Device and method for producing marsh gas by vinegar residue solid and liquid split-phase anaerobic digestion

A technology of anaerobic digestion and solid-liquid phase separation, applied in biochemical equipment and methods, methods of supporting/immobilizing microorganisms, sterilization methods, etc. Solve problems such as crusting and floating of vinegar residues, and achieve the effects of improving heat utilization efficiency, improving capacity, and increasing damage degree

Inactive Publication Date: 2017-05-31
CHANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Anaerobic digestion includes 4 processes: extracellular hydrolysis, acid production, acetogenic production and methanogenic production. Traditional single-phase anaerobic digestion can only handle low concentration of fermentation raw materials (less than 20%), and the residue of vinegar grains is not easy to Decomposition and rich acetic acid content, single-phase anaerobic digestion methane production process in a single reactor is likely to cause crusting and floating of vinegar grains, and the system is easy to acidify, resulting in low stability and gas production efficiency of vinegar grains biogas fermentation
[0004] Vinegar grains raw materials are raw materials with high organic acid content, and the methanogenic process of the entire anaerobic digestion process is the rate-limiting step, which leads to organic acid inhibition and long lag period when vinegar grains are subjected to single-phase continuous anaerobic digestion treatment
To avoid organic acid inhibition, conventional single-phase anaerobic digestion can only be run at lower loads with lower yields

Method used

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  • Device and method for producing marsh gas by vinegar residue solid and liquid split-phase anaerobic digestion
  • Device and method for producing marsh gas by vinegar residue solid and liquid split-phase anaerobic digestion

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Embodiment 1

[0037] Such as figure 1 As shown, a device for producing biogas by solid-liquid phase separation anaerobic digestion of vinegar residues mainly includes a solid-state fermentation tank 2, a high-temperature digester 4, a packing reactor 6, a biogas purifier 9, a solid-liquid separator 11 and a storage tank 5, 8; the bottom end of the solid-state fermentation tank 2 is connected to one end of the reservoir A5, the upper end of the solid-state fermentation tank 2 is fixedly installed with a spray head 1, and the lower end is placed with a solid percolation bed 3; the other end of the reservoir A5 It is connected with the bottom of the packing reactor 6, and the position of the packing reactor 6 is equipped with a fibrous packing 7, and methanogenic bacteria are attached to the fibrous packing 7, and the liquid outlet at the upper end of the packing reactor 6 is connected to the reservoir B8, and the packing reactor 6 The liquid outlet at the upper end is located above the fiber ...

Embodiment 2

[0056] Experimental group: Using the washed vinegar grains after high-temperature hydrothermal treatment and washing liquid as raw materials, a 25L solid-state fermenter 2 and a 25L packed reactor 6 were used for solid-liquid phase separation anaerobic fermentation. Add the pre-acclimated biogas fermentation inoculum and keep it stable for one week. After the gas production of the system inoculum is basically zero, feed according to the organic load of 1.0gVS / L.d ​​and 1.0g COD / L.d respectively. The initial pH values ​​in the solid-state fermenter 2 and the packing reactor 6 were determined to be in the range of 6.5 to 8, and within 30 days of the first load operation, the methane content was in the range of 55% to 65%, and the pH value was stable at 6.5 to 8 within range.

[0057] In the second stage of fermentation load, that is, during the 31st to 60th day of operation, the organic load of 2.0g VS / L.d ​​and 2.0g COD / L.d was fed, the methane content was in the range of 55% t...

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Abstract

The invention relates to a device and a method for producing marsh gas by vinegar residue solid and liquid split-phase anaerobic digestion, and belongs to the technical field of biological fermenting. The device mainly comprises a solid-state fermenting tank, a high-temperature boiler, a filler reactor, a marsh gas purifier, a solid and liquid separator, and a water storage tank. The invention also discloses a method using the device to produce marsh gas by the vinegar residue solid and liquid split-phase anaerobic digestion. The method mainly comprises the following steps of (1) spraying and washing vinegar residue by water in the solid-state fermenting tank; (2) performing high-temperature hydrothermal treatment on the filtered water-washing vinegar residue; (3) performing medium-temperature vinegar residue fermentation on water washing liquid; (4) performing high-temperature solid-state fermentation; (5) purifying and utilizing the marsh gas. The device and the method have the characteristics that the vinegar residue solid and liquid split-phase anaerobic digestion is realized, the content of organic acid in the vinegar residue is high, the water washing and separation are easy, and the like; in the fermenting process, the adding of other raw materials is not needed, the hydrothermal circulation is realized, the cost is reduced, the traditional vinegar residue anaerobic digestion is broken, and the production capacity of marsh gas is increased.

Description

technical field [0001] The invention relates to waste biofermentation technology, in particular to a device and method for anaerobic digestion of vinegar lees solid-liquid phase separation to produce biogas, belonging to the field of biofermentation technology. Background technique [0002] Vinegar grains are organic wastes discharged during the production of vinegar using grain raw materials. In recent years, with the vigorous development of the national vinegar industry, the annual production and discharge of vinegar grains has reached 3 million tons, which is highly acidic (the content of acetic acid is 36000mg / kg ), high crude cellulose content (25.78% (dry basis)), low crude protein content (12.79% (dry basis)), difficult to decompose and so on. The above characteristics lead to some problems in the current treatment methods of vinegar grains. For example, a small part of vinegar grains is used as animal feed and edible fungus cultivation material, and the drying cost a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12M1/16C12M1/12C12M1/107C12M1/02C12P5/02
CPCC12M21/04C12M21/16C12M23/58C12M29/02C12M29/06C12M41/22C12M45/04C12M45/20C12M47/18C12P5/023Y02E50/30
Inventor 袁浩然冉根柱李东陈琳陈勇郑涛刘晓风何明阳
Owner CHANGZHOU UNIV
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