evenly, heat up to 60~70°C, and then add dropwise Concentrated hydrochloric acid with a concentration of 37%, react for 1-2 hours after the dropwise addition, cool to 20-30°C, add ammonia water, adjust the pH to 6-7, and obtain hydrogen-terminated fluorine-containing polysiloxane; among them, trifluoropropyl The mass ratio of methylcyclotrisiloxane, tetramethyldisiloxane, methylcyclosiloxane, sodium sulfate and concentrated hydrochloric acid is 4~6:1:10~15:0.5~1:0.2~0.5;
[0050] ② Stir the hydrogen-terminated fluorine-containing polysiloxane and methallyl alcohol obtained in step ① evenly, then add metal nickel, heat up to 80-90°C, and react for 1-2 hours to obtain hydroxy...
Embodiment 1
[0057] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 35kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 20kg of hydrogen-terminated polysiloxane, 55kg of 107 silicone rubber, and hydrophobic gas-phase 20kg of white carbon black, 3kg of nano zinc oxide, 2kg of ethyl oleate, 4kg of diatomaceous earth, 1kg of ketoxime type crosslinking agent, 5kg of dimethylaminopropylamine, 1kg of silane coupling agent, 3kg of magnesium hydroxide and 165kg of organic solvent;
[0058] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:
[0059] ①Stir 100kg of trifluoropropylmethylcyclotrisiloxane, 25kg of tetramethyldisiloxane and 250kg of methylcyclosiloxane evenly, add 12.5kg of sodium sulfate, heat up to 60°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react fo...
Embodiment 2
[0064] An improved slow-release long-lasting super-hydrophobic anti-fouling flashover coating, which is composed of the following raw materials: 45 kg of hydroxypropyl-terminated fluorine-containing polysiloxane, 30 kg of hydrogen-terminated polysiloxane, 65 kg of 107 silicone rubber, and hydrophobic gas-phase 30kg of white carbon black, 5kg of nano zinc oxide, 4kg of ethyl oleate, 6kg of diatomaceous earth, 3kg of ketoxime type crosslinking agent, 10kg of dimethylaminopropylamine, 2kg of silane coupling agent, 6kg of magnesium hydroxide and 175kg of organic solvent;
[0065] The hydroxypropyl-terminated fluorine-containing polysiloxane is obtained according to the following steps:
[0066] ①Stir 60kg of trifluoropropylmethylcyclotrisiloxane, 10kg of tetramethyldisiloxane and 150kg of methylcyclosiloxane evenly, add 10kg of sodium sulfate, heat up to 70°C after stirring evenly, and then add Add 5kg of concentrated hydrochloric acid with a concentration of 37% dropwise, react f...
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