A kind of high-performance nylon-based dyeable conductive fiber and its preparation method

A conductive fiber, nylon-based technology, applied in the field of high-performance nylon-based dyeable conductive fibers and their preparation, can solve problems such as gaps in electrical conductivity and poor electrical conductivity, and achieve improved fluidity, improved mechanical strength, and enhanced electrical conductivity. Effect

Active Publication Date: 2019-02-22
CTA HIGH TECH FIBER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the conductivity of the white conductive component is poorer than that of conductive carbon black, there is still a big gap between the conductive performance of this method and that of carbon black conductive fibers.

Method used

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  • A kind of high-performance nylon-based dyeable conductive fiber and its preparation method
  • A kind of high-performance nylon-based dyeable conductive fiber and its preparation method
  • A kind of high-performance nylon-based dyeable conductive fiber and its preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0050] In this embodiment, the white conductive component titanium dioxide is doped with antimony: polyester block polyamide: nylon PA6 (melt index 25g / 10min, 235°C, 2.16kg)=21%: 70%: 9%, antioxidant The contents of 1098 and stabilizer 168 are each 0.16%, and the content of dispersing lubricant (polyethylene wax) is 0.6%. When blending and granulating, the screw temperature is 220°C, the screw speed is 500rpm, and the melt index of the masterbatch is 35g / 10min (230°C, 2.16kg); ): titanium dioxide (random distribution of particle size 70-700nm): ether ester imide = 62.5%: 20%: 17.5%, coupling agent (ethylene dioxydioleoyl titanate) content 1.2%, blending When granulating, the screw temperature is 260°C, the screw speed is 500rpm, and the melt index of the masterbatch is 27g / 10min (230°C, 2.16kg); the conductive carbon black of the highly conductive medium carbon black component: nylon=32%:68%, antioxidant 1098 The content of stabilizer 168 is 0.25%, and the dispersing lubrican...

Embodiment 2

[0052] In this embodiment, the white conductive component titanium dioxide is doped with antimony: polyester block polyamide: nylon PA12 (melt index 30g / 10min, 235°C, 2.16kg) = 20%: 70%: 10%, antioxidant The contents of 1098 and stabilizer 168 are each 0.20%, and the content of dispersing lubricant (polyethylene wax) is 1.65%. When blending and granulating, the screw temperature is 215°C, the screw speed is 600rpm, and the melt index of the masterbatch is 38g / 10min (230°C, 2.16kg); ): titanium dioxide (random distribution of particle size 70~700nm): dimethyl hexadecyl ammonium chloride=65.5%: 22.5%: 12%, coupling agent (vinyl triethoxysilane) content 0.7%, total During mixing and granulation, the screw temperature is 245°C, the screw speed is 350rpm, and the melt index of the masterbatch is 25g / 10min (230°C, 2.16kg); the conductive carbon black of the high conductive medium carbon black component: nylon=33.5%: 66.5%, anti-oxidation The contents of agent 1098 and stabilizer 16...

Embodiment 3

[0054]In the present embodiment, white conductive component titanium dioxide: polyurethane block polyamide: nylon PA66=15%: 80%: 5%, each 0.40% of antioxidant 1098 and stabilizer 168 content, dispersion lubricant (polyethylene wax ) content of 0.7%. When blending and granulating, the screw temperature is 245°C, and the screw speed is 450rpm; the masking compound material component nylon PA66: titanium dioxide (random distribution of particle size 70-700nm): N-picoline dipetaphosphate=60%: 15%: 25%, coupling agent (isopropyl, isostearyl diacryloyl titanate) content 0.6%, screw temperature 275°C during blending and granulation, screw speed 550rpm; high conductivity dielectric carbon black component conductive carbon black : nylon=15%: 85%, each 0.35% of antioxidant 1098 and stabilizer 168 content, 2.1% of dispersing lubricant zinc stearate. During blending and granulation, the screw temperature was 277° C., and the screw speed was 400 rpm. When spinning, the high-conductivity ...

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Abstract

The invention relates to a high-performance polyamide-based dyeable conductive fiber and a preparation method thereof, belonging to the field of composite conductive fibers. The fiber provided by the invention employs a three-layer concentric circle structure which comprises three components, i.e., a highly-conductive medium carbon black component, a shielding composite substance component and a white conductive component in a mass ratio of 5-30%: 20-30%: 50-65%, wherein an inner layer, a middle layer and an outer layer are the highly-conductive medium carbon black component, the shielding composite substance component and the white conductive component respectively, or are the highly-conductive medium carbon black component, the white conductive component and the shielding composite substance component respectively. The fiber provided by the invention has improved conductivity and maintains original whiteness and dyeability. According to the invention, a metal oxide and a conductive intrinsic polymer are blended and granulated during preparation of white dyeable conductive master batch, so the characteristics of the two white conductive additive are integrated; and polyamide carrier resin is added to adjust a fusion index, so fluidity is improved, and the conductivity of the eventually prepared fiber is improved.

Description

technical field [0001] The invention relates to a composite conductive fiber, in particular to a high-performance nylon-based dyeable conductive fiber and a preparation method thereof. Background technique [0002] In recent years, with the vigorous development of polymer materials, the three major synthetic fibers - polyester, nylon, acrylic and polypropylene, a rising star, have occupied an important position in the fiber market due to their excellent performance. However, the surface of synthetic fibers can only be wetted by liquid whose critical surface tension is smaller than itself, and its volume resistivity is mostly 10 13 More than Ω·cm, so synthetic fibers are prone to static electricity. The existence of static electricity makes it easier for clothes to absorb dust and entangle each other, which seriously affects the production of high-precision instruments, biomedicine, food and other industries, and also increases the possibility of fire and explosion in flamma...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/12D01F1/09D01F1/10D01D1/04D01D5/30
Inventor 李睿焦红娟刘建兵高扬杨春喜王颢王双燕曹占理杨德林赵静波张莹
Owner CTA HIGH TECH FIBER
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