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Preparation method of dye-sensitized solar battery photo-anode material

A solar cell and dye sensitization technology, which is applied in the field of solar cell material preparation, can solve the problems of reducing transmission and recombination impedance, insufficient photoelectric effect, and small dye absorption, so as to improve photoelectric conversion efficiency, reduce dark current, and prepare steps simple effect

Active Publication Date: 2017-06-13
盐城滨瀚新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem to be solved by the present invention: for the existing TiO prepared with flexible plastic film as the substrate 2 thin film TiO 2 The connection between particles and between particles and the conductive substrate is poor, the amount of dye absorption is small, and the photoelectric effect is insufficient. It provides a titanium dioxide film loaded with high specific surface area titanium dioxide colloid and prepared with an inverse opal structure to improve the material. In the method of photoelectric effect, the present invention uses tetrabutyl titanate as a precursor, acetic acid solution as a hydrolysis inhibitor, and nitric acid solution as a peptizer to prepare nano-titanium dioxide colloid, and then coat the titanium dioxide colloid on the surface of a high-impedance ITO conductive film, and dry After that, it is mixed with methyl methacrylate solution and polymerized to grow on the surface of the conductive film. After being washed with ethanol, it is soaked in the dye N719 ethanol solution for absorption, rinsed with ethanol and cured, and then dried naturally to prepare the photoanode material. The dye-sensitized solar cell photoanode material prepared by the invention effectively reduces the transmission and recombination impedance of electrons on the film, and has excellent photoelectric conversion efficiency

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0017] First, at a mass ratio of 1:10, tetrabutyl titanate and a mass fraction of 5% acetic acid solution were stirred and mixed for 10 minutes, then after standing for 6 hours, and after ultrasonic dispersion at 200W for 10 minutes, the dispersion liquid was collected, and the mass ratio was 1:8. , add 70% nitric acid and nitric acid to the dispersion, and heat it in a water bath at 75 °C for 1 h; after the heating in the water bath is completed, collect the mixture, and then mix the mixture with deionized water at a mass ratio of 1:10. , then heated in an oil bath at 200 °C for 10 h, then left to cool to room temperature, rotary evaporated to 1 / 5 of the original volume at 75 °C, collected the concentrate and centrifuged at 2500 r / min for 10 min, and removed the supernatant. And at a mass ratio of 1:10, the remaining mixture was stirred and mixed with a mass fraction of 50% ethanol solution to prepare a mixed slurry; the mixed slurry prepared above was evenly coated on the sur...

example 2

[0020] Firstly, at a mass ratio of 1:10, tetrabutyl titanate and a mass fraction of 5% acetic acid solution were stirred and mixed for 12 minutes, then after standing for 7 hours, and ultrasonically dispersed for 12 minutes at 250W, the dispersion liquid was collected at a mass ratio of 1:8 , add 70% nitric acid and nitric acid to the dispersion, and heat it in a water bath at 77 °C for 2 hours; after the heating in the water bath is completed, collect the mixture, and then mix the mixture with deionized water at a mass ratio of 1:10. , then heated in an oil bath at 250°C for 11h, then left to cool to room temperature, rotary evaporated to 1 / 5 of the original volume at 77°C, collected the concentrate and centrifuged at 2700r / min for 12min, and removed the supernatant And at a mass ratio of 1:10, the remaining mixture was stirred and mixed with a mass fraction of 50% ethanol solution to prepare a mixed slurry; the mixed slurry prepared above was evenly coated on the surface of a...

example 3

[0023] Firstly, at a mass ratio of 1:10, tetrabutyl titanate and a mass fraction of 5% acetic acid solution were stirred and mixed for 15 minutes, then after standing for 8 hours, and ultrasonically dispersed for 15 minutes at 300W, the dispersion liquid was collected at a mass ratio of 1:8 , add 70% nitric acid and nitric acid to the dispersion liquid, and heat it in a water bath at 80 °C for 2 hours; after the heating in the water bath is completed, collect the mixed liquid, and then stir and mix the mixed liquid with deionized water at a mass ratio of 1:10 , then heated in an oil bath at 300°C for 12h, then left to cool to room temperature, rotary evaporated to 1 / 5 of the original volume at 80°C, collected the concentrate and centrifuged at 3000r / min for 15min, and removed the supernatant And at a mass ratio of 1:10, the remaining mixture was stirred and mixed with a mass fraction of 50% ethanol solution to prepare a mixed slurry; the mixed slurry prepared above was evenly c...

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Abstract

The invention relates to a preparation method of a dye-sensitized solar battery photo-anode material, and belongs to the technical field of preparation of a solar battery material. According to the method, tetrabutyl titanate is used as a precursor; an acetic acid solution is used as a hydrolysis inhibitor; a nitric acid solution is used as a glue solvent; nanometer titanium dioxide colloid is prepared; then, the titanium dioxide colloid is coated on the surface of a high-impedance ITO (indium tin oxide) conductive film; after being dried, the material is mixed with a methyl methacrylate solution; the mixture performs polymerization and grows onto the surface of the conducting film; after being washed by ethyl alcohol, the material is soaked into a dye N719 ethyl alcohol solution for absorption; ethyl alcohol flushing and curing are performed; then, natural drying is performed; the photo-anode material is obtained through preparation. The dye-sensitized solar battery photo-anode material prepared by the method has the advantages that the transmission of electrons on the film and the composite impedance are effectively reduced; the excellent photo-electric conversion efficiency is realized.

Description

technical field [0001] The invention relates to a preparation method of a dye-sensitized solar cell photoanode material, and belongs to the technical field of solar cell material preparation. Background technique [0002] In today's economic globalization, the massive consumption of energy has become the most concerned issue. So far, natural gas, oil, coal and other energy sources still occupy the main position, but traditional energy can no longer meet the needs of sustainable economic development. Therefore, new renewable energy must be selected to get rid of the shackles of fossil energy and fully meet the economic sustainability needs. For a long time, the complex process of silicon solar cells, serious environmental pollution and high cost during the preparation process have limited their wide application. Until the early 1990s, the sandwich structure of dye-sensitized solar cells came out, and then this new type of solar cells became an international research hotspot...

Claims

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Application Information

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IPC IPC(8): H01G9/20H01G9/042
CPCY02E10/542H01G9/2022H01G9/042
Inventor 何迎春王艳芹
Owner 盐城滨瀚新材料科技有限公司