Self-crosslinking type waterproof emulsion, preparation method of waterproof emulsion and waterproof base film prepared by utilizing waterproof emulsion

A waterproof emulsion and self-crosslinking technology, used in anti-corrosion coatings, coatings, etc., can solve the problems of shortening the service life of wall decoration materials, inconvenient production, packaging, transportation, and complicated on-site operation of base film, and achieve strong bonding force. , the effect of long storage time, hardness and strength improvement

Active Publication Date: 2017-06-09
GUANGDONG YULAN GRP
View PDF5 Cites 11 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, as there are more and more problems in today's buildings, the problems of cracks and water seepage are becoming more and more serious. Ordinary base film products cannot cope with such a harsh wall environment, which greatly shortens the use of wall decoration materials. life
[0003] There are also some base films with waterproof function on the market, some are solvent-based waterproof base films, and their environmental friendliness is poor; some replace solvent-based base films with water-based waterproof base films. Difference
At the same time, a two-component waterproof base film with excellent waterproof performance and good environmental protection performance has also appeared. However, this type of base film is relatively complicated and has high requirements for on-site operations, because the A\B of the base film must be adjusted befor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] The self-crosslinking waterproof emulsion of this embodiment includes the following raw materials in parts by weight: 20 parts of polyisocyanate, 20 parts of oligomer polyol, 15 parts of chain extender, 20 parts of blocking agent, 0.2 part of catalyst, and comonomer 55 parts, 5 parts of emulsifier, 5 parts of initiator, 5 parts of pH adjuster, 8 parts of deionized water, comonomer is hard monomer, soft monomer and functional monomer have a mass ratio of 20:12: Mix of 8.

[0061] Wherein, the blocking agent is methyl ethyl ketoxime. Among them, the catalyst is an organotin compound catalyst: dibutyltin dilaurate. Among them, the emulsifier is a composite emulsifier in which ammonium perfluorooctanoate and sodium lauryl sulfate are mixed at a mass ratio of 1:1. Among them, the initiator is potassium persulfate. Wherein, the pH adjusting agent is ammonia water. The oligomer polyol is 1,4-cyclohexanedimethanol, polyethylene adipate, polycarbonate diol and polyoxypropylene ...

Embodiment 2

[0068] The self-crosslinking waterproof emulsion of this embodiment includes the following raw materials in parts by weight: 40 parts of polyisocyanate, 50 parts of oligomer polyol, 25 parts of chain extender, 35 parts of blocking agent, 3 parts of catalyst, and comonomer 65 parts, 12 parts of emulsifier, 8 parts of initiator, 10 parts of pH adjuster, 36 parts of deionized water, the mass ratio of comonomer is hard monomer, soft monomer and functional monomer is 43:18: 18's mix.

[0069] Wherein, the capping agent is a mixture of hydroxyethyl acrylate and hydroxyethyl methacrylate in a mass ratio of 1:3.5. Among them, the catalyst is an organotin compound catalyst: stannous octoate. Among them, the emulsifier is a mixture of ammonium perfluorooctanoate and sodium lauryl sulfate in a mass ratio of 3:1.5. Among them, the initiator is ammonium persulfate. Wherein, the pH adjusting agent is ammonia water. The oligomer polyol is 1,4-cyclohexanedimethanol, polycaprolactone diol, po...

Embodiment 3

[0076] The self-crosslinking waterproof emulsion of this embodiment includes the following raw materials in parts by weight: 30 parts of polyisocyanate, 20 parts of oligomer polyol, 14 parts of chain extender, 26 parts of end-capping agent, 2.0 parts of catalyst, and comonomer 45 parts, 8 parts of emulsifier, 9 parts of initiator, 6 parts of pH adjuster, 55 parts of deionized water, the mass ratio of comonomer is hard monomer, soft monomer and functional monomer 35:16: 13's mix.

[0077] Wherein, the end-capping agent is a mixture of hydroxyethyl acrylate, hydroxyethyl methacrylate and caprolactam in a mass ratio of 1:3:6. Among them, the catalyst is a tertiary amine compound: N,N-dimethylcyclohexylamine. Among them, the emulsifier is a mixture of ammonium perfluorooctanoate and sodium lauryl sulfate in a mass ratio of 2:7. Among them, the initiator is ammonium persulfate. Wherein, the pH adjusting agent is ammonia water. The oligomer polyol is a mixture of 1,4-cyclohexanedim...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the technical field of film-forming materials and in particular relates to a self-crosslinking type waterproof emulsion, a preparation method of the waterproof emulsion and a waterproof base film prepared by utilizing the waterproof emulsion. The emulsion comprises the following raw materials in parts by weight: polyisocyanates, low polymer polyols, a chain extender, an end-capping reagent, a catalyst, a comonomer, an emulsifier, an initiator, a pH regulator and deionized water, wherein the comonomer is a mixture of a hard monomer, a soft monomer and a functional monomer according to a mass part ratio of (30-50):(10-20):(5-20). The emulsion can realize self-crosslinking and is high in crosslinking degree and high in weather resistance; the preparation method is simple in preparation process, and the environmental pollution is avoided in the preparation process; and the prepared waterproof base film is high in crosslinking degree, high in water resistance, high in impact resistance, high in tear resistance and high in binding force with the base surface and has relatively high flexibility and high weather resistance.

Description

Technical field [0001] The invention relates to the technical field of film forming materials, in particular to a self-crosslinking type waterproof emulsion, a preparation method thereof, and a waterproof base film prepared by using the waterproof emulsion. Background technique [0002] In the prior art, the base film is a wall surface treatment material with anti-alkali, moisture-proof, and mildew-proof functions, which can effectively prevent the moisture and alkaline substances from the construction base surface from leaking out, and avoid the wall decoration materials: Bad damage to wallpaper, paint layer, plywood, decorative board, such as dampness, mildew and black. However, as there are more and more problems in buildings nowadays, cracks and water seepage problems are getting more and more serious. Ordinary base film products cannot cope with such a harsh wall environment at all, which greatly reduces the use of wall decoration materials. life. [0003] There are also som...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08F283/00C08F290/06C08F220/32C08F230/08C08F2/26C08G18/67C08G18/66C08G18/42C08G18/48C08G18/44C08G18/32C08G18/28C09D151/08C09D5/08C09D7/12
CPCC08F2/26C08F283/006C08F290/067C08G18/286C08G18/3206C08G18/3855C08G18/4018C08G18/4238C08G18/44C08G18/4829C08G18/6611C08G18/6618C08G18/672C08L2201/08C08L2205/02C08L2205/035C08L2312/00C09D5/08C09D7/63C09D7/65C09D151/08C08F230/08C08G18/6625C08G18/6651C08L83/04C08L33/00
Inventor 张小琼陆勇新刘亮
Owner GUANGDONG YULAN GRP
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products