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High-water-white-resistance acrylic acid water-in-water emulsion and preparation method thereof

A technology of water-in-water emulsion and water-whitening resistance, which is applied in coatings and other directions, can solve problems such as poor stability, poor water-whitening resistance, and poor corrosion resistance, so as to improve transparency, water resistance, water-whitening resistance, The effect of improving stability

Inactive Publication Date: 2017-12-19
GUANGDONG VALSPAR CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current water-in-water multi-color coatings generally have the problems of poor initial water whitening resistance, particle strength, aging resistance, and corrosion resistance. Every time it rains, after being washed by rain, the surface of the paint film will turn white and turn white. It is not resistant to scratching, loosening or even peeling off, which greatly affects the appearance of the building; at the same time, it also has problems such as poor stability, easy thickening, particle bleeding, etc., and these problems are related to the formulation system of water-in-water multicolor coating The design itself is directly related to

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A high water whitening resistance acrylic water-in-water emulsion, made of the following parts by weight: 70 parts by weight of 2-ethylhexyl acrylate emulsion, 58 parts by weight of silicon acrylic emulsion, 9 parts by weight of cellulose, and 10 parts by weight of kaolin , 5 parts by weight of rutile titanium dioxide, 10 parts by weight of talcum powder, 12 parts by weight of hydrated iron oxide, 8 parts by weight of tetramethyl silicate, 8 parts by weight of aminopropyl triethoxysilane, allyloxy polyoxyethylene ether 1.5 parts by weight of ammonium sulfate, 6 parts by weight of sodium persulfate, and 70 parts by weight of water.

[0027] The preparation method of described highly water-resistant whitening acrylic water-in-water emulsion comprises the following steps:

[0028] (1) Mix 2-ethylhexyl acrylate emulsion and tetramethyl silicate in deionized water evenly, add sodium hydroxide solution to adjust the pH value of the solution to 10-12, then add aminopropyltriet...

Embodiment 2

[0033] A highly water-resistant acrylic water-in-water emulsion, made of the following parts by weight: 60 parts by weight of ethyl acrylate emulsion, 60 parts by weight of silicon acrylic emulsion, 10 parts by weight of cellulose, 8 parts by weight of kaolin, and rutile titanium dioxide 7 parts by weight, 5 parts by weight of talcum powder, 15 parts by weight of titanium cobalt green, 6 parts by weight of tetramethyl silicate, 10 parts by weight of aminoethylaminopropylmethyl dimethoxysilane, allyloxypolyoxyethylene 1 part by weight of ammonium ether sulfate, 5 parts by weight of sodium persulfate, and 60 parts by weight of water.

[0034] The preparation method of described highly water-resistant whitening acrylic water-in-water emulsion comprises the following steps:

[0035](1) Mix ethyl acrylate emulsion and tetramethyl silicate in deionized water evenly, add sodium hydroxide solution to adjust the pH value of the solution to 11.3, then add aminoethylaminopropylmethyldime...

Embodiment 3

[0040] A highly water-resistant acrylic water-in-water emulsion, made of the following parts by weight: 72 parts by weight of methyl acrylate emulsion, 55 parts by weight of silicon acrylic emulsion, 8 parts by weight of cellulose, 10 parts by weight of kaolin, and rutile titanium dioxide 12 parts by weight, 15 parts by weight of talc, 10 parts by weight of zinc chromate, 10 parts by weight of tetrabutyl silicate, 6 parts by weight of 2-aminoethylaminopropyl trimethoxysilane, allyloxynonylphenol poly 2 parts by weight of oxyethylene ether, 8 parts by weight of sodium persulfate, and 80 parts by weight of water.

[0041] The preparation method of described highly water-resistant whitening acrylic water-in-water emulsion comprises the following steps:

[0042] (1) Mix methyl acrylate emulsion and tetrabutyl silicate in deionized water evenly, add sodium hydroxide solution to adjust the pH value of the solution to 10.8, then add 2-aminoethylaminopropyltrimethoxysilane and allyl ...

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Abstract

The invention belongs to the technical field of coatings and particularly relates to a high-water-white-resistance acrylic acid water-in-water emulsion and a preparation method thereof. The high-water-white-resistance acrylic acid water-in-water emulsion is prepared from the following substances in parts by weight: 50-80 parts of an acrylate emulsion, 50-70 parts of a silicone acrylate emulsion, 5-12 parts of cellulose, 10-40 parts of an inorganic filler, 5-18 parts of pigments, 5-12 parts of organic silicate ester, 5-12 parts of a silane coupling agent, 1-3 parts of an emulsifying agent, 3-8 parts of an initiator and 50-100 parts of water. By utilizing a reactive emulsifying agent, most emulsifying agent molecules can be bonded to a molecular chain through polymerization reaction, so that a micromolecular existence form of the emulsifying agent is reduced, the desorption, migration and aggregation of the emulsifying agent are avoided, and therefore, the water white resistance of an emulsion coating film is improved.

Description

technical field [0001] The invention belongs to the technical field of coatings, in particular to a highly water-resistant whitening acrylic water-in-water emulsion and a preparation method thereof. Background technique [0002] With the improvement of people's living standards, the upsurge of interior decoration has quietly risen, and people have higher and higher requirements for the decorative effect of coatings. With its bold conception, multi-color paint breaks the traditional single-color and flat coating decoration effect, and creates a colorful and three-dimensional decorative surface, which is favored by consumers. At present, the oil-in-water type colorful pattern paint is more popular in the market. Its coating film is plump, bright in color, gorgeous in pattern and perfect in decorative effect. It is actually a colloid, which contains a dispersed phase and a continuous phase. In the dispersed phase, there is The existence of the protective colloid solution makes...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/08C09D133/12C09D133/04C09D131/04C09D7/12C08F2/24
CPCC09D133/08C08F2/24C08K2003/2241C08L2205/02C08L2205/035C08L2312/00C09D131/04C09D133/12C09D143/04C08L43/04C08L1/02C08L71/02C08K13/06C08K3/34C08K3/22C08K3/36C08L33/08C08L33/12C08K3/24
Inventor 黄宏亭袁海兵廖基林谢志超张海军黄冠陪刘振兴
Owner GUANGDONG VALSPAR CHEM IND
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