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A method for manufacturing a high-density tungsten carbide coated roller for a solvent-free composite machine

A solvent-free lamination machine and tungsten carbide coating technology, which is applied in the coating, metal material coating process, fusion spraying, etc., can solve the problems of reduced barrier performance of aluminum foil, air bubbles, and uneven high points on the roller surface. Improved wear resistance and service life, improved service life, and less sticking effect

Active Publication Date: 2019-08-13
GUANGDONG INST OF NEW MATERIALS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Electroplated chromium is relatively dense, with small porosity, less glue, surface finish Ra0.02μm, but not wear-resistant; chromium oxide coating is more wear-resistant than electroplated chrome, but the porosity is generally 2-3%, and the amount of glue is large. Residual glue remains in the pores, which is difficult to clean. Residual glue will cause unevenness and high points on the roller surface. When the compounding speed is fast, it will cause changes in the amount of glue applied and coating uniformity. Blanks will cause white spots and air bubbles, which will reduce product quality. , especially when compounding aluminum foil, the concave and convex high points cause the surface of the aluminum foil to be uneven, the pinhole size is large, and the number increases, which reduces the barrier performance of the aluminum foil and cannot meet the use requirements
[0005] Tungsten carbide coating has the characteristics of low porosity (1100Hv), but conventional supersonic flame spraying still has a porosity of 0.7-1%, and the combination of particles and particles during high-speed operation Insufficient force will also cause wear and tear, which cannot meet the requirements of the coating mechanism of the solvent-free compound machine

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] In the HVAF supersonic flame spraying embodiment described in this embodiment, the roller of the solvent-free laminating machine has a diameter of 190mm and a length of 1450mm, and adopts 45# quenched and tempered seamless steel pipe, and the hardness of the roller surface is about HRC50.

[0031] The metering roller of this solvent-free composite machine has a diameter of 190mm. After conventional degreasing and sandblasting, the supersonic flame spraying equipment (HVAF) is used to spray nickel-based tungsten carbide (10% nickel 90% tungsten carbide), and the weight ratio is 30%. Spherical WC particles with a particle size of 35-70 microns. The linear speed of the roller is 71.6m / min, the workpiece speed is 120 rpm, the lateral movement speed of the spray gun is 10mm / s, and the spraying parameters are: air 0.56MPa, propane 0.54MPa, H 2 Flow rate is 30L / min, spray 10 times. During the spraying process, the air cooling method is used to control the temperature of the r...

Embodiment 2

[0034] In the HVAF supersonic flame spraying embodiment described in this embodiment, the roller of the solvent-free laminating machine has a diameter of 188mm and a length of 1140mm, and a 20# seamless steel pipe is used.

[0035] The coating roller of this solvent-free composite machine has a diameter of 188mm. After conventional degreasing and sandblasting, the supersonic flame spraying equipment (HVAF) is used to spray cobalt-based tungsten carbide (12% cobalt 88% tungsten carbide), adding 40% Spherical WC particles with a particle size of 35-70 microns. The linear speed of the roller is 70.8m / min, the workpiece speed is 120 rpm, the lateral movement speed of the spray gun is 10mm / s, and the spraying parameters are: air 0.55MPa, propane 0.48MPa, H 2 Flow rate is 30L / min, spray 9 times. During the spraying process, the roller temperature is controlled below 120°C. Spray tungsten carbide coating 0.23-0.25mm. Using MH-5D microhardness tester, the microhardness of the coati...

Embodiment 3

[0037] In the example of HVOF supersonic flame spraying described in this example, the rubber transfer roller of the solvent-free compound machine has a diameter of 240mm and a length of 1400mm, and is made of forged alloy steel.

[0038] The diameter of the rubber roller is 240mm. After conventional degreasing and sandblasting, the cobalt-chromium-based tungsten carbide (10% cobalt 4% chromium 86% tungsten carbide) is sprayed with supersonic flame spraying equipment (HVOF), and 40% of the particle size is added. 35-70 micron spherical WC particles. The linear speed of the roller is 90m / min, the rotational speed of the workpiece is 120 rpm, the lateral movement speed of the spray gun is 10mm / s, and the spraying parameters are: oxygen 900L / min, kerosene 26L / min, H 2 Flow rate is 30L / min, spray 11 times. During the spraying process, the temperature of the roller is controlled below 120°C, and the tungsten carbide coating is sprayed with a thickness of 0.21-0.22mm. Using MH-5D ...

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Abstract

The invention provides a manufacturing method of a high-density tungsten carbide coating roll for a solvent-free compound machine. Aiming at meeting the requirements for high wear resistance, low porosity and low friction coefficient of a coating roll for the solvent-free compound machine, a method for adding 5%-50% by weight of spherical WC particles with particle size being 30-100 mu m to spraying powder of sintered or agglomerated Ni-based WC, Co-based WC or Co-Cr-based WC and the like is adopted, high-speed spherical WC particles rebound instead of depositing in a coating during spraying,under the beating action after rebounding, the coating is more dense and low in porosity, coating glue is not prone to sticking and is easy to clean during using, and transfer rate is high; meanwhile,binding force between particles in the coating is increased under the action of repeated beating of the spherical WC particles, the particles are not prone to stripping during high-speed wearing, wear resistance is improved, and service life of the roll is prolonged. Porosity of a metering roll, a glue transfer roll and the coating roll, manufactured with the method, of the solvent-free compoundmachine is lower than 0.4%, surface smoothness is high, Ra is smaller than 0.08 mu m, wear resistance and transfer rate are high, and the service life is prolonged by 5 times or more.

Description

technical field [0001] The invention relates to a method for manufacturing a high-density tungsten carbide coating roller for a solvent-free composite machine, in particular to a method for manufacturing a high-density tungsten carbide coating for a metering roller, a rubber transfer roller, and a rubber coating roller of a solvent-free composite machine coating mechanism. Method of supersonic flame spraying. Background technique [0002] At present, the three most important environmental protection technologies for international flexible packaging are: solvent-free lamination technology, flexographic printing and co-extrusion lamination, among which solvent-free lamination technology is the most environmentally friendly. At present, solvent-free lamination technology has occupied a very important position in the European and American markets, accounting for 80% to 90% of new lamination equipment. In my country, solvent-free composite technology began in the middle and late...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C4/129C23C4/06
CPCC23C4/06C23C4/129
Inventor 张忠诚朱晖朝李永才罗朝建雷运生朱霞高刘自敬李凯
Owner GUANGDONG INST OF NEW MATERIALS
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