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Method for quickly depositing graphene on glass surface through metal-free catalysis

A metal-free catalysis, glass surface technology, applied in graphene, chemical instruments and methods, inorganic chemistry, etc., can solve problems such as instability, high price, brittleness, etc., to improve density, improve electrical conductivity, and optimize experimental conditions. Effect

Inactive Publication Date: 2017-11-24
SOUTHEAST UNIV
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Problems solved by technology

With the development of technologies such as touch screens and solar energy, the amount of ITO glass is also increasing, and the amount of indium tin oxide, which is the main raw material of the film layer, is also increasing significantly. This material is mainly derived from rare earths. Crushed, unstable under acid-base conditions, and poisonous

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  • Method for quickly depositing graphene on glass surface through metal-free catalysis
  • Method for quickly depositing graphene on glass surface through metal-free catalysis
  • Method for quickly depositing graphene on glass surface through metal-free catalysis

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[0036] The glass slides were ultrasonically cleaned with acetone, absolute ethanol, and deionized water for 10 min, and then dried with nitrogen gas for later use.

[0037] The dried glass sheet is placed on a special support so that the glass surface is perpendicular to the direction of the horizontal airflow, and then placed in the center of the quartz tube. After sealing, turn on the vacuum pump to evacuate the vacuum in the quartz tube to 20Pa, and finally use argon to backfill the quartz tube to normal pressure.

[0038] Heat the quartz tube from room temperature to 1050°C at a heating rate of 15°C / min, keep the flow rates of argon and hydrogen at 150sccm and 30sccm respectively during the process, anneal for 10 minutes after the temperature reaches 1050°C, and introduce 8sccm of methane as the carbon source. Grow for 35min, then turn off the methane, and cool naturally to room temperature under the mixed gas of argon (150sccm) and hydrogen (30sccm), to obtain graphene gl...

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Abstract

The invention provides a method for quickly depositing graphene on a glass surface through metal-free catalysis. The graphene is quickly deposited on the quartz glass surface by using a chemical vapor deposition (CVD) method under the condition free of an assist of a metal catalyst. The method mainly comprises the following process steps of (1) putting a clean quartz glass sheet on a special bracket, putting the quartz glass sheet and the bracket into a quartz tube and making the glass surface vertical to the horizontal air direction; (2) introducing a carrier gas into the quartz tube, heating the quartz tube to a reaction temperature from a room temperature and introducing a carbon source gas; and (3) quickly growing the graphene on the glass surface through an atmospheric chemical vapor deposition method under the condition free of the assist of the metal catalyst. The process is simple in process and easy to operate; and the conductivity of the graphene glass surface is improved on the premise of ensuring high light transmittance of the graphene glass. The graphene conductive glass with good light transmittance has potential application in multiple fields, such as a photocatalytic substrate and an anti-fog window.

Description

technical field [0001] The invention relates to a method for directly and rapidly depositing graphene on a glass surface, and belongs to the technical field of material chemical preparation. Background technique [0002] Glass is a relatively transparent solid substance that forms a continuous network structure during melting, and is a silicate non-metallic material that gradually increases in viscosity and hardens during cooling. Glass is one of the indispensable materials in daily life, and has a wide range of applications in the fields of architecture, home furnishing and decoration. Traditional glass has the characteristics of insulation, hydrophilicity and high transparency. A layer of transparent conductive film is coated on the surface of the glass, and the obtained transparent conductive glass is widely used in liquid crystal displays, solar cells, optoelectronics and various optical fields. The most common conductive glass is ITO glass, that is, a layer of indium ...

Claims

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Application Information

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IPC IPC(8): C01B32/186C03C17/22
CPCC03C17/22C01B2204/22C01P2002/82C01P2004/03C01P2004/04C03C2217/28C03C2217/76C03C2218/152
Inventor 郭新立陈忠涛刘园园赵丽张伟杰祝龙刘闯殷亮亮金开
Owner SOUTHEAST UNIV
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