Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Electrolyte and preparation method therefor, and lithium-sulfur battery

An electrolyte and electrolyte technology, applied in non-aqueous electrolyte batteries, lithium batteries, secondary batteries, etc., can solve the problems of low coulombic efficiency of lithium-sulfur batteries, loss of positive active material, and rapid capacity decay, and achieve improved Coulombic efficiency and Capacity retention rate, effect of suppressing solubility

Inactive Publication Date: 2017-06-20
QINGDAO XIANGZHI ELECTRONICS TECH CO LTD
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The lithium-sulfur battery system is also the focus of extensive research in the current academic circles. It is generally believed that the main problems of lithium-sulfur batteries are: 1) The electronic conductivity of elemental sulfur is low
2) The S x n-anions generated during charging and discharging have strong nucleophilic ability, and there is interaction between them and solvents such as carbonate and LiPF 6 or electrolyte materials, so traditional lithium-ion battery electrolytes are not suitable for lithium ion batteries. Sulfur battery system, 3) polysulfides (Li2S x) (x=4~8) generated during charging and discharging will gradually dissolve into the electrolyte and shuttle between the positive and negative electrodes, resulting in the loss of positive active materials, At the same time, this is also an important factor for the low coulombic efficiency and fast capacity decay of lithium-sulfur batteries.
4) Using metal lithium as the negative electrode, there is a problem of lithium dendrites in the long cycle process
It has also been reported that the selection of solid-state electrolytes can partially inhibit the generation of dendrites (X.Liang, et al., Journal of Power Sources, 2011, 196, 3655), but the conductivity of organic all-solid-state electrolytes is low, resulting in the battery's low temperature at room temperature. Difficult to charge and discharge with high current

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Electrolyte and preparation method therefor, and lithium-sulfur battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1. Preparation of electrolyte materials

[0026] Lithium reference preparation of perfluoroalkylsulfonylimides. Preparation of ionic liquids containing ether functional groups.

[0027] 2. Preparation of electrolyte

[0028] In an argon atmosphere glove box (H2O<1ppm), dissolve 1M lithium trifluoromethanesulfonyl imide in N,N-diethyl-N,N-di(methoxyethyl)ammonium-tris In the fluoromethylsulfonylimide salt, fully stir evenly to obtain the lithium-sulfur battery electrolyte (free acid<5ppm, moisture<10ppm) of the present invention.

[0029] 3. Preparation of lithium-sulfur battery

[0030] Place the sulfur-based positive pole piece, the separator, and the lithium metal sheet in the battery case, add the electrolyte solution prepared in this example dropwise, and seal it to prepare a CR2025 button battery.

[0031] 4. Test method for flame retardant performance of electrolyte

[0032] Soak an equal weight of glass wool in the electrolyte solution for 10 minutes, then t...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention provides an electrolyte and a preparation method therefor, and a lithium-sulfur battery prepared by adopting the electrolyte. The electrolyte comprises an electrolyte lithium salt, a non-aqueous organic solvent and an ether group functional group-containing ionic liquid. By taking the ether group functional group-containing ionic liquid as a solvent, the vapor pressure of the electrolyte can be obviously lowered, and the flame retardancy of the electrolyte can be improved; and by virtue of the existence of the ether group functional group, the dissolvability and degree of dissociation of the lithium salt in the electrolyte can be promoted.

Description

technical field [0001] The invention relates to the field of preparation of lithium battery electrode materials, in particular to an electrolytic solution and a preparation method thereof, and a lithium-sulfur battery prepared by using the electrolytic solution. Background technique [0002] With the rapid development of compact portable electronic devices and power batteries, the demand for high energy density batteries is increasing. Elemental sulfur has a high theoretical specific capacity (1675mAh / g) and specific energy (2600Wh / kg), which is more than five times the theoretical energy density of traditional lithium-ion batteries. The actual energy density of lithium-sulfur batteries currently developed is 400~ 600Wh / kg, which is 2 to 3 times the actual energy density of commercial lithium-ion batteries. Elemental sulfur as a cathode material also has the advantages of abundant natural reserves, low price, and environmental friendliness. [0003] The lithium-sulfur batt...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0569H01M10/052
CPCH01M10/052H01M10/0569Y02E60/10
Inventor 李春花
Owner QINGDAO XIANGZHI ELECTRONICS TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products