Water-soluble ternary chelating polymer molecular brush anionic dye capture agent and its preparation method and application
A technology for chelating polymers and anionic dyes, applied in water pollutants, chemical instruments and methods, waste paint treatment, etc. It can solve the problem of complex heavy metal ions, efficiently capture, and quickly settle.
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Embodiment 1
[0019] It is a water-soluble ternary chelating polymer molecular brush anionic dye scavenger, which is prepared by the following steps:
[0020] Step 1 Synthesis of polymer backbone PHEMAA
[0021] Take 2 parts of azobisisobutyronitrile initiator, 200 parts of hydroxyethylacrylamide (HEMAA), and 200 parts of methanol, and carry out polymerization reaction at 60°C for 7 hours under the protection of nitrogen to obtain a degree of polymerization (DP) of 35 Polyhydroxyethylacrylamide (PHEMAA);
[0022] Step 2 Synthesis of cationic polymer side chain precursor polymer PDMC-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0023] Synthesis of cationic polymer side chain PDMC-COOH: Take 4 parts of azodicyanovaleric acid initiator, 150 parts of methacryloyloxyethyltrimethylammonium chloride (DMC) and 150 parts of water , carry out free radical polymerization at 60°C for 6 hours under the protection of nitrogen, and obtain PDMC-COOH with a degree of polymerization...
Embodiment 2
[0032] It is a water-soluble ternary chelating polymer molecular brush anionic dye scavenger, which is prepared by the following steps:
[0033] Step 1 Synthesis of polymer backbone PHEMAA
[0034] Take 2 parts of ethyl 2-bromoisobutyrate initiator, 2 parts of CuBr and 2 parts of 4,4-linked 2-picoline (BPy), 100 parts of hydroxyethylacrylamide (HEMAA), 50 Parts of methanol were polymerized at 55°C for 12 hours under the protection of nitrogen to obtain polyhydroxyethylacrylamide (PHEMAA) with a degree of polymerization (DP) of 110;
[0035] Step 2 Synthesis of cationic polymer side chain precursor polymer PDMC-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0036] Synthesis of cationic polymer side chain PDMC-COOH: Take 3 parts of azodicyanovaleric acid initiator, 150 parts of methacryloyloxyethyltrimethylammonium chloride (DMC) and 100 parts of water , carry out free radical polymerization at 70°C for 12 hours under the protection of nitrogen, and obtai...
Embodiment 3
[0045] It is a water-soluble ternary chelating polymer molecular brush anionic dye scavenger, which is prepared by the following steps:
[0046] Step 1 Synthesis of PHEMAA polymer backbone
[0047] Take 1 part of ethyl 2-bromoisobutyrate initiator, 1 part of CuBr and 1 part of 4,4-linked 2-picoline (BPy), 100 parts of hydroxyethylacrylamide (HEMAA), 50 Parts of methanol were polymerized at 70°C for 10 hours under the protection of nitrogen to obtain polyhydroxyethylacrylamide (PHEMAA) with a degree of polymerization (DP) of 195;
[0048] Step 2 Synthesis of cationic polymer side chain precursor polymer PDMC-COOH and functional polymer side chain precursor polymer PNVF-COOH
[0049] Synthesis of cationic polymer side chain PDMC-COOH: Take 1 part of azodicyanovaleric acid initiator, 150 parts of methacryloyloxyethyltrimethylammonium chloride (DMC) and 100 parts of water , under the protection of nitrogen, free radical polymerization was carried out at 75°C for 18 hours to obta...
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