A honeycomb denitration catalyst with increased specific surface area and preparation method thereof

Abstract

The invention discloses a honeycomb denitration catalyst with increased specific surface area and a preparation method. The preparation method comprises steps as follows: (1) beating active alumina; (2) dissolving a titanium source precursor; (3) dissolving a tungsten source precursor and mixing the dissolved tungsten source precursor with the materials in the steps (1) and (2); (4) adjusting pH of the material evenly mixed in the step (3) to 8-13, and performing precipitation, filtering and washing to obtain a filter cake; (5) adding water to the filter cake obtained in the step (4), mixing the filter cake into a slurry state, adding a vanadium source precursor solution, and performing mixing, drying and roasting to form powder; (6) mixing a solution formed by a molybdenum source precursor with the powder in the step (5) into a slurry, stirring the mixture, adding a pore-forming agent, performing secondary stirring, allowing the mixture to stand, squeezing the mixture into a honeycomb shape, performing drying, and coating the surface with nano-tungsten oxide for roasting to obtain the denitration catalyst. The prepared denitration catalyst has the advantages that the specific surface area can be increased, and non-uniform deposition of heavy metals in flue gas on the surface of the catalyst is prevented.

Description

technical field [0001] The invention relates to a honeycomb denitration catalyst with increased specific surface area and a preparation method thereof, in particular to a denitration catalyst resistant to uneven deposition of vanadium in flue gas and a preparation method thereof, which belongs to the technical field of new inorganic materials. Background technique [0002] Nitrogen oxides (NO x ) is one of the main air pollutants, and the emission requirements are becoming increasingly stringent. my country's "Twelfth Five-Year Plan" Comprehensive Work Plan for Energy Conservation and Emission Reduction stipulates that by 2015, the total national nitrogen oxide emissions will drop by 10% compared with 2010. In September 2011, the Ministry of Environmental Protection promulgated GB13223-2001 "Emission Standards of Air Pollutants for Thermal Power Plants", which made stricter requirements on the NOx emission concentration of thermal power plants: it stipulates that the coal-f...

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Problems solved by technology

[0007] The main purpose of the present invention is to provide a honeycomb denitrification catalyst with increased specific surface area and its preparation method, so as to overcome the defect that the active center of the denitrification catalyst in the prior art is unbalanced in the high-temperature flue gas, and the catalyst of the present invention can resist smoke The uneven deposition of vanadium oxides on the surface of the channel gas increases the specific surface area of ​​the catalyst and improves the performance of the catalyst.

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