Cerium-zirconium compound oxide loading platinum catalyst as well as preparation method and application thereof
A composite oxide and catalyst technology, applied in metal/metal oxide/metal hydroxide catalysts, physical/chemical process catalysts, chemical instruments and methods, etc. The problem of uneven size distribution can achieve the effect of simple and easy preparation method, high resistance to high temperature sintering, and easy control of the preparation process.
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Embodiment 1
[0050] This embodiment provides a method for preparing a catalyst of platinum nanoparticles supported on cerium-zirconium composite oxide, the method comprising the following steps:
[0051] 1. The cerium-zirconium composite oxide of nanorod structure is prepared, comprising the following steps:
[0052] a, 1.49g of cerous nitrate and 0.16g of zirconium nitrate were dissolved in 5mL of water to obtain a cerium-zirconium salt solution;
[0053] B, the sodium hydroxide of 14.4g is dissolved with 55mL water, obtains sodium hydroxide solution;
[0054] c. Add the sodium hydroxide solution obtained in step b dropwise to the cerium-zirconium salt solution obtained in step a in the stirring state, and continue stirring for 1 h after the dropwise addition is completed;
[0055] d. Transfer the mixed solution obtained in step c to a 100mL hydrothermal crystallizer for crystallization at a constant temperature of 100°C for 24h, and then naturally cool down to room temperature;
[0056...
Embodiment 2
[0066] This embodiment provides the Rod-Ce that embodiment 1 prepares 0.9 Zr 0.1 o 2 and Pt / Rod-Ce 0.9 Zr 0.1 o 2 The application in the combustion of particulate matter emitted by motor vehicles is to investigate the catalytic activity of the above-mentioned catalyst.
[0067] Catalyst activity evaluation method:
[0068] The activities of the above two catalysts were evaluated using a fixed-bed microreactor-gas chromatography detection system.
[0069] Specific parameters in the application process: the dosage of the above catalyst samples is 100 mg, and the mass ratio of catalyst to adsorption carbon is 10:1.
[0070] Specific steps: put the above-mentioned catalyst and adsorption carbon weighed in a small beaker, stir evenly with a medicine spoon, make the catalyst loosely contact with the particles, put the above-mentioned catalyst and adsorption carbon into a 6mm quartz reaction tube, and control the gas The flow rate is 50mL / min, the volume content of NO in the g...
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