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Spinning material capable of being quickly dissolved or dispersed and preparation method and application thereof

A spinning material and fast technology, applied in the direction of electrospinning, textiles and papermaking, single-component protein rayon, etc., can solve the problems of low solubility, slow evaporation rate, and reduce material porosity, etc., to achieve rich surface structure, Effects that are convenient to store and use

Pending Publication Date: 2018-04-24
山东彼岸化工产品有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the wet spinning process involved in this invention uses acetic acid solution as a collagen solvent, which has low solubility, and the acidic solvent has too strong binding force with collagen, and the evaporation speed is slow, which leads to fiber deposition and entanglement, and reduces the porosity of the material. What's more, it caused more than 70% damage to the triple helix structure
In addition, this patented technology needs to use sodium sulfate solution to promote protein salting out, so that the surface of collagen is closed, which further reduces the porosity of the material
In the follow-up treatment, although there is a short-term cleaning with dilute ethanol solution, the residue of sodium sulfate cannot be avoided; in addition, after cleaning, the as-spun silk needs to be kept at 60-80°C for 24-48 hours, and the production and processing cycle is longer; finally, with The water-soluble speed of the collagen spinning material processed by this process is slow, and it is not uniform enough, and there are flocs visible to the naked eye.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Solvent preparation: Mix 500 parts by weight of deionized water and 500 parts of ethanol evenly, slowly add lactic acid dropwise until the pH value shows 4, slowly add glycerin, the amount of glycerin added is 5% of lactic acid, and stir evenly to obtain a colorless and transparent Electrospinning solvent; the dehydrated ethanol is wt99.5%, the food-grade citric acid is wt54%, the food-grade lactic acid is wt88%, and the food-grade glycerin is wt99.7%.

[0021] Configure the electrospinning stock solution: pour 1000 parts by weight of solvent and 250 parts by weight of pure collagen powder into a round bottom flask, and stir at 60°C to dissolve all the collagen into a colorless and transparent solution;

[0022] A small electrospinning equipment is selected: the receiving distance is 70mm; the diameter of the spinneret is 1.0mm; the electric field strength is 300kV / m; the drum receiver with a diameter of 150mm is used, and the rotation speed is 3600rpm; A spinning mater...

Embodiment 2

[0024] Solvent preparation: mix 700 parts by weight of deionized water and 300 parts of ethanol evenly, slowly add citric acid dropwise until the pH value shows 3, add glycerin dropwise, the amount of glycerol is 5% of citric acid, stir evenly to obtain a colorless Transparent electrospinning solvent; the dehydrated alcohol is wt99.5%, the food-grade citric acid is wt54%, the food-grade lactic acid is wt88%, and the food-grade glycerin is wt99.7% %.

[0025] Prepare electrospinning stock solution: pour 1000 parts by weight of solvent, 250 parts by weight of pure collagen powder, 100 parts by weight of chitosan, and 7 parts by weight of Yunnan Baiyao into a round bottom flask. Stir at 60°C to dissolve all the solid powder to obtain a colorless and transparent solution;

[0026] A small electrospinning equipment is selected: the receiving distance is 70mm; the diameter of the spinneret is 1.0mm; the electric field strength is 300kV / m; the drum receiver with a diameter of 150mm ...

Embodiment 3

[0028] Solvent preparation: mix 500 parts by weight of deionized water and 500 parts of ethanol evenly, slowly add lactic acid dropwise until the pH value shows 4, add glycerin dropwise, the amount of glycerin added is 5% of citric acid, and electromagnetically stir evenly to obtain a colorless Transparent electrospinning solvent; the dehydrated alcohol is wt99.5%, the food-grade citric acid is wt54%, the food-grade lactic acid is wt88%, and the food-grade glycerin is wt99.7% %.

[0029] Configure the electrospinning stock solution: pour 1000 parts by weight of solvent into the round bottom flask, 350 parts by weight of A collagen paste powder, stir at 60°C to completely dissolve the A collagen paste powder, and then filter it with an 80-mesh filter screen to obtain Reddish brown translucent electrospinning stock solution;

[0030] A small electrospinning equipment is selected: the receiving distance is 90mm; the diameter of the spinneret is 1.5mm; the electric field strength...

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Abstract

The invention provides a rapidly dissolving or dispersing spinning material and its preparation method and application. Ethanol and water are used as neutral base solvents, a small amount of citric acid or lactic acid is used as a crosslinking agent, and glycerin is used as a crosslinking accelerator. , using the electrospinning method to process hot-melt natural macromolecular colloidal substances or pure natural macromolecular extracts or compound substances into silk threads, and weave the silk threads into various shapes that are convenient for packaging, storage and carrying. According to the melt viscosity, toughness and dispersion characteristics of the substance, it is processed into filaments of different diameters, so as to realize rapid dissolution or dispersion in the water phase or oil phase, and achieve the effect of instant dissolution in water.

Description

technical field [0001] The invention belongs to the field of health care products and skin care products, and in particular relates to a rapidly dissolving or dispersing spinning material and its preparation method and application. Background technique [0002] Hot-melt natural macromolecular colloids or pure natural macromolecular extracts, such as collagen, donkey-hide gelatin, propolis, isinglass, peach gum, bird's nest, etc., are widely used in food, beverages, cosmetics, health care products and medical treatment . Its many functions, such as nourishing blood, stopping bleeding, nourishing yin, nourishing qi, moistening dryness, moistening lungs and beautifying skin, relieving cough and asthma, repairing wounds, removing wrinkles, removing freckles, and improving immunity, have received more and more attention. The acquisition, pretreatment, finished product and use of these products are relatively complicated processes, and even more professional technical capabilitie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01D5/00D01F4/00
CPCD01D5/003D01F4/00
Inventor 薛永和
Owner 山东彼岸化工产品有限公司
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